Time-scales of recent Phlegrean Fields eruptions inferred from the application of a ‘diffusive fractionation’ model of trace elements

The variation of chemical element compositions in two pyroclastic sequences (Astroni 6 and Averno 2, Phlegrean Fields, Italy) is studied. Both sequences are compositionally zoned indicating a variability of melt compositions in the magma chamber prior to eruption. A clear dichotomy between the behaviour of major vs. trace elements is also observed in both sequences, with major elements displaying nearly linear inter-elemental trends and trace elements showing a variable scattered behaviour. Together with previous petrological investigations these observations are consistent with the hypothesis that magma mixing processes played a key role in the evolution of these two magmatic systems. Recently it has been suggested that mixing processes in igneous systems may strongly influence the mobility of trace elements inducing a ‘diffusive fractionation’ phenomenon, whose extent depends on the mixing time-scale. Here we merge information from 1) numerical simulations of magma mixing, and 2) magma mixing experiments (using as end-members natural compositions from Phlegrean Fields) to derive a relationship relating the degree of ‘diffusive fractionation’ to the mixing time-scales. Application of the ‘diffusive fractionation’ model to the two studied pyroclastic sequences allowed us to apply the relationship derived by numerical simulations and experiments to estimate the mixing time-scales for these two magmatic systems. Results indicate that mixing processes in Astroni 6 and Averno 2 systems lasted for approximately 2 and 9 days, respectively, prior to eruption.     

Evaluation of Soil Re-mineralizer from By-Product of Volcanic Rock Mining: Experimental Proof Using Black Oats and Maize Crops

Natural Resources Research - This study was focused on physical, petrographical, mineralogical, and chemical characterization of a volcanic-rock mining by-product (dacite rock), as well as on...     

Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)

Volumetrically minor microsyenites, alkali microgranite and related trachytic dykes intrude early Pliocene OIB-like alkali basaltic and basanitic flows of the Meseta del Lago Buenos Aires in Central Patagonia (47°S–71°30′W), and occur together with scarce trachytic lava flows. Whole-rock K–Ar ages between 3.98 and 3.08 Ma indicate that the emplacement of these felsic rocks occurred more or less synchronously with that of the post-plateau basaltic sequence that they intrude, during a bimodal mafic–felsic magmatic episode devoid of intermediate compositions. Chemically, these rocks have A₁-type granitoid affinities and are characterized by high silica and alkali contents (60–68 wt.% SiO₂; 8.7–10.8 wt.% Na₂O + K₂O), major and trace elements patterns evidencing evolution by low-pressure fractional crystallization, and Sr and Nd isotopic signatures similar to those of coeval basalts ((⁸⁷Sr/⁸⁶Sr)_o = 0.70488–0.70571; (¹⁴³Nd/¹⁴⁴Nd)_o = 0.512603–0.512645). Nevertheless, some of them have the most radiogenic Sr values ever reported for a magmatic rock in the Meseta and even in the whole Neogene Patagonian Plateau Lavas province ((⁸⁷Sr/⁸⁶Sr)_o = 0.70556–0.70571; (¹⁴³Nd/¹⁴⁴Nd)_o = 0.512603–0.512608). In addition, very high contents of strongly incompatible elements in the most evolved rocks, together with Sr isotopic ratios higher than those of coeval basalts, suggest the occurrence of open-system magmatic processes. Continuous fractional crystallization from a primitive basaltic source, similar to post-plateau coeval basalts, towards alkali granites combined with small rates of assimilation of host Jurassic tuffs (AFC) in a shallow magmatic reservoir, best explains the geochemical and petrographic features of the felsic rocks. Therefore, A₁-type magmatic rocks can be generated by open-system crystallization of deep asthenospheric melts in back-arc tectonic settings.

In Central Patagonia, these  3–4 Ma old alkaline intrusions occur aligned along a  N160–170 trending lineament, the Zeballos Fault Zone, stacking the morphotectonic front of one segment of the Patagonian Cordillera. Intrusion along this fault zone occurred during the onset of a new transtensional or extensional event in the area, related to major regional tectonics occurring in possible relation with the collision of one segment of the Chile Spreading Ridge with the trench.     

