Nanomineralogy of evaporative precipitation of efflorescent compounds from coal mine drainage

Efflorescent nanophases(NPs)are found as a transitory accumulation of potentially hazardous elements(PHEs),particularly in tropical climates.The central objective of this study was to investigate the distribution of PHEs with NPs through the evaporative formation structures(EFS)of enormously PHEs-rich coal-mine drainages(CMD).The EFS were studied in natural coal mine drainage for five months in order to determine their geochemical and ecological structures and to assess their position in the reduction of PHEs in nature.The largest coal-fired power plant in South America,located in south Brazil,is used as an example of such a problem.In this work,a novel methodology for the analysis of PHEs in CMD precipitates is proposed for this affected coal area.The analytical method,combining X-Ray Diffraction(XRD)and advanced electron microscopies,shows the importance of nanomineralogy in understanding different circumstances of coal contamination.Several ultrafine-nanoparticles(UNPs)were identified in the sampled soils and river sediments together with the PHEs.A decrease in PHEs was identified in association with UNPs.However,further investigations are required with regard to the mobility of PHEs in water,atmosphere,soils,and sediments.The EPS was thoroughly studied,acquiring suitable understanding with investigational facts for Ca and Fe-sulphates,pickeringite,and several amorphous phases.     

The Santa Filomena meteorite shower: Trajectory,classification, and opaque phases as indicators of metamorphic conditions

On August 19, 2020, at 13:18—UTC, a meteor event ended as a meteorite shower in Santa Filomena, a city in the Pernambuco State, northeast Brazil. The heliocentric orbital parameters resulting from images by cameras of the weather broadcasting system were semimajor axis a = 2.1 ± 0.1 au, eccentricity e = 0.55 ± 0.03, and inclination i = 0.15^o ± 0.05. The data identified the body as an Apollo object, an Earth-crossing object with a pericenter interior to the Earth's orbit. The chemical, mineralogical, and petrological evaluations, as well as the physical analysis, followed several traditional techniques. The meteorite was identified as a H5-6 S4 W0 ordinary chondrite genomict breccia. The large amount of metal in the meteorite made a metallographic evaluation based on the opaque phases possible. The monocrystalline kamacite crystals suggest a higher petrological type and the distorted Neumann lines imply at least two different shock events. The absence of the plessite phase shows that the meteorite did not reach the highest shock levels S5 and S6. The well-defined polycrystalline taenite is indicative of petrologic types 4 and 5 due to the conserved internal tetrataenite rim at the boundaries. The presence of polycrystalline taenites and the characteristics of the Agrell Effect suggest that the Santa Filomena meteorite did not reheat above 700°C. The absence of martensite confirms reheating temperatures <800°C and a slow cooling rate. The Ni contents and sizes of the zoned taenite particles indicate a slow cooling rate ranging from 1 to 10 K Myr⁻¹.     

Same Disease—different research strategies: Bananas and Black Sigatoka in Brazil and Colombia

Fungal disease epidemics have the potential to bring about drastic innovations. However, in the case of the Black Sigatoka (Mycosphaerella fijiensis) fungus in bananas, producers and international traders are still awaiting a breakthrough in crop protection research. Using the cases of Brazil and Colombia, this paper examines different agricultural research responses to the disease. Brazil opted to replace susceptible varieties with resistant ones, whereas in Colombia chemical control by private actors dominated. We argue that these different responses result from at least three interrelated factors. First, producer type—smallholder farmers or larger export‐oriented plantations—influences the setting of crop protection research priorities. Second, a central, state‐led role versus a private sector response influences the size and time perspective of research activities. Third, domestic markets with multiple crop varieties versus Cavendish‐only export markets leads to differences in control practices and research responses. From this case study, we argue that the currently proposed innovation systems approaches in international agricultural research should adopt a broader perspective that assesses how research is interwoven with agrarian dynamics, commodity chains and particular state roles to elucidate how state–producer–researcher networks perform disease control and where and how to find new solutions.     

Prediction of piezometric surfaces and drain spacing for horizontal drain design

Horizontal drains, used independently or as part of a more complex remediation scheme, are frequently installed to mitigate the effects of increased groundwater in slope stabilization projects. Due to a general trial and error approach to their design, the need for improved design practices has been recognized. The procedures established by Crenshaw and Santi in 2004 made some advances in this direction, but did not account for slopes with drains that were not horizontal or for sloping low-permeability layers underneath the slide mass. Furthermore, the method outlined by Crenshaw and Santi is time-consuming and requires some trial and error calculations to achieve convergence. Therefore, the method has been modified to account for nonhorizontal elements, and a horizontal drain spreadsheet has been developed to streamline the design for projects where horizontal drains will be installed. The horizontal drain spreadsheet may be used to: (1) predict a conservative piezometric profile in a drained slope for use in slope stability analyses, (2) predict piezometric heads in any single piezometer in a drainage field, and (3) predict drain spacing for design purposes. This document explains the revisions to Crenshaw and Santi’s procedures and provides instructions for applying the method. The instructions may be used for hand calculations, but are specifically intended for use with the horizontal drain spreadsheet. The spreadsheet may be used for slopes composed of silty or clayey sands, silts, and silty or sandy clays.     

