The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

H 187 - At the Onset of a New Eclipse

CCD photometry data of the T Tauri star H 187 are presented. They show that a new eclipse of this star began at the end of 2004. Since only one eclipse of this star has been observed previously with a duration of 3.5 years, our data indicate that the eclipses of this object are periodic with a period P=4.9 years between eclipses. Thus, in terms of the absolute duration of the eclipses and in terms of their relative length as a fraction of the period, H 187 is one of the most exotic objects in the sky. __________ Translated from Astrofizika, Vol. 48, No. 4, pp. 529–534 (November 2005).     

Variability of parameters of the <Emphasis Type="Italic">F</Emphasis>2-layer maximum in the quiet midlatitude ionosphere under low solar activity: 1. Statistical properties

Results of statistical analysis of the properties of variability of F2-layer maximum parameters (critical frequency foF2 and the height hmF2) in quiet midlatitude ionosphere under low solar activity in the daytime (1000–1500 LT) and nighttime (2200–0300 LT) hours are presented on the basis of Irkutsk station data for 2007–2008. It is found that the distribution density of δfoF2 could be presented as consisting of two distinctly different normal laws of this distribution, one of which corresponds to weak (|δfoF2| < 10%) fluctuations in foF2 and the other corresponds to strong (30% > |δfoF2| > 10%) fluctuations. Weak fluctuations in foF2 to a substantial degree are related to ionospheric variability at times less of than 1–3 h and determine the δfoF2 variability in the daytime hours. Strong fluctuations in foF2 are mainly related to day-to-day variability of the ionosphere at a fixed local time, the variability increasing by approximately a factor of 3 during the transition from day to night and determining the δfoF2 variability in the nighttime hours. The distribution density of ΔhmF2 is close to the normal distribution law. An interpretation of the different character of the distribution densities of δfoF2 and ΔhmF2 is given.     

Spread <Emphasis Type="Italic">F</Emphasis> in the Midlatitude Ionosphere According to DPS-4 Ionosonde Data

The results of studying spread F obtained from the DPS-4 ionosonde data at the observatory of the Pushkov Institute of Terrestrial Magnetism, Ionosphere, and Radio Wave Propagation (Moscow) are presented. The methodical questions that arise during the study of a spread F phenomenon in the ionosphere are considered; the current results of terrestrial observations are compared with previously published data and the results of sounding onboard an Earth-satellite vehicle. The automated algorithm for estimation of the intensity of frequency spread F, which was developed by the authors and was successfully verified via comparison of the data of the digisonde DPS-4 and the results of manual processing, is described. The algorithm makes it possible to quantify the intensity of spread F in megahertz (the dFs parameter) and in the number of points (0, 1, 2, 3). The strongest spread (3 points) is shown to be most likely around midnight, while the weakest spread (0 points) is highly likely to occur during the daytime. The diurnal distribution of a 1–2 point spread F in the winter indicates the presence of additional maxima at 0300–0600 UT and 1400–1700 UT, which may appear due to the terminator. Despite the large volume of processed data, we can not definitively state that the appearance of spread F depends on the magnetic activity indices Kp, Dst, and AL, although the values of the dFs frequency spread interval strongly increased both at day and night during the magnetic storm of March 17–22, 2015, especially in the phase of storm recovery on March 20–22.     

Saturation of groundwaters with respect to minerals of the host rocks

Calculations of the saturation of groundwaters with respect to minerals of the rocks hosting these waters indicate that most of the analyzed groundwaters were saturates with respect to calcite, dolomite, and quartz. Brines of chloride-calcic composition were determined to be saturated with respect to calcite, whereas brines of chloride-sodic composition are saturated with respect to dolomite and quartz. The solution was simultaneously saturated with respect to six minerals for the association ankerite-calcite-dolomite-pyrite-quartz-strontianite. An increase in the number of minerals with respect to which solution is saturated is correlated with an increase in the diversity of types of groundwaters and an increase in the runoff rate. The paper proposes possible avenues for searches for relations between hydrogeological and geochemical parameters that make it possible to adapt the thermodynamic models to real geological-hydrogeological conditions. The research was centered on the testing of groundwaters for their saturation with respect to minerals of the rocks hosting these waters. This parameter plays a significant part in forming the geochemical type of natural waters because it reflects the crystallization of a mineral from a solution and, consequently, the removal of an element from the aqueous solution.     

Evaluation of Interactions Between Oilfield Chemicals and Reservoir Rocks

Natural Resources Research - Sand failure and production occurs when the formation stress exceeds the strength of the formation, which is derived majorly from the natural material that cements the...