On the sulphur chemistry of a super-anoxic fjord, Framvaren, South Norway

The concentrations of total carbonate (C_t), sulphate, sulphide, thiols and oxygen, the ratio between the stable sulphur isotopes ³⁴S and ³²S in sulphate and sulphide, and the density (used to calculate salinity) were determined on samples from the water column of Framvaren, a superanoxic fjord in southern Norway. From a depth of 18m (the oxic-anoxic boundary) the initial sulphate concentration, ([SO₄]_init), as calculated from salinity, is significantly higher than the sum of the measured sulphur species. This is attributed to a loss of sulphur from the water column. The amount of total carbonate produced, corrected for the initial concentration (C_t - 2.4 Sal/35) is found to be proportional to the amount of sulphate consumed, ([SO₄]_init - [SO₄]), according to the following relation C_t- 2.4 Sal/35 = 1.84 ([SO₄]_init - [SO₄]). Isotopic fractionation caused by bacterial sulphate reduction in the anoxic part of the water column produces sulphide with a δ³⁴S 40‰ lower than the δ³⁴S for sulphate at corresponding depths. The isotopic fractionation also results in δ³⁴S value for the remaining sulphate at depths below 80 m being considerably higher than the mean value for ocean water, which is close to + 20‰. The δ³⁴S values for sulphate at depths between 10 and 50 m were lower than + 20‰ which indicates oxidation of sulphide, which follows upon diffusion of sulphide from deeper parts of the water column and inflow of oxygenated seawater over the sill into the anoxic water of the fjord. A conclusive scenario of the Framvaren sulphur chemistry is presented.     

Risk Management for Petroleum Reservoir Production: A Simulation-Based Study of Prediction

We consider numerical solutions of the Darcy and Buckley–Leverett equations for flow in porous media. These solutions depend on a realization of a random field that describes the reservoir permeability. The main content of this paper is to formulate and analyze a probability model for the numerical coarse grid solution error. We explore the extent to which the coarse grid oil production rate is sufficient to predict future oil production rates. We find that very early oil production data is sufficient to reduce the prediction error in oil production by about 30%, relative to the prior probability prediction.     

Statewide Estimates of Undiscovered Deposits of Gold,Silver, Copper,Lead, and Zinc

Estimates of the number of undiscovered deposits on a statewide basis offer a different perspective on the nation's undiscovered resources of gold, silver, copper, lead, and zinc. Mean estimates of the number of undiscovered deposits statewide were extracted from the estimates of undiscovered deposits nationwide. More than 50 undiscovered deposits are estimated to occur in Alaska, Arizona, Nevada, and Wisconsin. Estimating the number of undiscovered deposits statewide serves as a measure of a state's total remaining mineral resources in known conventional deposit types.     

Flow and form in rehabilitation of large-river ecosystems: An example from the Lower Missouri River

On large, intensively engineered rivers like the Lower Missouri, the template of the physical habitat is determined by the nearly independent interaction of channel form and flow regime. We evaluated the interaction between flow and form by modeling four combinations of modern and historical channel form and modern and historical flow regimes. The analysis used shallow, slow water (shallow-water habitat, SWH, defined as depths between 0 and 1.5 m, and current velocities between 0 and 0.75 m/s) as an indicator of habitat that has been lost on many intensively engineered rivers and one that is thought to be especially important in rearing of young fishes. Two-dimensional hydrodynamic models for modern and historical channels of the Lower Missouri River at Hermann, Missouri, indicate substantial differences between the two channels in total availability and spatial characteristics of SWH. In the modern channel, SWH is maximized at extremely low flows and in overbank flows, whereas the historical channel had substantially more SWH at all discharges and SWH increased with increasing discharge. The historical channel form produced 3–7 times the SWH area of the modern channel regardless of flow regime. The effect of flow regime is evident in increased within-year SWH variability with the natural flow regime, including significant seasonal peaks of SWH associated with spring flooding. Comparison with other reaches along the Lower Missouri River indicates that a) channel form is the dominant control of the availability of habitat even in reaches where the hydrograph is more intensively altered, and b) rehabilitation projects that move toward the historical condition can be successful in increasing topographic diversity and thereby decreasing sensitivity of the availability of habitat to flow regime. The relative efficacy of managing flow and form in creating SWH is useful information toward achieving socially acceptable rehabilitation of the ecosystem in large river systems.     

