Petrogenesis of the anorthosite-chromitite association: crystal-chemical and petrological insights from the Rum Layered Suite, NW Scotland

Thirteen Cr-bearing spinels from major horizons of magma replenishment in the open-system Rum Layered Suite have been analysed by X-ray single crystal diffraction and electron microprobe analyses. On the basis of the structural parameters and the chemistry of these spinels the so-called Rum trend, in which Al-content increases at the expense of Cr and Fe³⁺, has been easily recognised. In addition, natural spinels with Fe³⁺ content similar to synthetic spinels on the MgCr₂O₄?CMgFe₂O₄ join have been analysed for the first time. Layers of chromitite, anorthosite and peridotite situated within several cm of one another have yielded different intracrystalline exchange temperatures using an intercrystalline spinel-olivine thermometer. The Rum anorthosite Cr-spinels are interpreted as having crystallised within the cumulus pile following rejuvenation of the crystal mush. Their low Al-content is a function of simultaneous plagioclase crystallisation, reducing the amount of Al³⁺ present for the Cr-spinel. By contrast, Cr-spinels in well-known Archean anorthosites (e.g. Ujaragssuit nunat and Fisken?sset, western Greenland) and Sittampundi (southern India) are very aluminous in composition, attributed to crystallisation of Cr-spinel from high-alumina basalts in lower crustal magma chambers and linked to the control exerted by plagioclase crystallisation on Al content of the melt, in the absence of clinopyroxene crystallisation. The compositional differences between the Rum anorthosite Cr-spinels and the Fisken?sset and Sittampundi Cr-spinels suggest that postcumulus reaction of Cr-spinel and melt to low (800?C900°C) temperatures, as invoked for the Rum crystals, may not have been as important a process in the Archean anorthosites.     

In situ high-temperature X-ray and neutron powder diffraction study of cation partitioning in synthetic Mg(Fe<Subscript>0.5</Subscript>Al<Subscript>0.5</Subscript>)<Subscript>2</Subscript>O<Subscript>4</Subscript> spinel

The intra-crystalline cation partitioning over T- and M-sites in a synthetic Mg(Fe,Al)₂O₄ spinel sample has been determined as a function of temperature by Rietveld structure refinements from powder diffraction data, combining in situ high-temperature neutron powder diffraction (NPD; POLARIS diffractometer, at ISIS, Rutherford Appleton Laboratory, UK), to determine the Mg and Al occupancy factors, with in situ high-temperature X-ray powder diffraction, to fix the Fe³⁺ distribution. The results obtained agree with a two-stage reaction, in which an initial exchange between Fe³⁺ and Mg, the former leaving and the latter entering tetrahedral sites, is successively followed by a rearrangement involving also Al. The measured cation distribution has then been compared and discussed with that calculated by the Maximum Configuration Entropy principle, for which only NPD patterns have been used. The cation partitioning has finally been interpreted in the light of the configuration model of O’Neill and Navrotsky.     

Different flavors of the Atlantic Multidecadal Variability

We investigate how differently-constructed indices for North Atlantic sea-surface temperatures (NASSTs) describe the “Atlantic Multidecadal Variability” (AMV) in a suite of unperturbed as well as externally-forced millennial (pre-industrial period) climate simulations. The simulations stem from an ensemble of Earth system models differing in both resolution and complexity. Different criteria exist to construct AMV indices capturing different aspects of the phenomenon. Although all representations of the AMV maintain strong multidecadal variability, they depict different characteristics of simulated low-frequency NASST variability, evolve differently in time and relate to different hemispheric teleconnections. Due to such multifaceted signatures in the ocean-surface as well as in the atmosphere, reconstructions of past AMV may not univocally reproduce multidecadal NASST variability. AMV features under simulated externally-forced pre-industrial climate conditions are not unambiguously distinguishable, within a linear framework, from AMV features in corresponding unperturbed simulations. This prevents a robust diagnosis of the simulated pre-industrial AMV as a predominantly internal rather than externally-forced phenomenon. We conclude that a multi-perspective assessment of multidecadal NASSTs variability is necessary for understanding the origin of the AMV, its physics and its climatic implications.     

Efficiency of a wide-area survey in achieving short- and long-term warning for small impactors

We consider a network of telescopes capable of scanning all the observable sky each night and targeting Near-Earth objects (NEOs) in the size range of the Tunguska-like asteroids, from 160 m down to 10 m. We measure the performance of this telescope network in terms of the time needed to discover at least 50% of the impactors in the considered population with a warning time large enough to undertake proper mitigation actions. The warning times are described by a trimodal distribution and the telescope network has a 50% probability of discovering an impactor of the Tunguska class with at least one week of advance already in the first 10 yr of operations of the survey. These results suggest that the studied survey would be a significant addition to the current NEO discovery efforts.     

