Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin

The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (¹⁸O/¹⁶O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ¹⁸O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ¹⁸O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ¹⁸O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ¹⁸O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ¹⁸O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ¹⁸O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ¹⁸O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ¹⁸O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have a large variety of colored sapphires and rubies with a large variation in δ¹⁸O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire, syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire.     

Influence of low ozone episodes on erythemal UV-B radiation in Austria

This study investigates the influence of low ozone episodes on UV-B radiation in Austria during the period 1999 to 2015. To this aim observations of total column ozone (TCO) in the Greater Alpine Region (Arosa, Switzerland; Hohenpeissenberg, Germany; Hradec Kralove, Czech Republic; Sonnblick, Austria), and erythemal UV-B radiation, available from 12 sites of the Austrian UV-B monitoring network, are analyzed. As previous definitions for low ozone episodes are not particularly suited to investigate effects on UV radiation, a novel threshold approach—considering anomalies—is developed to provide a joint framework for the analysis of extremes. TCO and UV extremes are negatively correlated, although modulating effects of sunshine duration impact the robustness of the statistical relationship. Therefore, information on relative sunshine duration (SD_rel), available at (or nearby) UV-B monitoring sites, is included as explanatory variable in the analysis. The joint analysis of anomalies of both UV index (UVI) and total ozone (∆UVI, ∆TCO) and SD_rel across sites shows that more than 65% of observations with strongly negative ozone anomalies (∆TCO < −1) led to positive UVI anomalies. Considering only days with strongly positive UVI anomaly (∆UVI > 1), we find (across all sites) that about 90% correspond to negative ∆TCO. The remaining 10% of days occurred during fair weather conditions (SD_rel ≥ 80%) explaining the appearance of ∆UVI > 1 despite positive TCO anomalies. Further, we introduce an anomaly amplification factor (AAF), which quantifies the expected change of the ∆UVI for a given change in ∆TCO.

     

Fluorine and boron geochemistry of tektites,impact glasses,and target rocks

Abstract— We have analyzed fluorine and boron in nine tektites from all four strewn fields, and in a suite of impact glasses and target rocks from the Zhamanshin and Darwin impact craters, as well as Libyan Desert Glass and Aouelloul impact glass samples. Fluorine and boron are useful indicators for the volatilization and temperature history of tektites and impact glasses. Tektites from different strewn fields show a limited range of F and B contents and have F/B ratios near unity. Most splash-form tektites have lower average F and B contents than Muong Nong type tektites, which is similar to the relation between irghizites and zhamanshinites. The F and B contents in target rocks from the Zhamanshin and Darwin impact craters are similar to normal terrestrial sediments. Fluorine in impact glasses and tektites is more depleted compared to their (known or inferred) target rocks than is boron, which is caused by the higher volatility of F. The F/B ratios therefore decrease with increasing temperature of formation (suggesting that irghizites were formed at a higher temperature than zhamanshinites, and Muong Nong type tektites at a lower temperature than splash-form tektites). Mixing of local country rocks together with partial loss of the volatiles F and B can reproduce the F and B contents of impact glasses.     

Density control in Potamogeton perfoliatus L. and Potamogeton pectinatus L.

The effect of density on the growth, recruitment of new ramets, biomass allocation, rhizome spacer length and rhizome branching of the submersed macrophyte Potamogeton perfoliatus L. was experimentally evaluated in a mesocosm with three different initial shoot densities. The findings suggest that the number of primary shoots available in the beginning of the season can strongly influence patterns of growth and clonal reproduction. In contrast to many studies that found decreasing production parameters with plant density, ramet and biomass production of Potamogeton perfoliatus plants were highest at medium plant density. This is probably due to negative feed-back through crowding at high density and unclear negative effects at low density. Shoot allocation tended to increase with density, rhizome allocation tended to decrease with density and root biomass remained unchanged. At low density Potamogeton perfoliatus produced longer rhizome spacers and more branchings than at higher densities. Shorter rhizome spacers at high plant density probably restrict patch expansion and cause discrete patch shapes. A likely mechanism for plastic changes in clonal architecture is increasing competition for light at increasing density, but other density-dependent factors may also contribute.Investigations on propagule numbers of tubers and turions show that self-regulation of ramet number was associated with self-regulation of propagule number in both Potamogeton perfoliatus and Potamogeton pectinatus, with higher densities producing less propagules per plant.     

