Geochemical characterization of adsorbed light gaseous alkanes in near surface soils of the eastern Ganga basin for hydrocarbon prospecting

This study aims to assess the hydrocarbon potential of Ganga basin utilizing the near surface geochemical prospecting techniques. It is based on the concept that the light gaseous hydrocarbons from the oil and gas reservoirs reach the surface through micro seepage, gets adsorbed to soil matrix and leave their signatures in soils and sediments, which can be quantified. The study showed an increased occurrence of methane (C₁), ethane (C₂) and propane (C₃) in the soil samples. The concentrations of light gaseous hydrocarbons determined by Gas Chromatograph ranged (in ppb) as follows, C₁: 0–519, C₂: 0–7 and C₃: 0–2. The carbon isotopic (VPDB) values of methane varied between ?52.2 to ?27.1‰, indicating thermogenic origin of the desorbed hydrocarbons. High concentrations of hydrocarbon were found to be characteristic of the Muzaffarpur region and the Gandak depression in the basin, signifying the migration of light hydrocarbon gases from subsurface to the surface and the area’s potential for hydrocarbon resources.     

Shifted cosmological parameter and shifted dust matter in a two-phase tachyonic field universe

We propose a model of the evolution of the tachyonic scalar field over two phases in the universe. The field components do not interact in phase I, while in the subsequent phase II, they change flavours due to relative suppression of the radiation contribution. In phase II, we allow them to interact mutually with time-independent perturbation in their equations of state, as Shifted Cosmological Parameter (SCP) and Shifted Dust Matter (SDM). We determine the solutions of their scaling with the cosmic redshift in both phases. We further suggest the normalised Hubble function diagnostic, which, together with the low- and high-redshift H(z) data and the concordance values of the present density parameters from the CMBR, BAO statistics etc., constrain the strength of interaction by imposing the viable conditions to break degeneracy in 3-parameter $(\gamma, \varepsilon, \dot{\phi}^{2})$ space. The range of redshifts (z=0.1 to z=1.75) is chosen to highlight the role of interaction during structure formation, and it may lead to a future analysis of power spectrum in this model vis a vis Warm Dark Matter (WDM) or ΛCDM models. We further calculate the influence of interaction in determining the age of the universe at the present epoch, within the degeneracy space of model parameters.     

On spin-up/spin-down torque reversals in disc accreting pulsars

The recent BATSE observations of the spin-up and spin-down of accreting pulsars have shown that the standard formulation for the accretion torque as proposed by Ghosh &38; Lamb may need to be revised. The observations indicate alternate spin-up and spin-down phases driven by torques of similar magnitude and typically larger than the mean torque. The variations of the torque in systems such as Cen X-3 are difficult to explain in terms of changes of the mass accretion rate. The implication is that the torque does not depend on the accretion rate as in the GL model. In this paper we argue that the observed changes in the spin rate can result from stochastic transitions between two magnetospheric states. In particular, we show that intermediate magnetospheric systems are not admissible, because of a disc-induced magnetospheric instability which exists in a star–disc magnetic interaction system. This explains why torque reversal occurs in disc accreting pulsars with similar magnitudes.     

Magnetic braking in magnetic binary stars

The role of an external magnetic field in the magnetic braking of a star with a dipolar field is investigated. In a magnetic cataclysmic variable system (i.e. the primary compact star has a strong magnetic field), the field external to the braking star (a late-type main-sequence star with a dynamo-generated field) originates from the compact star. A closed field region — the system dead zone — is formed within the binary system, and it does not take part in magnetic braking. The overall braking rate depends on the extent of this region and of the open flux, and is dependent on centrifugal effects. In the case of two interacting dipoles, the dipole orientations relative to the spin axes and to each other are found to be important, leading to different amounts of open flux and therefore of magnetic braking, owing to different centrifugal effects on closed field regions. However, in circumstances consistent with observations and dynamo theory, the white dwarf's field reduces the magnetic braking of the secondary significantly, a finding qualitatively similar to the results previously obtained for two anti-aligned dipoles perpendicular to the orbital plane. In the cases where the two dipole axes are not perpendicular to the orbital plane, but are inclined in the plane that links them, the 'cut-off' in magnetic braking is less abrupt, and this effect is more obvious as the inclinations increase. Only in the extreme cases when the two dipole axes are aligned in the orbital plane does the braking increase with white dwarf field strength. We conclude that detailed evolutionary modelling of AM Herculis systems needs to take account of the inclination effect.     

