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441.
This paper extends the material point method to analyze coupled dynamic, two‐phase boundary‐valued problems via a velocity formulation, in which solid and fluid phase velocities are the variables. Key components of the proposed approach are the adoption of Verruijt's sequence of update steps when integrating over time and the enhancement of volumetric strains. The connection between fractional step method and the time‐stepping algorithm presented in this paper is addressed. Enhancement of volumetric strains allows lower order variations in pressure and mitigates spurious pressure fields and locking that plague low‐order finite‐element implementations. A stress averaging technique to smoothen stress variations is proposed, and the local damping procedure adopted by FLAC is extended to handle two‐phase problems. Special Kelvin‐Voigt boundaries are developed to suppress reflections at artificial boundaries. Idealized examples are presented to demonstrate the capability of the proposed framework to accurately capture the physics of wave propagation, consolidation and wave attack on a sea dike. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
442.
Abstract— The bulk chemical composition of Orgueil and 25 other carbonaceous chondrites was determined by x‐ray fluorescence analysis. The sample sizes of the analyzed meteorites were in all cases 120 mg. The abundances of P and Ti in Orgueil and Ivuna were precisely determined by the standard addition method. The new P CI abundance is 926 ± 65 ppm. Excluding the low P of Ivuna and one Orgueil sample with unusual chemistry gives a CI P content of 930 ± 23 ppm. A CI abundance of 926 ppm corresponds to a P/Si wt ratio of 8.66 times 10?3 (atomic ratio 7.85 times 10?3). For Ti a CI content of 458 ± 18 ppm and a Ti/Si wtratio of 4.28 times 10?3 (atomic ratio 2.51 times 10?3) were found. A Si content of 10.69% was obtained for average CI. The new P CI abundance is 20 to 30% below earlier estimates, while the Ti CI abundance is in agreement with earlier determinations. From the results of the analyses of bulk carbonaceous chondrites it is concluded: (1) Refractory element/Mg ratios increase from CI through CM and C3O to C3V, but ratios among Al, Ca and Ti are constant, except for low Ca/Al ratios in the reduced subgroup of C3V. (2) The Si/Mg ratios are constant in all groups of carbonaceous chondrites. (3) There is a volatility related depletion of Cr and Fe, but the Cr/Fe ratios are constant. (4) The sequence of volatility related depletions of the moderately volatile elements P, Au, As, Mn, and Zn follows condensation temperatures (except for As), if in condensation calculations non‐ideal solid solution in the host phase is considered. 相似文献
443.
Karin Thomas Andreas Volz-Thomas Djuro Mihelcic Herman G. J. Smit Dieter Kley 《Journal of Atmospheric Chemistry》1998,29(1):17-43
The exchange of NO3 radicals with the aqueous-phase was investigated at room temperature (293 K) in a series of wetted denuders. From these experiments, the uptake coefficient of NO3 was determined on 0.1 M NaCl solutions and was found to be (NO3) 2 × 10-3 in good agreement with recent studies. The Henry coefficient of NO3 was estimated to be KH(NO3) = 1.8 M · atm-1, with a (2) uncertainty of ±3 M · atm-1. From the upper limit for the Henry coefficient (KH = 5 M · atm-1) and available thermodynamic data, the redox potential of dissolved NO3/NO
3
–
is estimated to be in the range of 2.3 to 2.5 V. This range is at the lower boundary of earlier estimates. The results are discussed in the light of a recent publication. Based on our data and a model of the transport and chemistry in the liquid film, an upper limit is derived for the product of the Henry coefficient KH and the rate coefficient k
10 of the potential reaction NO3 + H2O HNO3 + OH. For KH = 0.6 M · atm-1, we find k
10 < 0.05 s-1 · atm-1, i.e., about 100 times smaller than what was suggested by Rudich and co-workers. Because of its small solubility, heterogeneous removal of NO3 is only important under conditions where the dissolved NO3 is removed quickly from equilibrium, for example by reactions with Cl– or HSO
3
–
ions in the liquid-phase. Otherwise, heterogenous removal should mainly proceed via N2O5. 相似文献
444.
Jens Mingram Jörg F. W. Negendank Achim Brauer Dieter Berger Andreas Hendrich Michael Köhler Hartmut Usinger 《Journal of Paleolimnology》2007,37(4):517-528
We present a unique, versatile piston corer for recovering continuous lake and bog sediment sequences with superior accuracy
and quality. The main components of the system and their function are described, with special focus on measures for obtaining
long, continuous lake sediment sections up to a current maximum length of 95 m. Examples of lake sediment profiles obtained
with this system from different climatic zones are presented. 相似文献
445.
Mohammed A. Khairy Marit Kolb Christiane Schmidt Dieter W. Zachmann Alaa R. Mostafa Anwar A. EL‐Fiky Müfit Bahadir 《洁净——土壤、空气、水》2011,39(3):301-312
Sediment samples were collected from 30 different locations in Abu Qir Bay (Mediterranean Sea), East Alexandria, Egypt and analyzed for trace elements. The highest concentrations of most of the elements were observed in the nearshore stations in the vicinity of the major anthropogenic activities as industrial settlements, wastewater discharges, and agricultural drainage. In addition, mussel samples of Mactra corallina and Tapes decussata were collected corresponding to the sediment samples. Concentrations of As, Cd, Cr, Mn, and Zn in the mussel tissues were higher than concentrations in sediments, thus indicating their relatively high bioavailability. Sequential extraction procedure was performed on selected sediment samples. Significant correlations were observed between the concentrations of Cu, Mn, Pb, and Zn in the exchangeable fraction of the sediments and the corresponding tissues of M. corallina. The output of the risk assessment applied on the sediments revealed that adverse ecological effects to benthic species could occur and that a higher level of risk is expected from the exposure to Cd, Cr, Hg, and Zn. No adverse carcinogenic or non‐carcinogenic human health effects are expected from the consumption of the two mussel species from Abu Qir Bay. 相似文献
446.
Jörg Geldmacher Karsten M. Haase Colin W. Devey C. Dieter Garbe-Schönberg 《Contributions to Mineralogy and Petrology》1998,131(2-3):196-209
Abundant cone sheets form one of the last magmatic stages in the Tertiary central complex on the Scottish peninsula of Ardnamurchan
and can be grouped into a younger inner and an older outer suite relative to a gabbro intrusion. Most of the cone-sheets consist
of tholeiitic to transitional basalt with MgO contents between 7.5% and 4%, although more evolved rocks also occur (to 0.5%
MgO). The mafic samples are slightly enriched in the light rare earth elements (Chondrite-normalized La/Sm ∼1.1), the enrichment
increases in the more evolved rocks. The compositional variation of the basaltic rocks is mainly due to crystal fractionation
of olivine and clinopyroxene at depths of ∼10 km but trace elements show simultaneous assimilation of Archean Lewisian granulite
crust. The andesitic to rhyolitic lavas formed by fractional crystallization from the contaminated basaltic magma coupled
with assimilation of Proterozoic Moine metasediments at uppermost crustal levels. The occurrence of composite cone-sheets
with basaltic and rhyolitic parts and mixtures between these magmas implies that the melts ascended successively but within
a short period of time. The parental magmas of the Ardnamurchan cone-sheets must have formed at relatively shallow depths
in the mantle and are comparable to the youngest tholeiitic lavas from the neighbouring island of Mull.
Received: 5 June 1997 / Accepted: 12 November 1997 相似文献