THE COMPOSITION OF IRON METEORITES: A STUDY BY FACTOR ANALYSIS

A factor analysis has been performed on nickel and trace element data for iron meteorites. The technique shows that the present distribution of these elements is the result of three processes. These can be identified from the elements involved:

• 1 Ga, Ge, Sb and Zn (condensation and accretion).
• 2 Ni, Pd, Co and Cu (oxidation and sulphuration).
• 3 Ir, Au, As, Re, Pt, Os, Ru and Cr (an igneous event).

The distribution of Mo, however, is not readily explicable in terms of these processes. Within the groups IAB and IIAB only one process is required for all elements, but in groups IIIAB and IVA the situation for Ga, Ge and Sb is more complex.     

The influence of the structural distribution and hardness of mineral phases on the size and shape of rock drilling particles

Abstract

Rock drilling is a significant activity widely used in the exploration of marine mineral resources and offshore civil engineering such as marine mining, petroleum and deep-water drilling. The characteristics of size and shape of particles produced during rock drilling influence drilling efficiency and energy consumption. We report a series of drilling experiments on sandstone, limestone and shale to systematically examine particle size distribution and shape and correlate these with original rock structure and composition. Correlations are established via metrics of particle size distribution, average circularity and specific surface area. Impact breakage and contact abrasion of individual particles during rock drilling are the main mechanisms controlling particle size and shape. Impact breakage is controlled by the structural distribution of mineral phases, while contact abrasion is principally related to the hardness of mineral phases. The particle size distribution is affected by the structural distribution of mineral phases. The average circularity of the drilling particles is mainly controlled by the hardness of mineral phases. The specific surface area of rock drilling particles is determined by both structural distribution and hardness of mineral phases – with homogeneous structure and low average hardness of the phases reducing the resulting specific surface area of the drilling products.     

Some insight into the influence of urban ground surface properties on the air-surface exchange of total gaseous mercury

Experiments utilizing meteorologically normalized sampling conditions were used to illustrate the role and function of urban pavement, bare soil and turf grass surface properties with respect to the air-surface exchange of total gaseous Hg (TGM). After ensuring uniform meteorological effects to each surface, resultant TGM fluxes from turf grass, bare soil and pavement were specifically representative of their diverse physical and biogeochemical properties. Results spanning the entire sampling year show distinct TGM flux signatures for each surface (5.69 ± 5.79 (ng/m² h) for bare soil, 0.53 ± 1.25 for turf grass, 0.26 ± 0.41 for pavement). Based on medians, the surface limitations of pavement decreased TGM flux by a factor of 22 compared to bare soil and by a factor of 2 compared to turf grass. Turf surface limitations decreased TGM flux by a factor of 11 compared to bare soil. By comparing these results to a parallel study, meteorological effects were found to develop 24% of the TGM flux signature for pavement, 53% for turf and 60% for bare soil. The remaining percentage contributions to each TGM flux signature were from the cumulative surface property effects of each surface. These results suggest that the greater the TGM flux magnitude for a particular surface, the more measurements are needed under a wide variety of meteorological conditions to develop a broad understanding of its TGM flux characteristics. Seasonal observation allowed closer investigation of a large shift to TGM deposition for the turf surface during the fall season. The large shift toward deposition was suspected to be linked to the formation of a thatch layer on the unexposed soil surface just beneath the turf layer.     

Development and application of a quantitative risk assessment to a very slow moving rock slope and potential sudden acceleration

The benefits of quantitative risk assessments for landslide management have been discussed and illustrated in several publications. However, there still are some challenges in its application for low-probability, high-magnitude events. These challenges are associated with the difficulties in populating our models for risk calculations, which largely require the input of expert opinion. This paper presents a quantitative risk assessment to a very slow moving rock slope within a dam reservoir in the Province of British Columbia, Canada. The assessment is focused on the risk to the population in the vicinity of the dam and the populated areas downstream. Expert opinions quantified the slope failure probabilities in the order of 10^?3 to 10^?1 per year for the smallest failure scenario considered and less than 10^?6 for a failure of the entire slope. However, these estimations are associated with high levels of uncertainty. Our approach starts with the calculation and assessment of the magnitude and probability of the potential slope failure consequences, minimizing the uncertainties associated with estimated slope failure probabilities. Then, these consequences and failure probabilities are combined to obtain a measure of risk. The uncertainty associated with the slope failure probabilities is managed by the estimation of plausible ranges for these. The calculated risk levels are then presented as ranges of values and assessed against adopted evaluation criteria. The consequence and risk assessment of the rock slope suggest that the risk to the population exposed in the vicinity of the dam and populated areas downstream is under adequate control. The probability of large consequence scenarios is extremely low, in the order of 10^?7 chance of an event causing more than 100 fatalities. We propose an observational technique to assess changes in risk levels and decide when to update the risk management approach or deploy emergency measures. The technique is focused on the detection of changes in the slope deformation patterns that would indicate an increase in the potential failure volumes or an imminent failure. It can be considered an extension to the current early warning system in place, easy to implement and enhanced with the strength of the comprehensive analysis required for a quantitative risk assessment.     

SWAT.nz: New-Zeland-based “Sand Waves and Turbulence” experimental programme

The SWAT.nz (“New-Zealand-based Sand Waves and Turbulence”) research programme was carried out to advance understanding of subaqueous sand waves. The programme was based around detailed measurements at varying scales of bed morphologies and associated flow fields as sand waves formed from plane-bed conditions and grew to equilibrium. This paper outlines the philosophy and details of the SWAT.nz programme, with the aim of providing insight into experiment and analysis design and methodologies for studies of highly-variable bed surfaces and flows. Example challenges addressed in the SWAT.nz programme include the measurement over large spatial domains of developing flow fields and three-dimensional bed morphology, including flow measurements below roughness (sand-wave) crests, and how to interpret the collected measurements. Insights into sand-wave dynamics that have arisen from the programme are presented to illustrate the values of the SWAT.nz programme and the developed methodologies. Results are presented in terms of mobile-bed processes, and flow-bed interaction and flow processes for fixed-bed roughness and erodible beds, respectively.     

