Brittle failure of shale under uniaxial compression

Shale gas reservoirs are characterized by tight matrix, well-developed micro-fissures, and laminations. The study about the failure of shale under compression is of great significance to safe drilling operation and the subsequent reservoir stimulation. The variation of rock mechanical properties with the angle between the axial stress and bedding plane normal (coring angle) is analyzed based on laboratory tests. A failure criterion is applied and verified to describe the strength of shale. Moreover, ultrasonic technology is used to study the damage characteristics of shale during the uniaxial compression process. The experimental results show that shale strength decreases initially and then increases with the increase of the coring angle. The Young’s modulus and Poisson’s ratio increase with the increase of coring angle. In a compression process, damage is essentially the development of new micro-cracks induced by the compression. Shale failure is the microscopical reflection of the process of the generation and expansion of axial micro-cracks, so it is the result of damage accumulation. The variation of the lateral p wave velocity can function as a monitor of the development process of shale damage. The damage factor will increase in the linear elastic stage and then enlarge rapidly after entering the stage of unstable micro-crack expansion.     

黔西北下寒武统牛蹄塘组页岩气成藏条件与有利勘探区预测

以野外露头调查、老井复查和岩心样品测试等为基础,通过现场解吸实验和等温吸附模拟的含气性分析,认为黔西北下寒武统牛蹄塘组岩性主要为深水陆棚黑色碳质页岩和浅水陆棚粉砂质页岩,其中富有机质页岩段为牛蹄塘组底部的碳质页岩。页岩沉积厚度大(大于39m)、分布稳定。有机质类型主要为Ⅰ型干酪根,有机碳含量较高(富有机质页岩段平均大于5%),有机质热演化程度处于高—过成熟阶段;页岩储层中微裂缝、微孔隙发育,具较好的孔隙度(平均5.14%)和渗透率(0.011 4×10-3μm2),含气量大(平均1.3 m3/t),具有良好的气资源潜力。预测金沙—息烽以及仁怀两个地区为页岩气勘探有利区。     

Trace and rare earth element geochemistry of the Upper Triassic mudstones in the southern Ordos Basin,Central China

Oil‐source correlation studies have demonstrated that the crude oils in the Ordos Basin were mainly derived from organic‐rich lacustrine mudstones of the Yanchang Formation. The sedimentology, petrology and organic geochemistry of these mudstones have been studied intensively, but their trace and rare earth element (REE) characteristics have received little attention. In this paper, we present trace and rare earth element data of the Upper Triassic Yanchang Formation mudstones in the southern Ordos Basin to constrain the palaeoenvironment, provenance and depositional setting. Our results show that the REE and trace element concentrations of the Yanchang Formation mudstones are higher than those of the upper continental crust (UCC). The Sr contents and Sr/Ba and Y/Ho ratios of these mudstones indicate the absence of a marine transgression during the sedimentation of the Upper Triassic mudstones. The depositional environment of the Upper Triassic mudstones was slightly oxic as evidenced by the values of Eu/Eu*, Ce/Ce*, Ce_anom, δU, U/Th, V/Cr and Ni/Co. The UCC‐normalized distribution pattern of REEs, spider diagrams, the ratios of related elements, the bivariate diagrams of Th/Sc–Zr/Sc and La/Th–Hf and the ternary plots of La–Th–Sc and Th–Sc–Zr/10 signify that the provenances of the Chang9–7 mudstones were mainly derived from a continental island arc, whereas the provenances of the Chang6–3 mudstones were mainly derived from a mixture of continental island arc and active continental margin, and the latter contain less recycled materials. Combined with the previous studies of detrital zircon dating and petrography of the Yanchang Formation sandstones in the southern Ordos basin, we propose that the Qinling orogenic belt served as one of the primary source regions occurring between the Chang7 and Chang6 periods, corresponding to the initial uplift of the west Qinling Mountains due to the collision between the Yangtze and North China blocks. Copyright © 2014 John Wiley & Sons, Ltd.     

Impacts of extreme precipitation on tree plantation carbon cycle

Extreme precipitation events are expected to increase in frequency and magnitude in future due to global warming, but relevant impacts on tree plantation ecosystem carbon cycle are unknown. In this study, we use an atmosphere–vegetation interaction model (AVIM2) to estimate the likely impacts of extreme precipitation events on carbon fluxes and carbon stocks of a tree plantation in south China. Our results indicate that shifting from moderate precipitation events to extreme precipitation events whilst keeping monthly precipitation unchanged could decrease the tree plantation carbon accumulation. Tree plantation net primary productivity, net ecosystem productivity, soil carbon stock and vegetation carbon stock could decrease by 4.2, 28, 4.3 and 1.4 % during the studying period of 1962–2004, respectively. Though reductions in net primary productivity and net ecosystem productivity are relatively smaller than their annual variations, our sensitivity test shows that the tree plantation carbon stock could decrease by 3.3 % if the assumed extreme precipitation regime lasts for 500 years. Observed and simulated gross primary productivity, ecosystem respiration and net ecosystem productivity have significant positive correlation with soil water content (SWC), especially the deep SWC. The mechanism for the extreme precipitation effect is that the increase in extreme precipitation events will cause SWC to decrease, consequently, reducing carbon fluxes and stocks.     

Production of dimethylsulfide and acrylic acid from dimethylsulfoniopropionate during growth of three marine microalgae

We measured the concentrations of dimethylsulfide （DMS）, acrylic acid （AA）, and dimethylsulfoniopropionate （DMSP） during growth of three microalgae： Prorocentrum micans, Gephyrocapsa oceanica, and Platymonas subcordiformis. The DMSP, AA, and DMS concentrations in culture media varied significantly among algal growth stages, with the highest concentrations in the late stationary growth stage or the senescent stage. In the stationary growth stage, the average DMSP concentration per cell in P. micans （0.066 5 pmol/cell） was 1.3 times that in G. oceanica （0.049 5 pmol/ cell） and 20.2 times that in P. subcordiformis （0.003 29 pmol/cell）. The average concentrations of AA were 0.044 6, 0.026 9, and 0.003 05 pmol/cell in P. micans, G. oceanica, and P. subcordiformis, respectively, higher than the concentrations of DMS （0.272, 0.497, and 0.086 2 fmol/cell, respectively）. There were significant positive correlations between cell density and AA, DMSP, and DMS concentrations. The ratios of DMS/AA and AA/（DMSP＋AA） in the three algae differed significantly over the growth cycle. In all three microalgae, the DMS/AA ratios were less than 25% during the growth period, suggesting that the enzymatic cleavage pathway, which generates DMS, was not the main DMSP degradation pathway. The changes in the DMS/AA ratio indicated that there was a higher rate of enzymatic breakdown of DMSP in the early growth period and a lower rate during senescence. In all three microalgae, the AA/（DMSP＋AA） ratio （degradation ratio of DMSP） decreased during the exponential growth phase, and then increased. The variations in these ratios can approximately indicate the cleavage mechanism of DMSP at different stages of algal growth.     

Seasonal dynamics of crustacean zooplankton community structure in Erhai Lake,a plateau lake,with reference to phytoplankton and environmental factors

The seasonal dynamics of a crustacean zooplankton community in Erhai Lake was investigated from May 2010 to April 2011. In total, 11 species were recorded, including six （6 genera） cladoceran and five （5 genera） copepod species. The crustacean zooplankton densities ranged from 24.3 to 155.4 ind./L. In winter and spring, the large-bodied cladoceran Daphnia galeata dominated the crustacean plankton community. In summer and autumn, when the colonial or filamentous algae dominated the phytoplankton communities, the small-bodied species （e.g. Bosminafatalis, Ceriodaphnia quadrangular, and Mesocyclops leuckarti） replaced the large-bodied ones. One-way ANOVA and redundancy analysis revealed that community structure was dependent upon total nitrogen, total phosphorus, water temperature, transparency, and the biomass of small algae. The variation in both phytoplankton structure and environmental variables were important factors in the seasonal succession of crustacean zooplankton structure in Erhai Lake.     

