MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.     

Constraints on the bulk Lorentz factor in the internal shock scenario for gamma-ray bursts

We investigate, independently of specific emission models, the constraints on the value of the bulk Lorentz factor Γ of a fireball. We assume that the burst emission comes from internal shocks in a region transparent to Thomson scattering, and before deceleration caused by the swept-up external matter is effective. We consider the role of Compton drag in decelerating fast-moving shells before they interact with slower ones, thus limiting the possible differences in the bulk Lorentz factor of shells. Tighter constraints on the possible range of Γ are derived by requiring that the internal shocks transform more than a few per cent of the bulk energy into radiation. Efficient bursts may require a hierarchical scenario, where a shell undergoes multiple interactions with other shells. We conclude that fireballs with average Lorentz factors larger than 1000 are unlikely to give rise to the observed bursts.     

The rest-frame ultraviolet spectra of GRBs from massive rapidly rotating stellar progenitors

The properties of a massive star prior to its final explosion are imprinted in the circumstellar medium (CSM) created by its wind and termination shock. We perform a detailed, comprehensive calculation of the time-variable and angle-dependent transmission spectra of an average-luminosity gamma-ray burst (GRB) which explodes in the CSM structure produced by the collapse of a  20 M_⊙  , rapidly rotating,   Z = 0.001  progenitor star. We study both the case in which metals are initially in the gaseous phase and the situation in which they are heavily depleted into dust. We find that high-velocity lines from low-ionization states of silicon, carbon and iron are initially present in the spectrum only if the metals are heavily depleted into dust prior to the GRB explosion. However, such lines disappear on time-scales of a fraction of a second for a burst observed on-axis, and of a few seconds for a burst seen at high latitude, making their observation virtually impossible. Rest-frame lines produced in the termination shock are instead clearly visible in all conditions. We conclude that time-resolved, early-time spectroscopy is not a promising way in which the properties of the GRB progenitor wind can be routinely studied. Previous detections of high-velocity features in GRB ultraviolet spectra must have been either due to a superposition of a physically unrelated absorber or due to a progenitor star with very unusual properties.     

Generalised ultimate loads for pile groups

Acta Geotechnica - Foundation piles can be used as a means for increasing the capacity of the foundations under static loads or, at the same time, can be regarded as an additional source of energy...     

Multi-approach characterization of shallow-water carbonates off Minamitorishima and their depositional settings/history

Sedimentological, geochemical, and chronological analyses were carried out on 18 carbonate rock samples collected at depths of 938, 1085, and 3354 m on the western slope of Minamitorishima (Marcus Island), which is located near the western margin of the Pacific Plate. Four groups of carbonate rocks were distinguished: a mollusk-rich limestone, a coral-rich dolomite, a foraminiferal-nannofossil packstone, and a phosphatized mudstone/wackestone. The mollusk-rich limestone is characterized by the dominance of bivalves (including rudists) and gastropod shells. Strontium isotope ratios (⁸⁷Sr/⁸⁶Sr) and Mesorbitolina ex gr. texana (a large benthic foraminifer) indicate that the shallow-water carbonates were deposited during the late Aptian–early Albian (ca. 123–111 Ma). The coral-rich dolomite is characterized by abundant scleractinian corals and nongeniculate coralline algae associated with encrusting acervulinid foraminifers. The biotic composition is similar to that of the Oligocene–Pleistocene carbonates reported from other seamounts in the northwestern Pacific. Geochemical data show that the coral-rich carbonates were dolomitized at 9.5–6.8 Ma (Tortonian–Messinian) and that normal seawater was the most likely parent fluid. The foraminiferal-nannofossil packstone is a semi-consolidated foraminiferal-nannofossil ooze and was deposited during the Pleistocene (0.99–0.45 Ma). The phosphatized mudstone/wackestone is marked by the absence of macrofossils and the presence of traces of planktic foraminifers. Although its depositional age is not constrained, the Sr isotope ratios indicate that the phosphatization occurred at 33.2–28.9 Ma. After the deposition of the Cretaceous shallow-water carbonates, including the mollusk-rich limestone, Minamitorishima was drowned and its top was covered with a pelagic cap, represented by the mudstone/wackestone. The late Eocene–early Oligocene volcanism (40.2–33.2 Ma) caused episodic uplift and returned the top of Minamitorishima to a shallow-water environment. After the early Oligocene phosphatization of the pelagic cap, coral reefs flourished on the top of this island. The reef limestone was dolomitized during the Tortonian–Messinian.     

Observational constraints on the tropospheric and near-surface winter signature of the Northern Hemisphere stratospheric polar vortex

A composite analysis of Northern Hemisphere’s mid-winter tropospheric anomalies under the conditions of strong and weak stratospheric polar vortex was performed on NCEP/NCAR reanalysis data from 1948 to 2013 considering, as additional grouping criteria, the coincidental states of major seasonally relevant climate phenomena, such as El Niño-Southern Oscillation (ENSO), Quasi Biennial Oscillation and strong volcanic eruptions. The analysis reveals that samples of strong polar vortex nearly exclusively occur during cold ENSO states, while a weak polar vortex is observed for both cold and warm ENSO. The strongest tropospheric and near-surface anomalies are found for warm ENSO and weak polar vortex conditions, suggesting that internal tropospheric circulation anomalies related to warm ENSO constructively superpose on dynamical effects from the stratosphere. Additionally, substantial differences are found between the continental winter warming patterns under strong polar vortex conditions in volcanically-disturbed and volcanically-undisturbed winters. However, the small-size samples obtained from the multi-compositing prevent conclusive statements about typical patterns, dominating effects and mechanisms of stratosphere-troposphere interaction on the seasonal time scale based on observational/reanalysis data alone. Hence, our analysis demonstrates that patterns derived from observational/reanalysis time series need to be taken with caution as they not always provide sufficiently robust constraints to the inferred mechanisms implicated with stratospheric polar vortex variability and its tropospheric and near-surface signature. Notwithstanding this argument, we propose a limited set of mechanisms that together may explain a relevant part of observed climate variability. These may serve to define future numerical model experiments minimizing the sample biases and, thus, improving process understanding.     

Different flavors of the Atlantic Multidecadal Variability

We investigate how differently-constructed indices for North Atlantic sea-surface temperatures (NASSTs) describe the “Atlantic Multidecadal Variability” (AMV) in a suite of unperturbed as well as externally-forced millennial (pre-industrial period) climate simulations. The simulations stem from an ensemble of Earth system models differing in both resolution and complexity. Different criteria exist to construct AMV indices capturing different aspects of the phenomenon. Although all representations of the AMV maintain strong multidecadal variability, they depict different characteristics of simulated low-frequency NASST variability, evolve differently in time and relate to different hemispheric teleconnections. Due to such multifaceted signatures in the ocean-surface as well as in the atmosphere, reconstructions of past AMV may not univocally reproduce multidecadal NASST variability. AMV features under simulated externally-forced pre-industrial climate conditions are not unambiguously distinguishable, within a linear framework, from AMV features in corresponding unperturbed simulations. This prevents a robust diagnosis of the simulated pre-industrial AMV as a predominantly internal rather than externally-forced phenomenon. We conclude that a multi-perspective assessment of multidecadal NASSTs variability is necessary for understanding the origin of the AMV, its physics and its climatic implications.     

Petrogenesis of the anorthosite-chromitite association: crystal-chemical and petrological insights from the Rum Layered Suite, NW Scotland

Thirteen Cr-bearing spinels from major horizons of magma replenishment in the open-system Rum Layered Suite have been analysed by X-ray single crystal diffraction and electron microprobe analyses. On the basis of the structural parameters and the chemistry of these spinels the so-called Rum trend, in which Al-content increases at the expense of Cr and Fe³⁺, has been easily recognised. In addition, natural spinels with Fe³⁺ content similar to synthetic spinels on the MgCr₂O₄?CMgFe₂O₄ join have been analysed for the first time. Layers of chromitite, anorthosite and peridotite situated within several cm of one another have yielded different intracrystalline exchange temperatures using an intercrystalline spinel-olivine thermometer. The Rum anorthosite Cr-spinels are interpreted as having crystallised within the cumulus pile following rejuvenation of the crystal mush. Their low Al-content is a function of simultaneous plagioclase crystallisation, reducing the amount of Al³⁺ present for the Cr-spinel. By contrast, Cr-spinels in well-known Archean anorthosites (e.g. Ujaragssuit nunat and Fisken?sset, western Greenland) and Sittampundi (southern India) are very aluminous in composition, attributed to crystallisation of Cr-spinel from high-alumina basalts in lower crustal magma chambers and linked to the control exerted by plagioclase crystallisation on Al content of the melt, in the absence of clinopyroxene crystallisation. The compositional differences between the Rum anorthosite Cr-spinels and the Fisken?sset and Sittampundi Cr-spinels suggest that postcumulus reaction of Cr-spinel and melt to low (800?C900°C) temperatures, as invoked for the Rum crystals, may not have been as important a process in the Archean anorthosites.     

Mean Flow Near Edges and Within Cavities Situated Inside Dense Canopies

A streamfunction-vorticity formulation is used to explore the extent to which turbulent and turbulently inviscid solutions to the mean momentum balance explain the mean flow across forest edges and within cavities situated inside dense forested canopies. The turbulent solution is based on the mean momentum balance where first-order closure principles are used to model turbulent stresses. The turbulently inviscid solution retains all the key terms in the mean momentum balance but for the turbulent stress gradients. Both exit and entry versions of the forest edge problem are explored. The turbulent solution is found to describe sufficiently the bulk spatial patterns of the mean flow near the edge including signatures of different length scales reported in canopy transition studies. Next, the ‘clearing inside canopy’ or the so-called ‘cavity’ problem is solved for the inviscid and turbulent solutions and then compared against flume experiments. The inviscid solution describes the bulk flow dynamics in much of the zones within the cavity. In particular, the solution can capture the correct position of the bulk recirculation zone within the cavity, although with a weaker magnitude. The inviscid solution cannot capture the large vertical heterogeneity in the mean velocity above the canopy, as expected. These features are better captured via the first-order closure representation of the turbulent solution. Given the ability of this vorticity formulation to capture the mean pressure variations and the mean advective acceleration terms, it is ideal for exploring the distributions of scalars and roughness-induced flow adjustments on complex topography.