The importance of and need for rapid hydrologic assessments in Latin America

Long‐term observations are critical in hydrology to understand the dynamics of biological and physicochemical processes involved in and affected by the flux of water. Long‐term observations have been employed to provide basic understanding of the water cycle (e.g., infiltration, evaporation, run‐off generation, and groundwater–surface water interactions), but they are lacking in hydrologically relevant regions such as the Andes Mountains, including alpine watersheds. Although the call for long‐term data acquisition in Latin America has been made, the establishment of long‐term data collection centres remains logistically challenging. This ever‐growing scientific gap hinders our understanding of differences and similarities in hydrological processes of tropical and temperate regions. Furthermore, technological advances such as in situ optical sensors for water quantity and quality remain cost‐prohibitive for both short and long deployment at most existing research sites in Latin America, restricting researchers pursuing research funding or developing meaningful, intersite comparisons and syntheses. Here, we emphasize the importance of and need for rapid assessments (i.e., field campaigns conducted over a few days) for improved hypothesis development and mechanistic understanding of hydrological dynamics in Latin America. We report on rapid assessments conducted in the high‐elevation mountains (>3,000 m) of Colombia. Our results highlight rapidly changing dynamics in nutrient retention potential and dissolved CO₂ (pCO₂), as well as highly variable spatial distribution of water quality parameters (N, C, P, Cl) in areas with varying land use. We present an initial examination of the effects of land‐use change on stream nutrient dynamics in one of the most biodiverse and threatened ecosystems on Earth. We conclude that rapid assessments not only are necessary but also represent a cost‐effective way to develop clear, testable hypotheses to advance a hydrologic research agenda in Latin America and work towards long‐term hydrological knowledge and information for use by other scientists.     

Sedimentary processes and provenance of Quaternary marine formations from the Tangier Peninsula (Northern Rif, Morocco)

This work deals with new lithostratigraphic, sedimentological, petrographic and geochemical data collected from coastal Quaternary formations of the Tangier Peninsula along the Northern Atlantic and Mediterranean coasts in the southern side of the Gibraltar Strait (Morocco).The sedimentological features of the analyzed sections reflect a palaeoenvironment evolution from a submerged beach-type to a high energy littoral depositional system, namely lower shoreface to beachface environment with a regressive trend to thickening- and coarsening-upward sequences. Other successions, located nearby Larache city and in the Sidi Kankouch area, are also characterized by a positive trend to fining- and thinning-upward sequences, reflecting an evolution from lower beachface or upper shoreface to lower shoreface. It is possible that the transgressive to regressive trend inversion could be related to fluctuations of sediment input rate versus accommodation space during the progradation of a coastal palaeoenvironment.The lateral and vertical evolution of the studied marine formations is related to late Quaternary neotectonics, mainly to the last repercussions of isostatic rebound of the External and Flysch Basin Domains, during a period of relatively uniform sea level between 280,000 and 125,000 years B.P.The provenance of arenites of these Quaternary marine formations, studied by means of modal counting and geochemical analysis, seems to be linked mainly to Middle-Upper Miocene and Pliocene terrigenous successions, unconformably resting on various formations of the Neogene accretionary prism. The latter has been built by the stacking of Flysch Nappes and External Units of the Northern Rif Chain.     

Stratigraphy and formation processes of the Upper Pleistocene deposit at Gruta da Oliveira,Almonda karstic system,Torres Novas,Portugal

Gruta da Oliveira is a cave located in the Almonda karstic system in central Portugal. Its Upper Pleistocene fill is made up of gravitational sediments with varied biogenic and anthropogenic inputs. The archaeological sequence (35–70 ka) is fairly homogeneous, reflecting a predominantly moist climatic context modulated by millennial‐scale variations. Human occupation was almost continuous throughout. In the richer archaeological layers (8–14), the anthropogenic components are in primary position, and post‐depositional processes are restricted, although penecontemporaneous biological activity—such as hyena scavenging—overprinted the record. In layers 15–19, the excavated area corresponds to the footslope of a talus, where accumulation proceeded mainly through runoff and where the lithics and bones derive from occupations situated ca. 5m outward. The base of the deposit is >2m from the current base of the excavation, suggesting that Oxygen Isotope Stage (OIS)‐4 and OIS‐5 sediments underlay the deposit already exposed. This study confirms the archaeological integrity of the Mousterian assemblages found in the different layers, and, given the dates for layer 8, supports the hypothesis that Neanderthals survived in western Iberia until at least 35,000–38,000 calendar years ago. © 2009 Wiley Periodicals, Inc.     

Speleothem and glacier records of latest Pleistocene–early Holocene climate change in the western North American interior

Rapid and high-magnitude North Atlantic climate oscillations following the Last Glacial Maximum have been correlated to climate change events in western North America. However, the strength of teleconnections between the North Atlantic and the interior of western North America remains poorly understood. We present a U-series calibrated speleothem record from Timpanogos Cave National Monument, located at 2040 m asl in the Wasatch Mountains of Utah, spanning 13.5–10.6 ka. Additionally, we carried out a climate reconstruction for a coeval glacier advance in the Wind River Range of Wyoming. Our results indicate that between 13.5 and 12.8 ka, the Wasatch was probably first cool and dry and then warmed. After 12.8 ka, our record suggests cool and/or wetter conditions followed by reduced moisture until 11.8 ka, followed by an early Holocene wet period. The Timpanogos record exhibits few similarities with those from the North Atlantic. Climate reconstructions of the Titcomb Basin glacier suggest modest temperature depressions relative to modern (<−3 °C) were necessary to sustain the glacier with a moderate increase in precipitation (>150%). The high-altitude speleothem record presented here provides a valuable basis for understanding latest Pleistocene–early Holocene glacial episodes in western North America.     

Pingüino In-bearing polymetallic vein deposit,Deseado Massif,Patagonia, Argentina: characteristics of mineralization and ore-forming fluids

The Pingüino deposit, located in the low sulfidation epithermal metallogenetical province of the Deseado Massif, Patagonia, Argentina, represents a distinct deposit type in the region. It evolved through two different mineralization events: an early In-bearing polymetallic event that introduced In, Zn, Pb, Ag, Cd, Au, As, Cu, Sn, W and Bi represented by complex sulfide mineralogy, and a late Ag–Au quartz-rich vein type that crosscut and overprints the early polymetallic mineralization. The indium-bearing polymetallic mineralization developed in three stages: an early Cu–Au–In–As–Sn–W–Bi stage (Ps₁), a Zn–Pb–Ag–In–Cd–Sb stage (Ps₂) and a late Zn–In–Cd (Ps₃). Indium concentrations in the polymetallic veins show a wide range (3.4 to 1,184 ppm In). The highest indium values (up to 1,184 ppm) relate to the Ps₂ mineralization stage, and are associated with Fe-rich sphalerites, although significant In enrichment (up to 159 ppm) is also present in the Ps₁ paragenesis associated with Sn-minerals (ferrokesterite and cassiterite). The hydrothermal alteration associated with the polymetallic mineralization is characterized by advanced argillic alteration within the immediate vein zone, and sericitic alteration enveloping the vein zone. Fluid inclusion studies indicate homogenisation temperatures of 308.2–327°C for Ps₁ and 255–312.4°C for Ps₂, and low to moderate salinities (2 to 5 eq.wt.% NaCl and 4 to 9 eq.wt.% NaCl, respectively). δ³⁴S values of sulfide minerals (+0.76‰ to +3.61‰) indicate a possible magmatic source for the sulfur in the polymetallic mineralization while Pb isotope ratios for the sulfides and magmatic rocks (²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of 17.379 to 18.502; 15.588 to 15.730 and 38.234 to 38.756, respectively) are consistent with the possibility that the Pb reservoirs for both had the same crustal source. Spatial relationships, hydrothermal alteration styles, S and Pb isotopic data suggest a probable genetic relation between the polymetallic mineralization and dioritic intrusions that could have been the source of metals and hydrothermal fluids. Mineralization paragenesis, alteration mineralogy, geochemical signatures, fluid inclusion data and isotopic data, confirm that the In-bearing polymetallic mineralization from Pingüino deposit is a distinct type, in comparison with the well-known epithermal low sulfidation mineralization from the Deseado Massif.