Effect of two different habitats on spine and gonad colour in the purple sea urchin Paracentrotus lividus

This study investigates the effect of different Mediterranean habitats on spine and gonad colouring and gonadal index in the purple sea urchin Paracentrotus lividus (Echinodermata: Echinoidea). Specimens were collected in winter 2012 in Posidonia oceanica meadows and rocky bottom areas at two sites in Southern Sardinia (Italy, Tyrrhenian Sea). Colorimetric analyses of spines and gonads were conducted with a digital colorimeter using CIELAB colour spaces, which defines the colour in terms of three coordinate values: lightness (L*), redness (a*) and yellowness (b*). Lightness and redness of the spines differed significantly between habitats, whereas colour spaces of the gonads did not. A careful analysis of the gonad index showed it to be significantly affected by habitat, registering higher values in rocky bottom locations. In conclusion, it seems that habitat does affect spine colour but not gonad colour. Spine colour seems to be site‐dependent, whereas the gonad index depends solely on the habitat.     

Thorough wetting and drainage of a peat lysimeter in a climate change scenario

A peat deposit (Zennare basin, Venice coastland, Italy) was monitored in previous field studies to investigate the hydrological response of organic soil to meteorological dynamics. Field tests and modelling predictions highlighted the risk of the complete loss of this peat layer during the next 50 years, due to oxidation enhanced by the increased frequency of warmer periods. Unfortunately, despite the considerable impacts that are expected to affect peat bogs (in this area and worldwide), only a few experimental studies have been carried out to assess the hydrologic response of peat to severe water scarcity. Because of that, an undisturbed 0.7 m³ peat monolith was collected, transferred to the laboratory and instrumented. The total weight (representative of the water content dynamics of the peat monolith as a whole), and two vertical profiles of matric potentials and water content were monitored in controlled water-scarce conditions. After an extended air-drying period, the monolith was used as an undisturbed peat lysimeter and a complete cycle of wetting and drainage was performed. Supplementary measurements of matric potential ψ and water content θ were collected by testing peat subsamples on a suction table apparatus. A set of water retention curves was determined in a range of matric potentials broader (ψ down to −7 m) than the current natural conditions in the field (minimum ψ = −1 m). While water content at saturation showed values similar to those in the original natural conditions (θ ≅ 0.8), a remarkable loss of water holding capacity (even for low potentials) has been highlighted, especially in deep layers that are now permanently below the water table. The retention curves changed shape and values, with a more pronounced hysteresis visible in an increasing distance between wetting and drying data. Hydraulic non-equilibrium between the water content and water potential could be a possible cause and it is worth modelling in future studies. The parameters of the van Genuchten retention curves were obtained for the wetting and the drying phases.     

MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.     

Constraints on the bulk Lorentz factor in the internal shock scenario for gamma-ray bursts

We investigate, independently of specific emission models, the constraints on the value of the bulk Lorentz factor Γ of a fireball. We assume that the burst emission comes from internal shocks in a region transparent to Thomson scattering, and before deceleration caused by the swept-up external matter is effective. We consider the role of Compton drag in decelerating fast-moving shells before they interact with slower ones, thus limiting the possible differences in the bulk Lorentz factor of shells. Tighter constraints on the possible range of Γ are derived by requiring that the internal shocks transform more than a few per cent of the bulk energy into radiation. Efficient bursts may require a hierarchical scenario, where a shell undergoes multiple interactions with other shells. We conclude that fireballs with average Lorentz factors larger than 1000 are unlikely to give rise to the observed bursts.     

Observational constraints on the tropospheric and near-surface winter signature of the Northern Hemisphere stratospheric polar vortex