An array of lens-coupled antennas for cosmic microwave background measurements in the 30 Ghz band

An array of bow-tie slot antennas coupled through an extended hemispherical lens is proposed to operate in the 30?GHz frequency band. The design includes a combination of three microstrip Wilkinson power dividers (WPD) and transitions to coplanar wave guides (CPW) to form the feeding antenna network. This configuration is suitable for the integration with heterodyne imaging detectors commonly used in radioastronomy. Measurements and simulation results exhibit a frequency range of operation from 20 to 40?GHz with a bandwidth of 24% achieved for ?10?dB return loss at the central frequency. The measured radiation patterns show a maximum peak gain of around 13?dB with HPBW of 10° for the E-plane, and whose first side lobes are lower than 13?dB below the main lobe in both angular shift sides. The presented results will be considered as preliminary feasibility studies in the 30?GHz QUIJOTE-CMB Instrument, which is designed to study the anisotropies of the Cosmic Microwave Background (CMB).     

The sedimentary and tectonic evolution of the Amur River and North Sakhalin Basin: new evidence from seismic stratigraphy and Neogene–Recent sediment budgets

The North Sakhalin Basin in the western Sea of Okhotsk has been the main site of sedimentation from the Amur River since the Early Miocene. In this article, we present regional seismic reflection data and a Neogene–Recent sediment budget to constrain the evolution of the basin and its sedimentary fill, and consider the implications for sediment flux from the Amur River, in particular testing models of continental‐scale Neogene drainage capture. The Amur‐derived basin‐fill history can be divided into five distinct stages: the first Amur‐derived sediments (>21–16.5 Ma) were deposited during a period of transtension along the Sakhalin‐Hokkaido Shear Zone, with moderately high sediment flux to the basin (71 Mt year^?1). The second stage sequence (16.5–10.4 Ma) was deposited following the cessation of transtension, and was characterised by a significant reduction in sediment flux (24 Mt year^?1) and widespread retrogradation of deltaic sediments. The third (10.4–5.3 Ma) and fourth (5.3–2.5 Ma) stages were characterised by progradation of deltaic sediments and an associated increase in sediment flux (48–60 Mt year^?1) to the basin. Significant uplift associated with regional transpression started during this time in southeastern Sakhalin, but the north‐eastward propagating strain did not reach the NE shelf of Sakhalin until the Pleistocene (<2.5 Ma). This uplift event, still ongoing today, resulted in recycling of older deltaic sediments from the island of Sakhalin, and contributed to a substantially increased total sediment flux to the adjacent basinal areas (165 Mt year^?1). Adjusted rates to discount these local erosional products (117 Mt year^?1) imply an Amur catchment‐wide increase in denudation rates during the Late Pliocene–Pleistocene; however, this was likely a result of global climatic and eustatic effects, combined with tectonic processes within the Amur catchment and possibly a smaller drainage capture event by the Sungari tributary, rather than continental‐scale drainage capture involving the entire upper Amur catchment.     

