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101.
High-pressure liquids in the MgO-SiO2-H2O (MSH) system have been investigated at 11 and 13.5 GPa and between 1000 and 1350 °C. A bulk composition more magnesian than the tie-line forsterite-H2O was employed for the study. Rocking multi-anvil experiments were combined with a diamond trap set-up. After termination of the experiments, the liquid trapped in the diamond layer was analysed by laser ablation ICP-MS using the ‘freezing’ technique. At 11 GPa, liquids coexist with one or two of phase A, clinohumite, chondrodite, and forsterite. A marked discontinuity in the evolution of liquid compositions near 1100 °C is observed at 11 GPa. A step of ∼13 wt% H2O and 13 wt% MgO is interpreted to result from overstepping the fluid-saturated solidus reaction mass balanced to 1.00(18) phase A + 1.07(4) fluid = 0.63(15) chondrodite + 1.44(2) melt. At 13.5 GPa liquids coexist with one or two of hydrous wadsleyite, clinohumite, superhydrous B, phase B, and forsterite. The discontinuity in liquid composition is no longer present, indicating that the second critical endpoint of the solidus has been overstepped. Thus, hydrous melts in the Mg-rich part of the MSH system (molar bulk Mg/Si > 2) are chemically distinct from aqueous fluids at pressure up to 11 GPa. Convergence of fluid and melt compositions along the solidus resulting in a supercritical liquid occurs between 11 and 13.5 GPa, at which pressure the entire MSH system becomes supercritical. 相似文献
102.
Anomalously high Au concentrations (2.5 to 50 ppb) in regolith carbonate accumulations, such as calcrete and calcareous sands in aeolian sand dunes overlying Au mineralisation of the Gawler Craton, South Australia, show a marked covariance of Au with K, Mg and most notably Ca. This relationship appears to be linked to the authigenic formation of smectites and carbonates within the aeolian dunes in the region. However, little is known about the processes involved in the formation of carbonates under semi-arid and arid conditions. In this study the geochemical properties of aeolian dunes along several depth profiles of 2 to 4 m are investigated in order to assess the relationship between Au mobility and calcrete formation. In the profiles a strongly systematic relationship between Au and the increasing Ca–Mg contents at depth highlights the close association between the enrichment of Au in the calcrete and the underlying hydrothermal mineralisation. Intense calcrete formation and concurrent Au enrichment also occurs in the vicinity of roots penetrating the dune. Thin section petrography and cathodoluminescence show that most of the calcrete in the regolith profiles is micritic; some sparic crystallites have also been identified. To demonstrate the presence of microbial processes that may mediate the formation of calcrete, samples from a depth profile in the dune were taken under sterile conditions. After amendment with urea and incubation of up to 24 h, up to 18 mg/l of NH4+ were detected in near surface samples. At depth of 2.3 m 1 mg/l NH4+ were detected compared to a control that contained below 0.05 mg/l NH4+. These results suggest that the genesis of calcrete and pedogenic carbonate in the area may be partly biologically mediated via processes such as the metabolic breakdown of urea by resident microbiota which generates a pH and pCO2 environment conducive to the precipitation of carbonate. In the process of urea breakdown organic Au complexes such as Au-amino acid complexes may become destabilised in solution and Au may be co-precipitated, resulting in the fine, non-particulate distribution of Au throughout the micritic calcrete carbonate. In conclusion, this study suggests a coupled mechanism of biologically mediated and inorganic mechanisms that lead to the formation of Au-in-calcrete anomalies. 相似文献
103.
Dieter Kelletat Sander R. Scheffers Anja Scheffers 《Pure and Applied Geophysics》2007,164(2-3):413-431
The Andaman-Sumatra Tsunami of Dec. 26, 2004, was by far the largest tsunami catastrophe in human history. An earthquake of
9 to 9.3 on the Richter scale, the extension of waves over more than 5000 km of ocean and run-ups up to 35 m are its key features.
These characteristics suggest significant changes in coastal morphology and high sediment transport rates. A field survey
along the west coast of Thailand (Phuket Island, Khao Lak region including some Similan Islands, Nang Pha mangrove areas and
Phi Phi Don Islands) seven to nine weeks after the tsunami, however, discovered only small changes in coastal morphology and
a limited amount of dislocated sediments, restricted to the lower meters of the tsunami waves. This is in striking contrast
to many paleo-tsunami's events of the Atlantic region. Explanations for this discrepancy are sought in:
a. Mechanics of the earthquake. A rather slow shock impulse on the water masses over the very long earthquake zone,
b. Shallow water in the earthquake zone, and
c. Bathymetry of the foreshore zone at the impacted sites. Shallow water west of Thailand has diminished wave energy significantly.
The differences in geomorphological and sedimentological signatures of this tsunami compared with many paleo-tsunami worldwide
makes it unsuitable to be used as a model for old and future tsunami imprints by an event of this extreme energy and extension. 相似文献
104.
Sources and sinks of atmospheric methane 总被引:7,自引:0,他引:7
In 1972 average mixing ratio of methane in the troposphere was 1.41 ppm and 1.3 ppmv for the northern and southern hemisphere, respectively, which corresponds to a total amount of 4×1015 g of CH4 present in the atmosphere. Most is of recent biologic origin.14C analyses show that no more than 20 percent is released by fossil sources. The various ecosystems producing CH4 are discussed and the total annual production is estimated to lie between 5.5×1014 g/yr and 11×1014 g/yr. The corresponding turnover times for atmospheric CH4 range from 4 to 7 yrs. The destruction of CH4 takes place mainly in the troposphere, most probably through the reaction of CH4 + OH CH3 + H2O. About 10 percent of the CH4 is destroyed in the stratosphere. The CH4 cycle contributes on the order of 1 percent to the atmospheric carbon cycle. 相似文献
105.
Vít Kárník Dana Procházková Zdeňka Schenková Julius Drimmel Dieter Mayer-Rosa Dragutin Cvijanovic Vladimir Kuk Andelka Miloševič Francesco Giorgetti Reviewer J. Janský 《Studia Geophysica et Geodaetica》1978,22(4):411-414
Summary Isoseismal maps of the three strongest Friuli aftershocks of September 1976 were compiled using the contributions from European countries within the shaken area. The characteristic features of the macroseismic fields are discussed. 相似文献
106.
107.
108.
The fractionation of the oxygen isotopes between water molecules from different sites in CuSO4 · 5H2O has been measured for crystallization temperatures of 25, 40 and 50°C. The temperature dependence found provides a basis for the determination of crystallization temperatures from such intracrystalline oxygen isotope effects; also for hydrated crystals of mineralogical and geological interest. Necessary suppositions for the application of this method are discussed. 相似文献
109.
110.
V.A. Schmidt 《Earth and Planetary Science Letters》1976,29(1):146-154
The simplest non-interactive forms of Néel's domain-reversal and wall-motion models are examined and the variations of their respective blocking temperatures as functions of applied field and coercivity are compared. Both models show remarkably similar blocking temperature behavior, but the remanence acquisition mechanisms are so different as to produce diametrically opposed results when the Lowrie-Fuller stability criterion is considered. In particular, in low fields the wall-motion model selectively activates high-coercivity fractions while the domain-reversal model favors the low coercivities. This results in the paradox that the wall-motion model predicts behavior experimentally associated with the single-domain and pseudo-single-domain size range while the domain-reversal model predicts behavior usually associated with the large multidomain range. The paradox can be partly resolved within the multidomain model alone, but this would not apply for the smallest grain sizes. Several alternative approaches to the problems of this size range are suggested. 相似文献