Local‐scale and watershed‐scale determinants of summertime urban stream temperatures

The influence of urbanization on the temperature of small streams is widely recognized, but these effects are confounded by the great natural variety of their contributing watersheds. To evaluate the relative importance of local‐scale and watershed‐scale factors on summer temperatures in urban streams, hundreds of near‐instantaneous temperature measurements throughout the central Puget Lowland, western Washington State, were collected during a single 2‐h period in August in each of the years 1998–2001. Stream temperatures ranged from 8.9 to 27.5 °C, averaging 15.4 °C. Pairwise correlation coefficients between stream temperature and four watershed variables (total watershed area and the watershed percentages of urban development, upstream lakes, and permeable glacial outwash soils as an indicator of groundwater exchange) were uniformly very low. Akaike's information criterion was applied to determine the best‐supported sets of watershed‐scale predictor variables for explaining the variability of stream temperatures. For the full four‐year dataset, the only well‐supported model was the global model (using all watershed variables); for the most voluminous single‐year (1999) data, Akaike's information criterion showed greatest support for per cent outwash (Akaike weight of 0.44), followed closely by per cent urban development + per cent outwash, per cent lake area only, and the global model. Upstream lakes resulted in downstream warming of up to 3 °C; variability in riparian shading imposed a similar temperature range. Watershed urbanization itself is not the most important determining factor for summer temperatures in this region; even the long‐recognized effects of riparian shading can be no more influential than those imposed by other local‐scale and watershed‐scale factors. Copyright © 2013 John Wiley & Sons, Ltd.     

Cosmogenic 10Be insights into the extent and chronology of the last deglaciation in Wester Ross,northwest Scotland

Cosmogenic ¹⁰Be surface exposure ages for bedrock sites around Torridon and the Applecross Peninsula in Wester Ross, northwest Scotland, provide new insights into the Lateglacial transition. Accounting for postglacial weathering, six statistically comparable exposure ages give a late Younger Dryas (G‐1) exposure age of 11.8 ± 1.1 ka. Two further outliers are tentative pre‐Younger Dryas exposure ages of 13.4 ± 0.5 ka in Torridon, and 17.5 ± 1.2 ka in Applecross. The Younger Dryas exposure ages have compelling implications for the deglaciation of marginal Loch Lomond Stadial ice fields in Torridon and Applecross. Firstly, they conflict with predictions of restricted ice cover and rapid retreat based on modelling experiments and climate proxies, instead fitting a model of vertically extensive and prolonged ice coverage in Wester Ross. Secondly, they indicate that >2 m of erosion took place in the upper valleys of Torridon and Applecross during the Younger Dryas, implying a dominantly warm‐based glacial regime. Finally, the exposure ages have clarified that corrie (cirque) glaciers did not readvance in Wester Ross, following final deglaciation. Copyright © 2011 John Wiley & Sons, Ltd.     

A fracture mapping and extended finite element scheme for coupled deformation and fluid flow in fractured porous media

This paper presents a fracture mapping (FM) approach combined with the extended finite element method (XFEM) to simulate coupled deformation and fluid flow in fractured porous media. Specifically, the method accurately represents the impact of discrete fractures on flow and deformation, although the individual fractures are not part of the finite element mesh. A key feature of FM‐XFEM is its ability to model discontinuities in the domain independently of the computational mesh. The proposed FM approach is a continuum‐based approach that is used to model the flow interaction between the porous matrix and existing fractures via a transfer function. Fracture geometry is defined using the level set method. Therefore, in contrast to the discrete fracture flow model, the fracture representation is not meshed along with the computational domain. Consequently, the method is able to determine the influence of fractures on fluid flow within a fractured domain without the complexity of meshing the fractures within the domain. The XFEM component of the scheme addresses the discontinuous displacement field within elements that are intersected by existing fractures. In XFEM, enrichment functions are added to the standard finite element approximation to adequately resolve discontinuous fields within the simulation domain. Numerical tests illustrate the ability of the method to adequately describe the displacement and fluid pressure fields within a fractured domain at significantly less computational expense than explicitly resolving the fracture within the finite element mesh. Copyright © 2013 John Wiley & Sons, Ltd.     

Frontogenesis and Frontal Progression of a Trapping-Generated Estuarine Convergence Front and Its Influence on Mixing and Stratification

Estuarine fronts are well known to influence transport of waterborne constituents such as phytoplankton and sediment, yet due to their ephemeral nature, capturing the physical driving mechanisms and their influence on stratification and mixing is difficult. We investigate a repetitive estuarine frontal feature in the Snohomish River Estuary that results from complex bathymetric shoal/channel interactions. In particular, we highlight a trapping mechanism by which mid-density water trapped over intertidal mudflats converges with dense water in the main channel forming a sharp front. The frontal density interface is maintained via convergent transverse circulation driven by the competition of lateral baroclinic and centrifugal forcing. The frontal presence and propagation give rise to spatial and temporal variations in stratification and vertical mixing. Importantly, this front leads to enhanced stratification and suppressed vertical mixing at the end of the large flood tide, in contrast to what is found in many estuarine systems. The observed mechanism fits within the broader context of frontogenesis mechanisms in which varying bathymetry drives lateral convergence and baroclinic forcing. We expect similar trapping-generated fronts may occur in a wide variety of estuaries with shoal/channel morphology and/or braided channels and will similarly influence stratification, mixing, and transport.