Inferring protoliths of high-grade metamorphic gneisses of the Erzgebirge using zirconology,geochemistry and comparison with lower-grade rocks from Lusatia (Saxothuringia,Germany)

Protoliths of highly metamorphosed gneisses from the Erzgebirge are deduced from the morphology, age and chemistry of zircons as well as from whole rock geochemistry and are compared with lower-grade rocks of Lusatia. Gneisses with similar structural appearance and/or geochemical pattern may have quite different protoliths. The oldest rocks in the Erzgebirge are paragneisses representing meta-greywackes and meta-conglomerates. The youngest group of zircon of meta-greywackes that did not undergo Pb loss represents the youngest igneous component for source rocks (about 575 Ma). Similar ages and zircon morphology reflect the subordinate formation of new zircon grains or only zircon rims in the augengneiss from Bärenstein and Wolkenstein, which probably represent metamorphic equivalents to Lower Cambrian two-mica granodiorites from Lusatia. Bulk rock chemistry, intense fracturing and high U and Th concentrations of zircons suggest deformation-induced and fluid-enhanced recrystallisation of zircon grains. Temperatures during tectonic overprinting—too low to reset zircon ages—indicate mid- or upper crustal levels for shearing recorded in these augengneisses. Lower Cambrian (~540 Ma) granodiorites are widespread in Lusatia but are exclusively represented by the Freiberg gneiss dome in the Eastern Erzgebirge. Ordovician protolith ages were recorded by zircons from the augengneisses of the Reitzenhain–Catherine dome and the Schwarzenberg dome (Western Erzgebirge) documenting significant regional differences between the eastern and the western Erzgebirge (~540 vs. ~490 Ma). In the Western Erzgebirge, most meta-volcanic rocks (muscovite gneisses) and meta-granites (mainly red augengneisses) yield Ordovician zircon ages, whereas in the Eastern part, similar rocks mainly recorded Lower Cambrian protolith ages. Zircon overprinting was highest within discrete tectonic zones where the combination of fluid infiltration and deformation induced variable degrees of recrystallisation and formation of a new augengneiss structure. Variable degrees of Pb loss caused age shifts that do not correspond to changes in zircon morphology but may be associated with U and Th enrichments. Major changes in bulk rock composition appear to be restricted to discrete zones and to (U)HP nappes, whereas gneisses with a MP–MT metamorphic overprint basically show no geochemical modifications.     

An expression of Philippine Sea plate rotation: the Parece Vela and Shikoku Basins

The Philippine Sea plate, located between the Pacific, Eurasian and Australian plates, is the world's largest marginal basin plate. The motion of the Philippine Sea plate through time is poorly understood as it is almost entirely surrounded by subduction zones and hence, previous studies have relied on palaeomagnetic analysis to constrain its rotation. We present a comprehensive analysis of geophysical data within the Parece Vela and Shikoku Basins—two Oligocene to Miocene back-arc basins—which provide independent constraints on the rotational history of the Philippine Sea plate by means of their seafloor spreading record. We have created a detailed plate model for the opening of the Parece Vela and Shikoku Basins based on an analysis of all available magnetic, gravity and bathymetric data in the region. Subduction along the Izu–Bonin–Mariana trench led to trench roll-back, arc rupture and back-arc rifting in the Parece Vela and Shikoku Basins at 30 Ma. Seafloor spreading in both basins developed by chron 9o (28 Ma), and possibly by chron 10o (29 Ma), as a northward and southward propagating rift, respectively. The spreading orientation in the Parece Vela Basin was E–W as opposed to ENE–WSW in the Shikoku Basin. The spreading ridges joined by chron 6By (23 Ma) and formed a R–R–R triple junction to accommodate the difference in spreading orientations in both basins. At chron 6No (20 Ma), the spreading direction in the Parece Vela Basin changed from E–W to NE–SW. At chron 5Ey (19 Ma), the spreading direction in the Shikoku Basin changed from ENE–WSW to NE–SW. This change was accompanied by a marked decrease in spreading rate. Cessation of back-arc opening occurred at 15 Ma, a time of regional plate reorganisation in SE Asia. We interpret the dramatic change in spreading rate and direction from E–W to NE–SW at 20±1.3 Ma as an expression of Philippine Sea plate rotation and is constrained by the spacing between our magnetic anomaly identifications and the curvature of the fracture zones. This rotation was previously thought to have begun at 25 Ma as a result of a global change in plate motions. Our results suggest that the Philippine Sea plate rotated clockwise by about 4° between 20 and 15 Ma about a pole located 35°N, 84°E. This implies that the majority of the 34° clockwise rotation inferred to have occurred between 25 and 5 Ma from paleomagnetic data may have in fact been confined to the period between 15 and 5 Ma.     

Geotechnical Aspects and Stability of Road Cuts in the Blue Nile Basin,Ethiopia

Road construction in the Blue Nile basin is largely determined by geotechnical factors. The area is characterized by steep slopes and has a history of landsliding. The geological formations range from Mesozoic sedimentary to Tertiary volcanic rocks making the stratigraphic makeup sensitive to deformation and failure. The heterogeneity of these rocks also means it is difficult to depend on results of stability analyses alone for road design and construction. As an alternative, ratios of cut-slope lengths to cut-slope heights have been developed in this study based on the performances of unsupported natural and artificial cuts and some stability analyses. Hence, road cuts on cliffs of hard rocks need a horizontal to vertical ratio of 0.25:1. Slopes made up of weak rocks can remain stable at a threshold angle of 45°. For heterogeneous slopes, it is advisable to use different road cuts depending on material makeup, and the degree of weathering and consolidation.     

Gem corundum deposits of Madagascar: A review

Madagascar is one of the most important gem-producing countries in the world, including ruby and sapphires. Gem corundum deposits formed at different stages in the geological evolution of the island and in contrasting environments. Four main settings are identified: (1) Gem corundum formed in the Precambrian basement within the Neoproterozoic terranes of southern Madagascar, and in the volcano-sedimentary series of Beforona, north of Antananarivo. In the south, high-temperature (700 to 800 °C) and low-pressure (4 to 5 kbar) granulites contain deposits formed during the Pan-African orogenesis between 565 and 490 Ma. They accompany mafic and ultramafic complexes (ruby deposits of the Vohibory group), skarns at the contact between Anosyan granites and the Proterozoic Tranomaro group (sapphire deposits of the Tranomaro–Andranondambo district), and shear-zone corridors cross-cutting feldspathic gneisses, cordieritites and clinopyroxenites in the Tranomaro, Vohimena and Androyan metamorphic series (biotite schist deposits of Sahambano and Zazafotsy, cordieritites of Iankaroka and Ambatomena). The circulation of fluids, especially along discontinuities, allowed in-situ alkaline metasomatism, forming corundum host rocks related to desilicified granites, biotitites, “sakenites” and “corundumites”. (2) Gem corundum also occurs in the Triassic detrital formations of the Isalo group, as giant palaeoplacers in the Ilakaka–Sakaraha area. Here, sapphires and rubies may come from the metamorphic granulitic terranes of southern Madagascar. (3) Gem corundum deposits occur within the Neogene-Quaternary alkali basalts from Ankaratra (Antsirabe–Antanifotsy area) and in the Ambohitra Province (Nosy Be, Ambato and Ambondromifehy districts). Primary deposits are rare, except at Soamiakatra where ruby in gabbroic and clinopyroxenite xenoliths within alkali-basalts probably derive from mantle garnet peridotites. The blue-green-yellow sapphires typical of basaltic fields are always recovered in palaeoplacer (in karst formed upon Jurassic limestones from the Montagne d'Ambre, Antsiranana Province) and alluvial and soil placers (Ankaratra volcanic massif). (4) Deposits occur within Quaternary eluvial, colluvial and alluvial concentrations, such as high-quality rubies from the Andilamena and Vatomandry deposits.     

Estimation of industrial and commercial asset values for hazard risk assessment

For risk analyses not only knowledge about the impact of different types of hazards, but also information about the elements and values at risk is necessary. This article introduces a methodology for a countrywide estimation of asset values for commercial and industrial properties using Germany as an example. It consists of a financial appraisal of asset values on the municipal level and a further disaggregation by means of land use data. Novelties are the distinction of 60 economic activities, the consideration of production site sizes and the application of a dasymetric mapping technique for a sector-specific estimation and disaggregation of asset values. A validation with empirical data confirms the feasibility of the calculation. The resulting maps can be used for loss estimations e.g. in the framework of cost–benefit analyses that aim to evaluate hazard mitigation measures or for portfolio analyses by banks and insurance companies. The approach can be used for other countries if the necessary data is available (mainly in industrialized countries). In any case, it reveals the critical points when estimating commercial and industrial asset values.