A composite analysis of Northern Hemisphere’s mid-winter tropospheric anomalies under the conditions of strong and weak stratospheric polar vortex was performed on NCEP/NCAR reanalysis data from 1948 to 2013 considering, as additional grouping criteria, the coincidental states of major seasonally relevant climate phenomena, such as El Niño-Southern Oscillation (ENSO), Quasi Biennial Oscillation and strong volcanic eruptions. The analysis reveals that samples of strong polar vortex nearly exclusively occur during cold ENSO states, while a weak polar vortex is observed for both cold and warm ENSO. The strongest tropospheric and near-surface anomalies are found for warm ENSO and weak polar vortex conditions, suggesting that internal tropospheric circulation anomalies related to warm ENSO constructively superpose on dynamical effects from the stratosphere. Additionally, substantial differences are found between the continental winter warming patterns under strong polar vortex conditions in volcanically-disturbed and volcanically-undisturbed winters. However, the small-size samples obtained from the multi-compositing prevent conclusive statements about typical patterns, dominating effects and mechanisms of stratosphere-troposphere interaction on the seasonal time scale based on observational/reanalysis data alone. Hence, our analysis demonstrates that patterns derived from observational/reanalysis time series need to be taken with caution as they not always provide sufficiently robust constraints to the inferred mechanisms implicated with stratospheric polar vortex variability and its tropospheric and near-surface signature. Notwithstanding this argument, we propose a limited set of mechanisms that together may explain a relevant part of observed climate variability. These may serve to define future numerical model experiments minimizing the sample biases and, thus, improving process understanding.     

Influence of the circumglobal wave-train on European summer precipitation

We investigate European summer (July–August) precipitation variability and its global teleconnections using the NCEP/NCAR reanalysis data (1950–2010) and a historical Coupled Model Intercomparison Project climate simulation (1901–2005) carried out using the ECHAM6/MPIOM climate model. A wavelike pattern is found in the upper tropospheric levels (200 hPa) similar to the summer circumglobal wave train (CGT) extending from the North Pacific to the Eurasian region. The positive phase of the CGT is associated with upper level anomalous low (high) pressure over western (eastern) Europe. It is further associated with a dipole-like precipitation pattern over Europe entailing significantly enhanced (reduced) precipitation over the western (eastern) region. The anomalous circulation features and associated summer precipitation pattern over Europe inverts for the negative CGT phase. Accordingly, the global teleconnection pattern of a precipitation index summarizing summer precipitation over Western Europe entails an upper level signature which consists of a CGT-like wave pattern extending from the North Pacific to Eurasia. The imprint of the CGT on European summer precipitation is distinct from that of the summer North Atlantic Oscillation, despite the two modes of variability bear strong similarities in their upper level atmospheric pattern over Western Europe. The analysis of simulated CGT features and of its climatic implications for the European region substantiates the existence of the CGT-European summer precipitation connection. The summer CGT in the mid-latitude therefore adds to the list of the modes of large-scale atmospheric variability significantly influencing European summer precipitation variability.     

Structure of magnetite (Fe<Subscript>3</Subscript>O<Subscript>4</Subscript>) above the Curie temperature: a cation ordering study

A pristine magnetite (Fe₃O₄) specimen was studied by means of Neutron Powder Diffraction in the 273–1,073 K temperature range, in order to characterize its structural and magnetic behavior at high temperatures. An accurate analysis of the collected data allowed the understanding of the behavior of the main structural and magnetic features of magnetite as a function of temperature. The magnetic moments of both tetrahedral and octahedral sites were extracted by means of magnetic diffraction up to the Curie temperature (between 773 and 873 K). A change in the thermal expansion coefficient around the Curie temperature together with an increase in the oxygen coordinate value above 700 K can be observed, both features being the result of a change in the thermal expansion of the tetrahedral site. This anomaly is not related to the magnetic transition but can be explained with an intervened cation reordering, as magnetite gradually transforms from a disordered configuration into a partially ordered one. Based on a simple model which takes into account the cation-oxygen bond length, the degree of order as a function of temperature and consequently the enthalpy and entropy of the reordering process were determined. The refined values are ΔH⁰ = −23.2(1.7) kJ mol⁻¹ and ΔS⁰ = −16(2) J K⁻¹ mol⁻¹. These results are in perfect agreement with values reported in literature (Mack et al. in Solid State Ion 135(1–4):625–630, 2000; Wu and Mason in J Am Ceramic Soc 64(9):520–522, 1981).     

Robust resolution of Kepler’s equation in all eccentricity regimes

The singularity for the big bang state can be represented using the generalized anisotropic Friedmann equation, resulting in a system of differential equations in a central force field. We study the regularizability of this singularity as a function of a parameter, the equation of state, w. We prove that for w > 1 it is regularizable only for w satisfying relative prime number conditions, and for w ≤ 1 it can always be regularized. This is done by using a McGehee transformation, usually applied in the three and four-body problems. This transformation blows up the singularity into an invariant manifold. The relationship of this result to other cosmological models is briefly discussed.