Deposition and provenance of the Early Pleistocene Siliceous Member in Westbury Cave,Somerset, England

The Early Pleistocene is an important interval in the Quaternary period as a time not only of climatic and environmental change, but also of key events in human evolution. However, knowledge of this period in northwest Europe is hampered by the limited extent of deposits of this age. Westbury Cave in the Mendip Hills of Somerset preserves an understudied example of fossil-bearing Early Pleistocene sediments, with rare potential to inform our understanding of British Early Pleistocene stratigraphy and landscape evolution outside the East Anglian Crag Basin. This study identifies the processes responsible for deposition of the Early Pleistocene Siliceous Member in Westbury Cave, thereby aiding taphonomic and palaeoenvironmental interpretations of associated fossil assemblages. New excavations revealed over ten metres of Siliceous Member stratigraphy, dominated by fine-grained silts/clays with interbedded sands and gravels, interpreted as being deposited within a subterranean lake or flooded conduit with fluvial input. All sediments sampled were reversely magnetised and are assigned to the Matuyama Reversed Chron. Lithological analysis of gravel clasts revealed variable components of durable non-local and non-durable local clasts. Gravels containing the latter are interpreted as distal talus slope deposits, and those lacking non-durable lithologies as stream or flood deposits. However, it remains unclear from available data whether apparently non-local clasts were sourced from long distance or stem from a more local, now denuded catchment. Siliceous Member bio- and magnetostratigraphy suggest that deposition occurred late in the Early Pleistocene, a period apparently otherwise unrepresented in the UK.     

Iron oxyhydroxide coating of pyrite for acid mine drainage control

When pyrite oxidizes at near neutral pH in the presence of sufficient alkalinity, Fe oxyhydroxide coatings develop on the surface. As these coatings grow thicker and denser they block oxidant transport from the solution to the pyrite surface and reduce the rate of pyrite oxidation. The authors’ measurements of pyrite oxidation rates in a NaHCO₃ solution show that the coating grows in two stages. In the first stage Fe oxyhydroxide colloids form and then attach to the pyrite surface to produce a slight reduction in oxidant transport. In the second stage interstitial precipitation of Fe oxyhydroxide material between the colloidal particles reduces the oxidant’s diffusion coefficient by more than five orders of magnitude. This causes the pyrite oxidation rate to decline as the square root of time. The kinetic predominance diagram, which compares the rates of Fe transformation reactions, shows that when pyrite oxidation releases Fe quickly enough for the total Fe concentration to rise to about 10⁻⁸ m, ferrihydrite forms but lower rates of Fe release will not produce coatings. Extrapolation of the results to longer times predicts that pyrite-bearing materials need to be treated with an extra source of alkalinity for several decades to produce coatings that are thick enough to be sustained by alkalinity levels typical of groundwater. However, once the coatings develop no additional treatment is needed and further pyrite oxidation simply causes the coating to grow thicker and denser until the entire pyrite grain is pseudomorphically replaced by goethite.     

Recent climate variability and its impacts on soybean yields in Southern Brazil

Recent climate variability in rainfall, temperatures (maximum and minimum), and the diurnal temperature range is studied with emphasis on its influence over soybean yields in southern Brazil, during 1969 to 2002. The results showed that the soybean (Glycine max L. Merril) yields are more affected by changes in temperature during summer, while changes in rainfall are more important during the beginning of plantation and at its peak of development. Furthermore, soybean yields in Paraná are more sensitive to rainfall variations, while soybean yields in the Rio Grande do Sul are more sensitive to variations in temperature. Effects of interannual climatic variability on soybean yields are evaluated through three agro-meteorological models: additive Stewart, multiplicative Rao, and multiplicative Jensen. The Jensen model is able to reproduce the interannual behavior of soybean yield reasonably well.     

