The Impact of Large-Scale Reclamation on Hydro-Dynamic Environment——A Case Study of Xinghua Bay

A hydro-dynamic model is established on basis of MIKE21 FM to simulate the hydro-dynamic characteristics of Xinghua Bay and investigate the influence of reclamation project on the tidal elevation and tidal currents. Tidal elevation data was obtained at the six tide gauge stations around the Xinghua Bay, and another six current stations were established to observe the tidal current velocity and direction. Validation shows that the model-simulated tidal elevation and tidal currents agree well with observations made at different stations. Predictions are made according to the reclamation project proposed in the regional marine planning of Hanjiang Industrial Park around the port in Putian City. The variations of hydro-dynamic factors, such as tide, current velocity and direction and tidal influx are obtained, and the adverse effect of reclamation on marine environment is discussed. It is shown that the tidal level inside the Xinghua Bay during high tide decreases after the reclamation project is completed. The tidal currents during flooding tide generally decrease in the southeast of the reclamation region, with the maximum decreasing amplitude reaching 0.44 m s^-1. On the other hand, the tidal currents during flooding tide increase around the southeast and southwest corners of the reclamation region. The tidal currents during ebb tide increase around the southeast and southwest corners of the reclamation region, with the maximum increasing amplitude attaining 0.18 m s^-1. The results in this paper can give some guidance for the marine environment management and the effective utilization of land in Putian.     

Constraints on sedimentary ages of the Chuanlinggou Formation in the Ming Tombs,Beijing, North China Craton: LA-ICP-MS and SHRIMP U–Pb dating of detrital zircons

Detrital zircons in five sedimentary samples, MC1 to MC5, from the bottom of the Chuanlinggou Formation in the Ming Tombs District, Beijing, were dated with the LA-ICP-MS and SHRIMP U–Pb methods. Age spectra of the five samples show a major peak at 2500 Ma and a secondary peak at 2000 Ma, suggesting their provenances were mainly from the crystalline basement of the North China Craton and the Trans-North China Orogen. The youngest zircon has an age of 1673 ± 44 Ma, indicating that the Chuanlinggou Formation was deposited after this age. From sample MC4 to MC5, lithology changed from a clastic rock (fine-grained sandstone) to a carbonate rock (fine-grained dolomite), suggesting that the depositional basin became progressively deeper. The age spectrum of sample MC5 shows a major peak at 2500 Ma and a secondary peak at 2000 Ma. Sample MC4, which is stratigraphically lower than sample MC5, only had one peak at 2500 Ma. We conclude that there was a transgressive event when sediments represented by MC5 was deposited, and seawater carried ca. 2000 Ma clastic materials to the basin where the Chuanlinggou Formation was deposited, leading to the addition of ca. 2000 Ma detritus. Our research indicates that the source area for the sediments became more extensive with time. We conclude that the Chuanlinggou Formation in the Ming Tombs District was deposited in a low-energy mud flat sedimentary environment in the inter-supra tidal zone because it is mainly composed of silty mudstone and fine-grained sandstone with relatively simple sedimentary structures.     

Mechanical behavior and micro-structure of cement kiln dust-stabilized expensive soil

In this study, the effects of cement kiln dust (CKD) on the swelling properties, strength properties, and microstructures of CKD-stabilized expansive soil were investigated. Samples were prepared and stabilized with different CKD content ratios, ranging from 0 to 18% by dry mass. The results obtained show that the maximum swelling pressures decrease exponentially with increases in CKD content. Both the cohesion and unconfined compressive strength (UCS) increase at ratios below 10% CKD and then decrease slightly, above that ratio. CKD can also improve the strength of saturated, expansive soil. There is no visible change of UCS for soil without CKD when cured, while the UCS of a sample with 10% CKD content after curing for 90 days is higher than that after curing for only 1 day. This indicates that CKD can improve the long-term strength of expansive soil. Finally, microstructure analysis reveals that the addition of CKD reduces the montmorillonite content of expansive soil and decreases its swelling properties. The addition of CKD also changes the pore volume distribution, both the size and amount of macro-pores and micro-pores decrease with increase in CKD content. For saturated samples, the size of macro-pores is obviously reduced, while that of micro-pores is slightly increased for both treated and untreated soils. Hydration and saturation processes make the soil structure become dispersive which results in a lower strength, and adding CKD can restrain this process. The suggested optimal CKD content is between 10 and 14% and with a curing time of more than 27 days.     

