Correlation of trace elements with hydrocarbon microseepage

Direct correlation have been observed between certain trace element and hydrocarbon anomalies in the near subsurface soils of Vindhyan basin, India. This relationship with hydrocarbon is very useful in hydrocarbon exploration. 52 soil samples from Vindhyan basin were collected from a depth of 2.5m. All the soil samples were analyzed for light hydrocarbon, isotope and trace element concentrations. The adsorbed light gaseous hydrocarbon analyses show the presence of methane (8–328 ppb), ethane (0–27 ppb) and propane (0–11 ppb) respectively and these values indicate the presence of hydrocarbon micro-seepage in the study area. The carbon isotopic values determined for methane and ethane for these soil samples are (?26.41 to ?47.70 ‰ PDB) and (?20.07 to ?35.30 ‰ PDB) respectively and they are thermogenic in nature. The trace element concentrations of nickel (33–220 ppm), vanadium (72–226 ppm), copper (20–131 ppm), chromium (94–205 ppm), zinc (66–561 ppm) and cobalt (9–39 ppm) have higher than the normal concentrations in soils. Trace element concentrations are used to plot with the data obtained from light gaseous hydrocarbon concentrations and carbon isotopic values of soil samples of the Vindhyan basin. Trace element anomalies have been observed around the hydrocarbon anomalies in the study area.     

Kinetics of silica sorption and clay dissolution reactions at 1 and 670 atm

Rates of reactions between clay minerals and silica-spiked seawater and the effect of pressure on the direction, extent and rate of such reactions have been studied. Kinetic behavior of short-term, clay-silica reaction indicates that diffusion is the rate controlling process in both clay dissolution and clay reconstitution reactions. Rate constants of these reactions are of the order of 10^?13 moles/ sec^{$\text{1}\text{2}$}cm². No significant pressure effect on the rate of clay dissolution was observed. Estimates of diffusion coefficient of silicic acid for clay dissolution and silica sorption reactions indicate that the true value lies within the range, 10^?13–10^?17cm²/sec, thus reflecting the semicrystalline or amorphous nature of the reaction product through which diffusion is occurring.     

Late Cretaceous mafic dykes in the Dharwar craton

Palaeomagnetic, geochemical and geochronological studies have been conducted on a set of dolerite dykes intruding the Peninsular gneisses near Huliyurdurga town, Karnataka, as a reconnaissance survey indicated a Cretaceous age for them. The dykes are mainly tholeiitic in composition with their 87Sr/86Sr ratios tightly clustered around 0·7045. Their palaeomagnetic data (D _m =329°,I _m =−55°) and the corresponding palaeopole coordinates (λ _p = 34°S,L _p =108°E) are strikingly close to those of the Deccan Traps to the north. Whole rock K-Ar ages of these dykes ranging between 69 and 84 Ma are also similar to the range of K-Ar ages of the Deccan basalts. The chemical, palaeomagnetic and temporal coherence between the dykes and the Deccan basalts indicate that they may indeed be tectonically related events.     

The behavior of iron,manganese and silicon in the Peconic River estuary,New York

The behavior of dissolved and particulate iron and manganese and dissolved silicon has been studied as a function of chlorinity in the Peconic River estuary, New York. This study sought to identify important geochemical processes in a relatively pristine estuary facing increasing anthropogenic impact.Dissolved iron behaved in the classical non-conservative manner exhibiting removal of nearly 80% at very low chlorinities, while particulate iron increased by a corresponding amount over the same chlorinity range. Dissolved manganese was enriched by up to 200% over its predicted concentration at low and intermediate chlorinities by desorption from suspended particulates and by a probable benthic flux. Dissolved silicon was enriched by up to 100% at low and intermediate chlorinities also from a probable benthic flux. These fluxes were estimated to be 5 μg cm^?2 day^?1 for dissolved manganese and 70 μg cm^?2 day^?1 for dissolved silicon.The quantity of both particulate iron and manganese increased at high chlorinities due to an influx of suspended inorganic particulates. In the intermediate to high chlorinity region, oxidation of sediment-derived manganese is believed to contribute to the observed increase in particulate manganese.Total iron was essentially conservative throughout most of the estuary, while total manganese was non-conservative presumably due to extensive remobilization of dissolved manganese from the sediments.     

Polarimetry and spectroscopy of RX J1141.3−6410: a single‐pole AM Her system

We present polarimetric and spectroscopic observations of the ROSAT source RX J1141.3−6410, recently identified as a polar. The detection of circular polarization variations, with an amplitude of 10 per cent, over a 3.16-h period confirms that the system is a polar (AM Herculis star). Supporting evidence comes from the nature of the emission lines and their radial velocity variability. In addition, we observe continuum slope changes in the far-red spectral region (∼6000–8200 Å), indicative of phase dependent cyclotron emission. Polarimetric modelling at two wavelengths establishes RX J1141.3−6410 as a single-pole system, with i ∼ β ∼70°. The accretion region is extended in magnetic longitude, and is totally self-occulted for ∼25 per cent of the orbit. The radial velocity curves derived from the emission lines show a phasing with maximum blueshift occurring with Δ φ ∼0.05 of maximum intensity and circular polarisation. In addition, the broader component of the lines exhibit a substantial radial velocity phase shift with respect to the narrower component, in the sense that the broad component preceeds the narrow. This can be readily understood if the narrower component is principally a result of orbital motion of the stream material and the broad component mainly a result of streaming motion near the coupling region. The phasing of the Ca  ii near-infrared line radial velocities also supports this general picture.     

Light hydrocarbons geochemistry of surface sediments from Pranhita-Godavari Basin,Andhra Pradesh

A geochemical study of surface sediments from Pranhita-Godavari Basin, Andhra Pradesh, India was carried out using light hydrocarbon compounds to assess the hydrocarbon potential of the basin. Suite of 80 soil samples were collected from the depth of 2.5 m and analyzed for adsorbed light gaseous hydrocarbons namely methane (CH₄), ethane (C₂H₆) and propane (C₃H₈) in Gas chromatograph. Compound specific Carbon isotope ratios for CH₄ and C₂H₆ were also determined using GC-C IRMS (Gas Chromatograph Combustion Isotope Mass Spectrometer). The presence of moderate to low concentrations of methane (C_CH4 C_{CH_4 } : 1 to 138 ppb), ethane (H₄{H_4 }: 1 to 35 ppb) and propane (C_{C3 H8} C_{C_3 H_8 } : 1 to 20 ppb) was measured in the soil samples. Carbon isotopic composition of d¹³ C_CH4 \delta ^{13} C_{CH_4 } ranges between −27.9 to −47.1 ‰ and d¹³ C_{C2 H6} \delta ^{13} C_{C_2 H_6 } ranged between −36.9 to −37.2 ‰ (V-PDB) indicating that these gases are of thermogenic origin. Study of soil samples suggests the area has good potential for hydrocarbon.