北京市电网雷害分布规律及风险评估

根据1996—2009年北京市逐日电网灾害资料分析了北京市电网雷害的发生规律, 结果显示:北京市电网雷害存在季节变化和日变化特征。结合同期气象观测站的雷暴日资料、北京市各区县的经济和人口密度特征提出了电网雷害概率、电网雷害频度、电网雷害密度、经济易损模数和生命易损模数作为北京市电网雷害风险评估指标。在此基础上,采用4级分区法对上述电网雷害易损性评估指标进行分级,并将北京市各区县按照5个电网雷害评估指标的所属等级值累加,得到电网雷害综合易损风险评估的评估系数。结果表明:北京地区电网雷害高风险区集中在北京城区中心附近,山区和山前迎风坡地带尽管电网雷害频次较高,但电网雷害风险却相对较低。     

Long-term activity of earthquake-induced landslides: A case study from Qionghai Lake Basin,Southwest of China

Earthquake-triggered landslides are a major geological hazard in the eastern Tibetan Plateau, and have prolonged impact on earth surface processes and fluvial system. To determine how long co-seismic landslides affect basins, a massive number of landslides existing in Qionghai Lake Basin were investigated for landslide distribution characteristics and geomorphological evidences, with further comparison and analysis using historic seismic analog method. The landslides found in Qionghai Lake Basin showed clear features of seismic triggering with strongly controlled by Zemuhe fault. These landslides are still active at present. Some new slides generally occur in ancient slope failure zones causing serious secondary hazards in recent years. In this study we strengthen the idea that the landslides triggered by the 185o Xichang earthquake （Ms7.5） have long term activity and prolonged impact on the mountain disasters with a period of more than 16o years. Our results support growing evidence that coseismic landslides have a prolonged effect on secondary disasters in a basin, and invite more careful consideration of the relationship between current basin condition and landslide history for a longer period.     

Spatial spillover and the factors influencing public service supply in Sichuan province,China

This article examines the spatial characteristics of public service supply and the factors influencing such supply in cities of Sichuan Province, China using spatial-autocorrelation and spatial econometric models with statistical data in 2012. The results demonstrate that expenditures on different types of public services present different spatial autocorrelation patterns. Although the spatial differences in basic public service expenditures are relatively small, a clear fan-shaped spillover to the east can be seen in Chengdu City. Chengdu also shows high clustering of advanced public service expenditures, being a typical core-periphery pattern. Post-earthquake reconstruction expenditures are clustered in the ＂5.12 Wenchuan earthquake＂ region and spill over toward cities to the east. The efficiency of public services in the mountainous areas in western Sichuan is low and exhibits a pattern of low-low spatial autocorrelation. The efficiency of public service supply is affected by economic, social, political and geographical factors. Based on the results of this analysis, we recommend a supply strategy that incorporates different types of public services and a specialized public service supply strategy for mountainous areas. Overall public service efficiency should be enhanced by focusing on narrowing the gap in farmers＇ income among regions and accelerating urbanization. Decision-makers should consider moresupportive policies with regard to providing basic public services in mountainous areas to ensure an equalized supply of basic public services. To enhance the efficiency of advanced public service supply, additional growth pole should be encouraged and incentivized; however, investments are required to drive the development of the peripheral regions through regional economic integration. Both software and hardware types of infrastructure are required to supply services efficiently during post-disaster reconstruction.     

地质资料数据服务体系建设

地质资料是地质工作成果的主要表现形式,是地质工作者智慧与劳动相结合的产物。如何对其进行有效的管理,挖掘其潜在的价值,以便更好的为社会服务,已成为地质资料信息化领域研究的一个重要课题。本文系统分析和阐述了地质资料数据服务体系建设,为地质资料数据的有效管理、应用和服务等提供参考。