碘化氨除锡后封闭酸溶-电感耦合等离子体质谱测定锡矿石中的共生和伴生元素

锡矿石是难分解的矿物,主要存在形式是锡石(SnO_2),且共生和伴生元素多,常用的酸溶方法几乎不能溶解SnO_2,从而给锡矿石中的共生与伴生元素的准确测定带来困难。本文基于碘化氨在较低温度下熔融可产生无水状态的碘化氢,利用碘化氢的酸性和氨的还原性分解SnO_2,使Sn呈SnI_4升华分离的原理处理锡矿石。实验中以高纯铂丝作催化剂,加入碘化铵在450℃的马弗炉中分解锡矿石30 min,使得Sn以SnI_4形式挥发,除锡率达到98%以上,再用2 mL氢氟酸和1 mL硝酸封闭溶解残渣,电感耦合等离子体质谱测定钴镍铜铌钽钍铀等24个共生和伴生元素。元素检出限在0. 001～2. 9μg/g之间,90%以上元素的相对标准偏差(RSD)小于5%,相对误差小于10%。本方法解决了锡矿石难分解的问题,可测定共存金属元素,也适合测定Sn含量在1. 27%～62. 49%之间的锡矿石中的微量和痕量元素及锡精矿中的微量元素。     

内蒙古阿拉善右旗大山口地区黑云母花岗岩地球化学特征及成因

内蒙古自治区阿拉善右旗大山口地区发育有大面积侵入岩,主要为华力西中晚期和印支期酸性侵入岩体及各类脉岩。本次运用LA-ICP-MS锆石U-Pb测年方法获得黑云母花岗岩的成岩年龄为229.5±5.6 Ma,属晚三叠世,大山口黑云母花岗岩SiO_2含量68.89%～71.04%,相对富钾贫钠;A/NKC介于0.89～1.05,强烈富集强不相容元素,亏损高场强元素Na、Ta、Ti、P,Eu异常不明显,HREE呈近平坦型分布。通过黑云母花岗岩的成因研究和构造环境判别分析,认为大山口黑云母花岗岩为加厚的中下地壳物质拆沉进入地幔加热并发生部分熔融,且熔体可能与地幔基性熔体发生一定程度的混合作用后上升形成的花岗岩,形成于晚三叠世后碰撞伸展垮塌的构造环境。     

Study on Water Internal Recycle Process and Mechanism in Typical Mountain Areas of Inland Basins,Northwest China: Progress and Challenge

The water resource and its change of mountainous area are very important to the oasis economic system and ecosystem in the arid areas of northwest China. Accurately understanding the water transfer and circulation process among vegetation, soil, and atmosphere over different hydrological units in mountainous areas such as snow and ice, cold desert, forest and grassland is the basic scientific issue of water research in cold and arid regions, which is also the basis of water resource delicacy management and regulation. There are many research results on the hydrological function of different land covers in mountain areas, basin hydrological processes, however, there are only very limited studies on the water internal recycle at basin scale. The quantitative study on the mechanism of water internal recycle is still at the starting stage, which faces many challenges. The key project “Study on water internal recycle processes and mechanism in typical mountain areas of inland basins, Northwest China” funded by National Natural Science Foundation of China will select the Aksu River and Shule River Basin, which have better observation basis, as study area. The internal mechanism of moisture transfer and exchange process of different land cover and atmosphere, the internal mechanism of water cycle in the basin, and water transfer paths in atmosphere will be studied through enhancing runoff plot experiments on different land cover, analyzing the mechanism of water vapor transfer and exchange between different land covers in the watershed by isotope tracing on the water vapor flux of vegetation water, soil moisture and atmospheric moisture, improving the algorithms of remote sensing inversion and ground verification on land surface evapotranspiration on different land cover, and analyzing the water vapor flux from reanalysis data, and the coupling modeling of regional climate model and land surface process model. At last, the effect of different land cover in hydrological process of mountain area, and the impact of land cover on downstream oasis will be systematically analyzed.     

A modified mix-differenced approach for estimating multi-GNSS real-time satellite clock offsets

A modified mixed-differenced approach for estimating multi-GNSS real-time clock offsets is presented. This approach, as compared to the earlier presented mixed-differenced approach which uses epoch-differenced and undifferenced observations, further adds a satellite-differenced process. The proposed approach, based on real-time orbit products and a mix of epoch-differenced and satellite-differenced observations to estimate only satellite clock offsets and tropospheric zenith wet delays, has fewer estimated parameters than other approaches, and thus its implementing procedure is efficient and can be performed and extended easily. To obtain high accuracy, the approach involves three steps. First, the high-accuracy tropospheric zenith wet delay of each station is estimated using mixed-differenced carrier phase observations. Second, satellite clock offset changes between adjacent epochs are estimated using also mixed-differenced carrier phase observations. Third, the satellite clock offsets at the initial epoch are estimated using satellite-differenced pseudorange observations. Finally, the initial epoch clock results and clock offset changes are concatenated to obtain the clock results of the current epoch. To validate the real-time satellite clock results, multi-GNSS post-processing clock products from IGS ACs were selected for comparison. From the comparison, the standard deviations of the GPS, GLONASS, BeiDou and Galileo systems clock results are approximately 0.1–0.4 ns, except for the BeiDou GEO satellites. The root mean squares are about 0.4–2.3 ns, which are similar to those of other international real-time products. When the clock estimates were assessed based on a pseudo-kinematic PPP procedure, the positioning accuracies in the East, North and Up components reach 5.6, 5.5 and 7.6 cm, respectively, which meet the centimeter level and are comparable to the application of other products.     

Variations of methane stable isotopic values from an Alpine peatland on the eastern Qinghai-Tibetan Plateau

Acta Geochimica - Isotopic signature is a powerful tool to discriminate methane (CH4) source types and constrain regional and global scale CH4 budgets. Peatlands on the Qinghai-Tibetan Plateau are...