Discrimination between wave‐ravinement surfaces and bedset boundaries in Pliocene shallow‐marine deposits,Crotone Basin,southern Italy: An integrated sedimentological,micropalaeontological and mineralogical approach

The lower Pliocene Belvedere Formation, cropping out in the Crotone Basin, southern Italy, exhibits a metre‐scale to decametre‐scale shallow‐marine cyclicity that shares features of both high‐frequency sequences linked to shoreline shifts and controlled by minor relative sea‐level and/or sediment supply changes, and sedimentological cycles unrelated to shoreline shifts. In order to better understand the high‐frequency sequence stratigraphic framework of this succession, an integration of sedimentological, micropalaeontological (micro‐foraminifera assemblages) and mineralogical (heavy mineral abundance) data is used. From a sedimentological/stratigraphic point of view, wave‐ravinement surfaces bounding high‐frequency sequences, and associated substrate‐controlled ichnofacies, are prominent in outcrop and document environmental and water‐depth changes, whereas bedset boundaries separating sedimentological cycles have a more subtle field appearance and are only associated with changes of environmental energy. Moreover, condensed deposits are present only above wave‐ravinement surfaces, and the high‐frequency sequences bounded by these surfaces have a thickness that is an order of magnitude greater than that of the bedsets. Micro‐foraminifera assemblages may change, and the content of heavy minerals usually increases, across wave‐ravinement surfaces, whereas both parameters do not change significantly across bedset boundaries. The abundance of heavy minerals is systematically higher, with respect to the underlying and overlying deposits, in the condensed shell beds that overlie wave‐ravinement surfaces. An integrated sedimentological, micropalaeontological and mineralogical approach represents a powerful tool to discriminate between wave‐ravinement surfaces bounding high‐frequency sequences and bedset boundaries, and in general to investigate at the intra high‐frequency sequence scale. This integrated approach is expected to be very useful in the study of potentially all shallow‐marine successions composed of small‐scale cycles, in order to delineate a detailed sequence stratigraphic framework and understand the factors that controlled the cyclicity.     

Explosion quakes at Stromboli (Italy)

This paper reports the results of two seismic experiments aimed at determining the wave field of explosion quakes at Stromboli Island (Mediterranean Sea, Southern Italy). The typical Strombolian activity mostly consists of explosive phenomena causing pyroclastic, materials to be emitted together with jets of volcanic gases from one or more craters. Stromboli is an active volcano characterized by persistent seismic activity consisting of explosion quakes that are seismic events associated with the explosive volcanic phenomena. Explosion quakes are short lived seismic events occurring intermittently whose amplitude tends to decrease with distance from the vent. A distinctive feature of explosion quakes is the presence on seismograms of two, often clearly distinct, seismic phases. The first, low-frequency seismic phase (<2 Hz) is in fact usually followed by a high-frequency seismic phase (>3–4 Hz) after one second or more. The first seismic phase of explosion quakes has been shown to be characterized by a nearly radial linear polarization and by an apparent propagation velocity estimated at 600–800 m/s. The second phase is characterized by a more chaotic motion and a lower apparent propagation velocity of 150–450 m/s. The wavefield associated with the first low-frequency seismic phase appears to be generated by a resonating P-wave seismic source accompanying gas explosion and emission of pyroclastic materials. The wavefield associated with the second high-frequency seismic phase of explosion quakes appears to be mainly composed of scattered and converted waves due to the critical topography of the volcano.     

Recharge estimation from discrete water-table datasets in a coastal shallow aquifer in a humid subtropical climate

A time-series approach to the estimation of recharge rate in unconfined aquifers of highly variable water level is proposed. The approach, which is based on the water-table fluctuation method (WTF), utilizes discrete water-level measurements. Other similar techniques require continuous measurements, which makes them impossible to apply in cases where no data from automatic loggers are available. The procedure is deployed at the Ressacada Farm site, southern Brazil, on a coastal shallow aquifer located in a humid subtropical climate where diurnal water-level variations of up to 1 m can follow a precipitation event. The effect of tidal fluctuations on the groundwater levels is analyzed using a harmonic component builder, while a time-variable drainage term is evaluated through an independent analysis and included in the assessment. The estimated recharge values are compared with those obtained from the continuous measurements showing a good agreement with the approaches for discrete dataset intervals of up to 15 days. Subsequently, the estimated recharge rates are incorporated into a transient groundwater-flow model and the water levels are compared showing a good match. Henceforth, the approach extends the applicability of WTF to noncontinuous water-level datasets in groundwater recharge studies.     

Generalised ultimate loads for pile groups

Acta Geotechnica - Foundation piles can be used as a means for increasing the capacity of the foundations under static loads or, at the same time, can be regarded as an additional source of energy...