Higher plant vegetation changes during Pliocene sapropel formation

The δ¹³C values of higher plant wax C_27–33 n-alkanes were determined in three, time-equivalent Pliocene (2.943 Ma) sapropels and homogeneous calcareous ooze from three different sites forming an east-west transect in the eastern Mediterranean Basin in order to study the composition of the vegetation on the continents surrounding the Mediterranean Sea. A two-end member mixing model transformed the measured δ¹³C values into the contribution of C₄ plants to the terrestrial vegetation. These calculations indicated a high C₄ plant contribution (i.e. 40–50%) in the periods just before and just after sapropel formation. During sapropel deposition the C₄ plant contribution increased by up to 20% at all sites. This is interpreted to record the increased overall plant coverage of the Mediterranean borderlands resulting from the change in formerly barren desert areas into C₄ grass-dominated savannahs as a response to the wetter climate during sapropel deposition. Enhanced accumulation rates (ARs) of long-chain n-alkanes (C_27–33) and n-alkan-1-ols (C_26–30) towards the middle of the sapropel in concert with a decrease in the Ti/Al ratio confirm an increased delivery of terrigenous organic matter at all sites. These biomarkers were probably predominantly fluvially transported to the Mediterranean Sea, not only by the Nile but by fossil wadi river systems on the northern African continent.     

Mechanistic and Kinetic Study of the Gas-Phase Reaction of Atomic Chlorine with Cyclohexanone using an Absolute and a Relative Technique; Influence of Temperature

The reaction of Cl with cyclohexanone (1) was investigated, for the first time, as a function of temperature (273–333 K) and at a low total pressure (1 Torr) with helium as a carrier gas using a discharge flow-mass spectrometry technique (DF-MS). The resulting Arrhenius expression is proposed, k ₁= (7.7 ± 4.1) × 10^–10 exp[–(540 ± 169)/T]. We also report a mechanistic study with the quantitative determination of the products of the reaction of Cl with cyclohexanone. The absolute rate constant derived from this study at 1 Torr of total pressure and room temperature is (1.3 ± 0.2) × 10^–10 cm³ molecule^–1 s^–1. A yield of 0.94 ± 0.10 was found for the H-abstraction channel giving HCl. In relative studies, using a newly constructed relative rate system, the decay of cyclohexanone was followed by gas chromatography coupled with flame-ionisation detection. These relative measurements were performed at atmospheric pressure with synthetic air and room temperature. Rate constant measured using the relative method for reaction (1) is: (1.7 ± 0.3) × 10^–10 cm³ molecule^–1 s^–1. Finally, results and atmospheric implications are discussed and compared with the reactivity with OH radicals.     

Modelling Carbon Dynamics of Boreal Forest Ecosystems Using the Canadian Land Surface Scheme

The ecosystem carbon (C) and nitrogen (N) simulations recently implemented in the Canadian Land Surface Scheme (CLASS) are presented. The main calculations include plant photosynthesis, autotrophic respiration, root N uptake, litterfall, plant growth, and soil heterotrophic respiration. Model experiments are made on two boreal forest ecosystems, deciduous (aspen) and conifers (black spruce). Simulated plant, soil, and ecosystem CO₂ exchanges are analysed on half-hourly, daily, and annual time scales and compared with tower eddy correlation flux measurements and estimates from various authors. Modeled daily ecosystem CO₂ exchange explained86% and 54%, respectively, of the observed variance of eddy correlationflux at the aspen site and at the black spruce site. Annual results show that the aspen ecosystem was simulated as a C sink in both 1994 (+164 g Cm^–2) and 1996 (+142 g C m^–2), and the black spruce ecosystem wassimulated as a C sink in 1994 (+39 g C m^–2) and 1995 (+25 g Cm^–2), but as a C source in 1996 (–27 g C m^–2).     

The abundance of volatiles in Hawaiian tholeiitic submarine basalts

High-temperature mass spectrometric studies have been made to determine the distribution of volatiles within glassy rims of submarine pillow basalts dredged from the east rift zone of Kilauea volcano, Hawaii. The CO₂/H₂O mole ratio for glass-vapor inclusions within olivine phenocrysts in the glassy rims is greater than 30 : 1 compared to 0.06 for matrix glasses. Enclosing matrix glasses contain 0.53–0.74 wt.% H₂O, 0.02–0.04 wt.% carbon, 0.08–0.12 wt.% sulfur, 0.012–0.028 wt.% chlorine and 0.012–0.077 wt.% fluorine.     

Modified treatment of intercepted snow improves the simulated forest albedo in the Canadian Land Surface Scheme

The Canadian Land Surface Scheme (CLASS) was modified to correct an underestimation of the winter albedo in evergreen needleleaf forests. Default values for the visible and near‐infrared albedo of a canopy with intercepted snow, α_VIS,cs and α_NIR,cs, respectively, were too small, and the fraction of the canopy covered with snow, f_snow, increased too slowly with interception, producing a damped albedo response. A new model for f_snow is based on z_I*, the effective depth of newly intercepted snow required to increase the canopy albedo to its maximum, which corresponds in the model with f_snow = 1. Snow unloading rates were extracted from visual assessments of photographs and modelled based on relationships with meteorological variables, replacing the time‐based method employed in CLASS. These parameterizations were tested in CLASS version 3.6 at boreal black spruce and jack pine forests in Saskatchewan, Canada, a subalpine Norway spruce and silver fir forest at Alptal, Switzerland, and a boreal maritime forest at Hitsujigaoka, Japan. Model configurations were assessed based on the index of agreement, d, relating simulated and observed daily albedo. The new model employs α_VIS,cs = 0.27, α_NIR,cs = 0.38 and z_I* = 3 cm. The best single‐variable snow unloading algorithm, determined by the average cross‐site d, was based on wind speed. Two model configurations employing ensemble averages of the unloading rate as a function of total incoming radiation and wind speed, and air temperature and wind speed, respectively, produced larger minimum cross‐site d values but a smaller average. The default configuration of CLASS 3.6 produced a cross‐site average d from October to April of 0.58. The best model employing a single parameter (wind speed at the canopy top) for modelling the unloading rate produced an average d of 0.86, while the two‐parameter ensemble‐average unloading models produced a minimum d of 0.81 and an average d of 0.84. © 2015 Her Majesty the Queen in Right of Canada. Hydrological Processes published by John Wiley & Sons, Ltd.     

Multifractal analysis of three large earthquakes in Chile: Antofagasta 1995, Valparaiso 1985, and Maule 2010

A multifractal analysis of seismicity of three large earthquakes in Chile is made: the Central Zone 1985 (M _W = 8.0), Antofagasta 1995 (M _W = 8.1), and Maule 2010 (M _W = 8.8) earthquakes. The analysis shows that the fractal dimension spectrum D _q decreases with time before an earthquake. This fact suggests that the spatial distribution of seismic events could form a cluster before a main shock.     

Analysis of nodal point pollution,variability, and sustainability in mesohaline tidal creeks

Mesohaline tidal creeks are critical since they may lie at the crossroads of aquatic habitat and urban/sub-urban pressures. The emphasis of this study was to determine the water quality stressor variations within and between tidal creeks and determine whether they serve as nodes of pollutants into the sub-estuary. Measurements of water quality stressors were conducted over a six-year period. The study revealed that characterizing the variability of individual tidal creeks is critical to understanding the process and impacts of stressors in sub-estuarine environments and that the tidal creeks are actually nodal points of sediment and nutrient pollution. This results in hypoxia being controlled within tidal creeks rather than being imported from the parent estuary. The calculated metrics were then used to create a Sustainability Characterization Map. Methods incorporated in this study would be of value to restoration managers, and in the decision-making process of urban and suburban watershed planners.