A MEASURE OF CROPPING INTENSITY*

The measurement of agricultural intensity is fundamental to an understanding of spatial organization of agriculture. This paper develops a new index of cropping intensity from land use data. The length of time for which a crop stays in the field, a factor ignored in other indirect measures of cropping intensity, has been incorporated in the new index. To illustrate the method, cropping intensity in India is measured, mapped and discussed. Differences between the patterns derived from the new index and the traditional index are noted and explained.     

Free fall penetrometer: a performance evaluation

The application of a free fall penetrometer for determining the in situ shear strength properties of marine sediments is discussed. The penetrometer is instrumented with three sensors for measuring the acceleration/deceleration, cone thrust and local side friction simultaneously and continuously. The instrument is simple and fast in operation (the entire operation of deploying, testing and retrieving the instrument takes only 20 minutes) and may prove to be a useful ground truth equipment for deep toe acoustic surveys. Recent trials offshore Newfoundland are discussed. Preliminary field test results indicate that with this system the dynamic strength profile, the soil type and the location and depth of different stratigraphic layers can be directly evaluated up to penetrated depths. A procedure is outlined for estimating the static strength profile from the dynamic strength profile by applying the correction for penetration rate effects.The penetrometer developed to date is capable of penetrating to a maximum depth of about 4 m but, in the future, it may be possible to obtain soil profiles to a depth of approximately 15 m (50 ft) with some modifications in the instrument design.     

Application of trace metal anomalies for recognition of petroleum prospects in surface sediments of Kutch and Saurashtra Basins, India

Seepage of hydrocarbons, either as macroseepage or microseepage, can set up near-surface oxidation-reduction zones that favour the development of a diverse array of chemical and mineralogic changes. In this study trace metal alterations were mapped that appear to be associated with hydrocarbon microseepages in the oil/gas fields. A total of 210 soil samples were collected from near surface sediments of Kutch and Saurashtra Basins, India. The soil samples were collected from a depth of 2–2.5 m. The paper reports the chemical alterations associated with trace metals in soils that are related to hydrocarbon microseepages above the Kutch and Saurashtra Basins, India. The soil samples for trace metals; Scandium (Sc), Vanadium (V), Chromium (Cr), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Barium (Ba) and Strontium (Sr) were analyzed using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The concentrations of the trace elements ranged between for Sc (12.69 to 21.91 ppm), V (109.20 to 436.05 ppm), Cr (87.15 to 481.57 ppm), Co (18.25 to 64.31 ppm), Ni (57.55 to 263.15 ppm), Cu (44.88 to 143.96 ppm), Zn (137.60 to 502.31 ppm), Ba (149.27 to 921.46 ppm) and Sr (143.93 to 425.63 ppm) were obtained. It was observed that trace elements concentrations were tremendously increased when compared with normal concentration in the soils. The adsorbed soil gas analysis showed the presence of high concentrations of ΣC₂₊ (C₂H₆, C₃H₈ and n-C₄H₁₀) ranged between 1 to 121 ppb respectively. Integrated studies of trace elements over adsorbed light gaseous hydrocarbon (ΣC₂₊) anomalies showed good correlation. The carbon isotopic composition of δ¹³C₁ of the samples ranges between — 36.6 ‰ to ?22.7‰ (Pee Dee Belemnite) suggest thermogenic source for hydrocarbon gases. The increase in trace metal concentrations near oil/gas producing areas, suggests that soil chemical change to a reducing environment, presumably due to the influence of hydrocarbon microseepage, which could be applied with other geo-scientific data to identify areas of future hydrocarbon exploration in the frontier areas.     

http://www.sciencedirect.com/science/article/pii/S1674987113001114

The Deccan Syneclise is considered to have significant hydrocarbon potential.However,significant hydrocarbon discoveries,particularly for Mesozoic sequences,have not been established through conventional exploration due to the thick basalt cover over Mesozoic sedimentary rocks.In this study,near-surface geochemical data are used to understand the petroleum system and also investigate type of source for hydrocarbons generation of the study area.Soil samples were collected from favorable areas identified by integrated geophysical studies.The compositional and isotopic signatures of adsorbed gaseous hydrocarbons(methane through butane) were used as surface indicators of petroleum micro-seepages.An analysis of 75 near-surface soil-gas samples was carried out for light hydrocarbons(C1-C4) and their carbon isotopes from the western part of Tapti graben,Deccan Syneclise,India.The geochemical results reveal sites or clusters of sites containing anomalously high concentrations of light hydrocarbon gases.High concentrations of adsorbed thermogenic methane(C_1 = 518 ppb) and ethane plus higher hydrocarbons(ΣC_(2+) = 977 ppb) were observed.Statistical analysis shows that samples from 13% of the samples contain anomalously high concentrations of light hydrocarbons in the soil-gas constituents.This seepage suggests largest magnitude of soil gas anomalies might be generated/source from Mesozoic sedimentary rocks,beneath Deccan Traps.The carbon isotopic composition of methane,ethane and propane ranges are from-22.5‰ to-30.2‰ PDB,-18.0‰to 27.1‰ PDB and 16.9‰-32.1‰ PDB respectively,which are in thermogenic source.Surface soil sample represents the intersection of a migration conduit from the deep subsurface to the surface connected to sub-trappean Mesozoic sedimentary rocks.Prominent hydrocarbon concentrations were associated with dykes,lineaments and presented on thinner basaltic cover in the study area,which probably acts as channel for the micro-seepage of hydrocarbons.     

Near surface manifestation of hydrocarbons in Proterozoic Bhima and Kaladgi Basins: Implications to hydrocarbon resource potential

Reconnaissance surface geochemical survey for adsorbed soil gas analysis conducted in Proterozoic Bhima and Kaladgi Basins, have revealed occurrence of anomalous concentrations of light gaseous hydrocarbons i.e. C₁ to C₄ (CH₄, C₂H₆, C₃H₈, i-C₄H₁₀ and n-C₄H₁₀) in the near surface soils. The concentrations of C₁ and ΣC₂₊(C₂H₆+C₃H₈+ i-C₄H₁₀+ n-C₄H₁₀) in Bhima and Kaladgi Basins are in the range of 1–2594 ppb and 1 to 57 ppb and 1–1142 ppb and 1–490 ppb, respectively. The carbon isotopic data of adsorbed soil gas methane in few selected samples are in the range of −29.9 to −39‰ (PDB). The evaluation of adsorbed soil gas data indicates that all the gas components are cogenetic and hydrocarbon ratios of C₁/(C₂+C₃) < 10 and C₃/C₁*1000 between 60–500 and 20–60 suggest that the adsorbed gases are derived from oil and gas-condensate zones. The carbon isotopic values of methane further support thermogenic origin of these migrated gases. The concentration distribution of C₁ and ΣC₂₊ in the study areas illustrate C₁ and ΣC₂₊ anomalies near Katamadevarhalli, Andola and Talikota in Bhima Basin and near Kaladgi, Lokapur and north of Mudhol in Kaladgi Basin. The hydrocarbon anomalies near the surface coincide with the favourable subsurface structural features and correlate with existing geochemical and geophysical data in these basins suggesting seepage related anomalies.