Connectivity and single/dual domain transport models: tests on a point-bar/channel aquifer analogue

In porous aquifers, groundwater flow and solute transport strongly depend on the sedimentary facies distribution at fine scale, which determines the heterogeneity of the conductivity field; in particular, connected permeable sediments could form preferential flow paths. Therefore, properly defined statistics, e.g. total and intrinsic facies connectivity, should be correlated with transport features. In order to improve the assessment of the relevance of this relationship, some tests are conducted on two ensembles of equiprobable realizations, obtained with two different geostatistical simulation methods—sequential indicator simulation and multiple point simulation (MPS)—from the same dataset, which refers to an aquifer analogue of sediments deposited in a fluvial point-bar/channel association. The ensembles show different features; simulations with MPS are more structured and characterised by preferential flow paths. This is confirmed by the analysis of transport connectivities and by the interpretation of data from numerical experiments of conservative solute transport with single and dual domain models. The use of two ensembles permits (1) previous results obtained for single realizations to be consolidated on a more firm statistical basis and (2) the application of principal component analysis to assess which quantities are statistically the most relevant for the relationship between connectivity indicators and flow and transport properties.     

Selective separation of very fine particles at a planar air–water interface

Selective fine particle separation is a key unit operation in the mineral and related industries. In flotation, the capture of fine particles by bubbles is inefficient due to their low mass and momentum, which result in low particle–bubble collision efficiency. We demonstrate that it is possible to selectively separate a mixture of very fine hydrophobic graphite and hydrophilic quartz particles by direct contact with an air–water interface without a particle–bubble collision step involved. We demonstrate that it is possible to scale-up the process from a simple batch to a continuous process. Good selective separation of graphite from quartz gangue could be obtained under continuous conditions.     

Parameterization of snow-free land surface albedo as a function of vegetation phenology based on MODIS data and applied in climate modelling

The aim of this study was to develop an advanced parameterization of the snow-free land surface albedo for climate modelling describing the temporal variation of surface albedo as a function of vegetation phenology on a monthly time scale. To estimate the effect of vegetation phenology on snow-free land surface albedo, remotely sensed data products from the Moderate-Resolution Imaging Spectroradiometer (MODIS) on board the NASA Terra platform measured during 2001 to 2004 are used. The snow-free surface albedo variability is determined by the optical contrast between the vegetation canopy and the underlying soil surface. The MODIS products of the white-sky albedo for total shortwave broad bands and the fraction of absorbed photosynthetically active radiation (FPAR) are analysed to separate the vegetation canopy albedo from the underlying soil albedo. Global maps of pure soil albedo and pure vegetation albedo are derived on a 0.5° regular latitude/longitude grid, re-sampling the high-resolution information from remote sensing-measured pixel level to the model grid scale and filling up gaps from the satellite data. These global maps show that in the northern and mid-latitudes soils are mostly darker than vegetation, whereas in the lower latitudes, especially in semi-deserts, soil albedo is mostly higher than vegetation albedo. The separated soil and vegetation albedo can be applied to compute the annual surface albedo cycle from monthly varying leaf area index. This parameterization is especially designed for the land surface scheme of the regional climate model REMO and the global climate model ECHAM5, but can easily be integrated into the land surface schemes of other regional and global climate models.     

Parametrization of peatland hydraulic properties for the Canadian land surface scheme

Abstract

A hydraulic parametrization is developed for peatland environments in the Canadian Land Surface Scheme (CLASS). Three ‐wetland soil classes account for the typical variation in the hydraulic characteristics of the uppermost 0.5 m of organic soils. Review of the literature reveals that saturated hydraulic conductivity varies from a median of 1.0 × 10^?7m/s in deeply humified sapric peat to 2.8 × 10^?4 m/s in relatively undecomposed fibric peat. Average pore volume fraction ranges from 0.83 to 0.93. Parameters have been designed for the soil moisture characteristic curves for fibric, hemic and sapric peat using the Campbell (1974) equation employed in CLASS, and the van Genuchten (1980) formulation. There is little difference in modelled soil moisture between the two formulations within the range of conditions normally found in peatlands. Validation of modelled water table depth and peat temperature is performed for a fen in northern Québec and a bog in north‐central Minnesota. The new parametrization results in a more realistic simulation of these variables in peatlands than the previous version of CLASS, in which unrealistic mineral soil “equivalents “ were used for wetland soil climate modelling.