On the crystal structure and compressional behavior of talc: a mineral of interest in petrology and material science

The crystal structure of a natural triclinic talc (1Tc polytype) [with composition: (Mg_2.93Fe_0.06)_Σ2.99(Al_0.02Si_3.97)_Σ3.99O₁₀(OH)_2.10] has been investigated by single-crystal X-ray diffraction at 223 and 170 K and by single-crystal neutron diffraction at 20 K. Both the anisotropic X-ray refinements (i.e. at 223 and 170 K) show that the two independent tetrahedra are only slightly distorted. For the two independent Mg-octahedra, the bond distances between cation-hydroxyl groups are significantly shorter than the others. The ditrigonal rotation angle of the six-membered ring of tetrahedra is modest (α ~ 4°). The neutron structure refinement shows that the hydrogen-bonding scheme in talc consists of one donor site and three acceptors (i.e. trifurcated configuration), all the bonds having O···O ≤ 3.38 Å, H···O ~ 2.8 Å, and O–H···O ~ 111–116°. The three acceptors belong to the six-membered ring of tetrahedra juxtaposed to the octahedral sheet. The vibrational regime of the proton site appears being only slightly anisotropic. The elastic behavior of talc was investigated by means of in situ synchrotron single-crystal diffraction up to 16 GPa (at room temperature) using a diamond anvil cell. No evidence of phase transition has been observed within the pressure range investigated. P–V data fit, with an isothermal third-order Birch-Murnaghan equation of state, results as follows: V ₀ = 454.7(10) Å³, K _T0 = 56(3) GPa, and K′ = 5.4(7). The “Eulerian finite strain” versus “normalized stress” plot yields: Fe(0) = 56(2) GPa and K′ = 5.3(5). The compressional behavior of talc is strongly anisotropic, as reflected by the axial compressibilities (i.e. β(a):β(b):β(c) = 1.03:1:3.15) as well as by the magnitude and orientation of the unit-strain ellipsoid (with ε ₁:ε ₂:ε ₃ = 1:1.37:3.21). A comparison between the elastic parameters of talc obtained in this study with those previously reported is carried out.     

Waste rock dump investigation at Roşia Montană gold mine (Romania): a geostatistical approach

Ro?ia Montan?, the largest European gold mine, could be re-opened. Environmental problems led to severe pollution of the Ro?ia and Abrud Rivers. The two main potentially toxic element (PTE) sources in mine sites are, in general, the abandoned underground workings and the piles of waste rock. Since the composition of waste rocks is often heterogeneous, this study faces the problem of estimating their mineralogical and chemical features starting from a set of sampling point. Twenty-five samples were collected on the main waste dump of the Ro?ia Montan? mine following a virtual squared grid (knots distance about 25 m). Grain size, color, bulk chemistry, mineralogy, acid mine drainage potential and a set of selected PTE (Ag, As, Cu, Ni, Pb and Zn) concentrations were determined on each sample. In a first approximation two main waste rock groups were identified: WR1 bulk composition is dacite-dominated, while WR2 is andesite-dominated. In both of them the concentrations of PTEs are below the regulatory limits for soils, with the exception of As. In terms of acid mine drainage, WR1 has a net acid-producing potential, while WR2 has a net neutralizing potential. The anisotropy of WR properties were analysed by means of semi-variograms and displayed with contour maps. Application of positive matrix factorization for the analysis of all the data relative to waste rocks allowed defining, in a semi-quantitative way, the factors controlling pollution and their spatial distribution. The processing of score matrix G factor associated with the geostatistical elaboration promises to be a powerful tool to discern the composition of mine dumps and support the exploitation and remediation phases.     

Relativistic positioning: four-dimensional numerical approach in Minkowski space-time

We simulate the satellite constellations of two Global Navigation Satellite Systems: Galileo (EU) and GPS (USA). Satellite motions are described in the Schwarzschild space-time produced by an idealized spherically symmetric non rotating Earth. The trajectories are then circumferences centered at the same point as Earth. Photon motions are described in Minkowski space-time, where there is a well known relation, (Coll et al. in Class. Quantum Gravit. 27:065013, 2010a), between the emission and inertial coordinates of any event. Here, this relation is implemented in a numerical code, which is tested and applied. The first application is a detailed numerical four-dimensional analysis of the so-called emission coordinate region and co-region. In a second application, a GPS (Galileo) satellite is considered as the receiver and its emission coordinates are given by four Galileo (GPS) satellites. The bifurcation problem (double localization) in the positioning of the receiver satellite is then pointed out and discussed in detail.     

Analysis of lateral loading of pile groups using embedded beam elements with interaction surface

The numerical simulation of soil-pile interaction problems, by means of full 3D finite element models, involves a large number of degrees of freedom (DOF) and difficulties during the mesh generation process. In order to reduce the unknowns and simplify and properly analyze such class of geotechnical problems, the so-called embedded beam elements (EBE) have recently been developed. In a preceding contribution of the authors, an improved EBE formulation, which brings into play the soil-pile interaction surface, was proposed with the aim to localize material plasticity in the soil surrounding the pile. This embedded beam model couples two different finite elements, each described by distinct kinematics (ie, solid and beam). The coupling is incorporated in the formulation by means of kinematical constrains established over the solid and beam displacement fields on the interaction surface. One of the main advantages of the embedded elements is that the addition of beams structural members immersed within the 3D soil model does not represent a constraint for the solid mesh, which can be adopted independently from the beam mesh. In this paper, the lateral loading of pile groups is studied by means of the proposed EBE approach with elasto-plastic interfaces. In order to represent a rigid cap, a master node and a special set of kinematical restrictions are incorporated into the formulation. The paper presents results obtained by means of the present formulation compared against other well-established analysis methods and test results published in the literature, for both elastic and elasto-plastic cases.     

From cave geomorphology to Palaeolithic human behaviour: speleogenesis,palaeoenvironmental changes and archaeological insight in the Atxurra-Armiña cave (northern Iberian Peninsula)

A detailed geomorphological study was performed in the Atxurra-Armiña cave system (northern Iberian Peninsula) to decode landscape evolution, palaeoenvironmental changes and human use of a cave within an Inner Archaeological Context. The results show an average incision rate of the river of <0.083 mm a^–1 for at least the last 419 ka, with interruptions due to sedimentary inputs. Moreover, allostratigraphic units comprising fluviokarstic deposits at the base and flowstone formation at the top have been shown to be climatically controlled, formed either during glacial–interglacial cycles or during interstadial cycles. Finally, when the cave was used by humans in the Late Magdalenian, the lower entrance was closed, and they must therefore have entered the cave through the upper entrance. To reach the sectors selected to decorate the panels, they probably travelled from the upper cave level, as the current crawlway was wider than today, according to our U/Th dating. Once these visitors reached the panels, the floor in the main gallery would have been around 15 cm lower than at present. However, the morphology of the conduit was similar; this has significant implications for understanding and interpreting the human use of the cave during the Palaeolithic.     

Patterns of sea surface temperature variability on seasonal to sub-annual scales at and offshore the Río de la Plata estuary

SST variability on seasonal to sub-annual scales in the coastal region of South America between 30° and 39°S, largely influenced by the Rio de la Plata estuary’s plume, and its relation to wind variability are explored. Data are six years of daily ensembles of gridded satellite SST and sea surface winds with spatial resolutions of about 11 and 25 km, respectively. Observations from oceanographic cruises are used to validate the results. It is found that the seasonal cycle can be explained in terms of two modes. The first one, characterizing fall-early winter/spring-early summer, is related to the radiative cycle. The second one, corresponding to late summer and winter, displays warm/cold anomalies along the Uruguayan coast forced by the prevailing winds during those seasons. In the upper estuary and the northern part of the area of influence of the freshwater plume, variability in sub-annual scales is significant. A large portion of this variance is related to zonal wind anomalies that force warm/cold SSTs along that coast. Cold anomalies of up to −5 °C occur under anomalously intense easterly winds, indicating upwelling. These events are very frequent and show large persistence, occurring up to one and a half months. They also display a marked seasonal cycle – being more frequent in late spring and summer – large inter-annual variability and seem to be modulated by the continental runoff. When discharge is low, the freshwater plume retracts to the west, reducing the inner-shelf stratification and increasing the likelihood of a full upwelling to the surface. In winter, short time-scale SST variability is mostly due to variability in the atmospheric cold fronts crossing the region. Weaker or less frequent (stronger or more frequent) fronts produce a generalized warming (cooling) over the region. As the estuary heats (colds) faster than the shelf, a warm (cold) anomaly develops in the upper Río de la Plata. On inter-annual time scales, probably because ENSO activity was weak during the studied period, SST variability was not important.     

Composition,pre-eruptive zonation,and geochronologic significance of the ∼450 ka Diamante Tuff,Andean Cordillera (34°S), Argentina

Vertical geochemical sampling through the Diamante Tuff establishes patterns of zonation in the pre-eruption magma. Volcanic glass demonstrates a roofward increase in Fe and Cl, and a roofward decrease in Ca. Trace elements have no measurable zonation. Welded volcanic glass shows post-eruption loss of Fe, Mg and Cl as well as K gain. Our reported glass chemistry provides robust criteria for correlation to other localities. The Diamante Tuff is an important stratigraphic marker and recognition of this unit provides age control on Quaternary deposits, allowing determination of process rates and elucidating timing of tectonic and geomorphic activity.     

Multi‐objective risk‐informed design of floor isolation systems

The design of floor isolation systems (FISs) for the protection of acceleration sensitive contents is examined considering multiple objectives, all quantified in terms of the probabilistic system performance. The competing objectives considered correspond to (i) maximization of the level of protection offered to the sensitive content (acceleration reduction) and (ii) minimization of the demand for the isolator displacement capacity and, more importantly, for the appropriate clearance to avoid collisions with surrounding objects (floor displacement reduction). Both of these objectives are probabilistically characterized utilizing a versatile, simulation‐based framework for quantifying seismic risk, addressing all important uncertainties related to the seismic hazard and the structural model. FIS performance is assessed through time‐history analysis, allowing for all important sources of nonlinearity to be directly addressed in the design framework. The seismic hazard is described through a stochastic ground motion model. For efficiently performing the multi‐objective optimization, an augmented surrogate modeling methodology is established, considering development of a single metamodel with respect to both the uncertain model parameters and the design variables for the FIS system. This surrogate model is then utilized to simultaneously support the probabilistic risk assessment and the design optimization to provide the Pareto front of dominant designs. Each of these designs establishes a different compromise between the considered risk‐related objectives offering a variety of potential options to the designer. Within the illustrative example, the efficiency of the established framework is exploited to compare three different FIS implementations, whereas the impact of structural uncertainties on the optimal design is also evaluated. Copyright © 2016 John Wiley & Sons, Ltd.