Origin of ultramafic xenoliths containing exsolved pyroxenes from Hualalai Volcano,Hawaii

Hualalai Volcano, Hawaii, is best known for the abundant and varied xenoliths included in the historic 1800 Kaupulehu alkalic basalt flow. Xenoliths, which range in composition from dunite to anorthosite, are concentrated at 915-m elevation in the flow. Rare cumulate ultramafic xenoliths, which include websterite, olivine websterite, wehrlite, and clinopyroxenite, display complex pyroxene exsolution textures that indicate slow cooling. Websterite, olivine websterite, and one wehrlite are spinel-bearing orthopyroxene +olivine cumulates with intercumulus clinopyroxene +plagioclase. Two wehrlite samples and clinopyroxenite are spinel-bearing olivine cumulates with intercumulus clinopyroxene+orthopyroxene + plagioclase. Two-pyroxene geothermometry calculations, based on reconstructed pyroxene compositions, indicate that crystallization temperatures range from 1225° to 1350° C. Migration or unmixing of clinopyroxene and orthopyroxene stopped between 1045° and 1090° C. Comparisons of the abundance of K₂O in plagioclase and the abundances of TiO₂ and Fe₂O₃in spinel of xenoliths and mid-ocean ridge basalt, and a single ⁸⁷Sr/ ⁸⁶Sr determination, indicate that these Hualalai xenoliths are unrelated to mid-ocean ridge basalt. Similarity between the crystallization sequence of these xenoliths and the experimental crystallization sequence of a Hawaiian olivine tholeiite suggest that the parental magma of the xenoliths is Hualalai tholeiitic basalt. Xenoliths probably crystallized between about 4.5 and 9 kb. The 155°–230° C of cooling which took place over about 120 ka — the age of the youngest Hualalai tholeiitic basalt — yield maximum cooling rates of 1.3×10^–3–1.91×10^–3 °C/yr. Hualalai ultramafic xenoliths with exsolved pyroxenes crystallized from Hualalai tholeiitic basalt and accumulated in a magma reservoir located between 13 and 28 km below sealevel. We suspect that this reservoir occurs just below the base of the oceanic crust at about 19 km below sealevel.     

Multicollinearity and correlation among local regression coefficients in geographically weighted regression

Present methodological research on geographically weighted regression (GWR) focuses primarily on extensions of the basic GWR model, while ignoring well-established diagnostics tests commonly used in standard global regression analysis. This paper investigates multicollinearity issues surrounding the local GWR coefficients at a single location and the overall correlation between GWR coefficients associated with two different exogenous variables. Results indicate that the local regression coefficients are potentially collinear even if the underlying exogenous variables in the data generating process are uncorrelated. Based on these findings, applied GWR research should practice caution in substantively interpreting the spatial patterns of local GWR coefficients. An empirical disease-mapping example is used to motivate the GWR multicollinearity problem. Controlled experiments are performed to systematically explore coefficient dependency issues in GWR. These experiments specify global models that use eigenvectors from a spatial link matrix as exogenous variables.This study was supported by grant number 1 R1 CA95982-01, Geographic-Based Research in Cancer Control and Epidermiology, from the National Cancer Institute. The author thank the anonymous reviewers and the editor for their helpful comments.     

Short-term residence and movement patterns of the annular seabream Diplodus annularis in a temperate marine reserve

The short-term movements of a small temperate fish, the annular seabream Diplodus annularis (Linnaeus 1758), were examined using standard tag-recapture and passive acoustic telemetry in Palma Bay (NW Mediterranean), a marine protected area (MPA). The study aimed to provide valuable information for assessing the recreational fishery and its results suggest that MPAs can be used to protect the adult stock of D. annularis. All the fish tagged with standard tags were recaptured near the release locations, with a maximum distance of ∼300 m. The maximum time between release and recapture was 185 d. Two different arrays of acoustic receivers were deployed, one in 2008 and another in 2009, within the MPA. Twenty adults were surgically tagged with acoustic transmitters. Fish monitored in 2008 (n = 12) were translocated from the point of capture to analyse the movement behaviour after artificial displacement. Upon release at displaced locations, 67% of the fish moved towards the original capture location using a time of return that ranged from 0.75 to 15.25 h. Fish monitored in 2009 (n = 8) were released at the point of capture. They showed high site fidelity with a maximum period of 27 d between the first time and the last time they were detected.