The Experiences of Weak and Non-Swimmers Caught in Rip Currents at Australian Beaches

Beach rip currents present a risk to weak and non-swimmers, whose limited open water swim competencies may render them incapable of swimming out of these common and strong offshore flows. Here, the aim has been to explore this group's vulnerability by identifying how the limits of their swimming competencies influence their abilities to successfully execute a rip current exit strategy. It provides empirical detail on their knowledge of rip currents, their behavioural responses when caught in the rip current, the advice they recalled and the educational messages they recommend to other swimmers. A secondary aim has been to begin a dialogue that recognises the capacity of the Australian beach cultures—as places of relaxation and natural beauty—to influence people's decisions to enter the water. This cultural contextualisation may help explain why some self-identified weak and non-swimmers still enter the water despite their limited competencies. Through a synthesis of survey and interview data, we argue that weak and non-swimmers need to take the threat of rip currents seriously. Pre-emptive safety advice should be sought, especially if people intend to swim regardless of their swimming ability.     

Uptake and metabolism of arsenate by anexic cultures of the microalgae Dunaliella tertiolecta and Phaeodactylum tricornutum

Axenic cultures of the microalgae species, Dunaliella tertiolecta and Phaeodactylum tricornutum were grown at arsenic (As) concentrations typically found in uncontaminated marine environments ( 2 µg L^− 1) under different phosphorus concentrations. D. tertiolecta accumulated higher arsenic concentrations (mean: 13.7 ± 0.7 µg g^− 1 dry mass) than P. tricornutum (mean: 1.9 ± 0.2 µg g−1 dry mass). Media phosphorus concentrations (0.6–3 mg/L) had little influence on microalgae growth rates or arsenic accumulation. Arsenic was present as lipid bound (29–38%; 4.2–9.5%), water-soluble (20–29%; 26–34%) and residue bound (41–45%; 57–69%) arsenic species in D. tertiolecta and P. tricornutum respectively. Hydrolysed lipids contained mostly glycerol arsenoribose (OH- ribose), dimethylarsinate (DMA) and inorganic arsenic (As(V)) moieties. Water-soluble species of microalgae were very different. D. tertiolecta contained inorganic arsenic (54–86%) with variable amounts of DMA (7.4–20%), arsenoriboses (5–25%) and traces of methylarsonate (MA) ( 1%). P. tricornutum contained mostly DMA (32–56%) and phosphate arsenoribose (PO₄-ribose, 23–49%) and small amounts of OH-ribose (3.8–6.5%) and As(V) (9–16%). Both microalgae contained an unknown cationic arsenic species. The residue fractions of both microalgae contained predominately inorganic arsenic (99–100%). These results show that at natural seawater arsenic concentrations, both algae take up substantial amounts of inorganic arsenic that is complexed with structural elements or sequestered in vacuoles as stable complexes. A significant portion is also incorporated into lipids. Arsenic is metabolised to simple methylated species and arsenoriboses.     

Erosion of rocky shore platforms by block detachment from layered stratigraphy

The majority of shore platforms form in rocks that are characterised by layered stratigraphy and pervasive jointing. Plucking of weathered, joint and bed bounded blocks is an important erosion process that existing models of platform development do not represent. Globally, measuring platform erosion rates have focused on microscale (< 1 mm) surface lowering rather than mesoscale (0.1-1 m) block detachment, yet the latter appears to dominate the morphological development of discontinuity rich platforms. Given the sporadic nature of block detachment on platforms, observations of erosion from storm event to multi-decadal timescales (and beyond) are required to quantify shore platform erosion rates. To this end, we collected aerial photography using an unmanned aerial vehicle to produce structure-from-motion-derived digital elevation models and orthophotos. These were combined with historical aerial photographs to characterise and quantify the erosion of two actively eroding stratigraphic layers on a shore platform in Glamorgan, south Wales, UK, over 78-years. We find that volumetric erosion rates vary over two orders of magnitude (0.1-10 m³ yr^-1) and do not scale with the length of the record. Average rates over the full 78-year record are 2-5 m³ yr^-1. These rates are equivalent to 1.2-5.3 mm yr^-1 surface lowering rates, an order of magnitude faster than previously published, both at our site and around the world in similar rock types. We show that meso-scale platform erosion via block detachment processes is a dominant erosion process on shore platforms across seasonal to multi-decadal timescales that have been hitherto under-investigated. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd