Extraterrestrial organic compounds and cyanide in the CM2 carbonaceous chondrites Aguas Zarcas and Murchison

Evaluating the water‐soluble organic composition of carbonaceous chondrites is key to understanding the inventory of organic matter present at the origins of the solar system and the subsequent processes that took place inside asteroid parent bodies. Here, we present a side‐by‐side analysis and comparison of the abundance and molecular distribution of aliphatic amines, aldehydes, ketones, mono‐ and dicarboxylic acids, and free and acid‐releasable cyanide species in the CM2 chondrites Aguas Zarcas and Murchison. The Aguas Zarcas meteorite is a recent fall that occurred in central Costa Rica and constitutes the largest recovered mass of a CM‐type meteorite after Murchison. The overall content of organic species we investigated was systematically higher in Murchison than in Aguas Zarcas. Similar to previous meteoritic organic studies, carboxylic acids were one to two orders of magnitude more abundant than other soluble organic compound classes investigated in both meteorite samples. We did not identify free cyanide in Aguas Zarcas and Murchison; however, cyanide species analyzed after acid digestion of the water‐extracted meteorite mineral matrix were detected and quantified at slightly higher abundances in Aguas Zarcas compared to Murchison. Although there were differences in the total abundances of specific compound classes, these two carbonaceous chondrites showed similar isomeric distributions of aliphatic amines and carboxylic acids, with common traits such as a complete suite of structural isomers that decreases in concentration with increasing molecular weight. These observations agree with their petrologic CM type‐2 classification, suggesting that these meteorites experienced similar organic formation processes and/or conditions during parent body aqueous alteration.     

The finite volume method for Richards equation

In this paper we prove the convergence of a finite volume scheme for the discretization of an elliptic–parabolic problem, namely Richards equation β(P)_t?div(K(β(P))× ?(P+z))=0, together with Dirichlet boundary conditions and an initial condition. This is done by means of a priori estimates in L² and the use of Kolmogorov's theorem on relative compactness of subsets of L².     

Resident Attitudes to Farmland Protection Measures in the Northern Rivers Region,New South Wales

In-migration to popular ‘sea change’ and ‘tree change’ regions has produced conflicts between rural land users. In the Northern Rivers region of New South Wales, new residential developments have been built on much of what was previously prime agricultural land, while farmers (in particular, those negatively affected by the deregulation of the dairy industry) have sought to secure retirement incomes by subdividing land for sale. Although developers, local councils and individual farmers sometimes see eye to eye on the mutual benefits of in-migration and population growth, land use has none the less become the subject of a hotly contested local political battle. Conflicts occur at the interface of growing urban developments and surrounding farmland, with new residents finding the sights, sounds and smells of rural production intrusive. More generally, there is considerable concern that the best farmland in the region may be lost to urbanisation and rural residential subdivision. This paper discusses the results of a survey that collected opinions from local residents about the pressures on the region's land uses by in-migration, the future role of farmland as both an economic and cultural landscape, and views on proposed measures to protect prime farmland in the region. Results highlighted a strong and consistent ‘pro-farmland’ and ‘pro-protection’ attitude throughout the region, and across social groups. Yet, variations emerged when respondents were asked about why they attribute value to agricultural landscapes. For some, ‘economic’ values dominated, while for others, value was attributed in ways that reflected an emerging ethos of ‘localism’ and village lifestyle. Although values differed, a clear message from this study is that the population of Australia's pre-eminent ‘sea change’ region strongly support measures to curb urban development and the more destructive consequences of a dynamic property market.     

Distinct erosional progressions in the Medusae Fossae Formation, Mars, indicate contrasting environmental conditions

The form of erosional remnants of the Medusae Fossae Formation (MFF) on Mars provide evidence of their development progression and implicate two spatially distinct environments in the equatorial regions of Mars. Ubiquitous yardangs are clearly the product of strong unidirectional winds acting over time on variably indurated deposits. Yardang orientation is used as a proxy to map regional and local wind direction at meso-scale resolution. In other, more limited areas not subjected to strong unidirectional winds, randomly oriented kilometer-scale mesas and buttes are found to be remnants of progressive cliff recession through mass wasting as support is lost from within the MFF lithology at its margins. The differing processes that dominate the formation of the distinctive landforms have implications for meso-scale variations in climate that remain unresolved by current modeling efforts. Additionally, the variability of erosional forms within the deposit emphasizes the overall complexity of this extensive formation.     

Investigations into a small fraction of volatile hydrocarbons: III. Two diatom cultures produce ectocarpene, a pheromone of brown algae

Ectocarpene was extracted from cultures of Skeletonema costatum and probably in traces from cultures of Lithodesmium undulatum shortly after a change in the light regime which is known to induce formation of gametes.     

Sensitivity of the active fracture model parameter to fracture network orientation and injection scenarios

Active fractures refer to the portions of unsaturated, connected fractures that actively conduct water. The active fracture model parameter accounts for the reduction in the number of fractures carrying water and in the fracture–matrix interface area in field-scale simulations of flow and transport in unsaturated fractured rocks. One example includes the numerical analyses of the fault test results at the Yucca Mountain site, Nevada (USA). In such applications, the active fracture model parameter is commonly used as a calibration parameter without relating it to fracture network orientations and infiltration rates. A two-dimensional, multiphase lattice-Boltzmann model was used in this study to investigate the sensitivity of the active fracture model parameter to fracture network orientation and injection scenarios for an unsaturated, variable dipping, and geometrically simple fracture network. The active fracture model parameter differed by as much as 0.11–0.44 when the effects of fracture network orientation, injection rate, and injection mode were included in the simulations. Hence, the numerical results suggest that the sensitivity of the active fracture model parameter to fracture network orientation, injection rates, and injection modes should be explored at the field-scale to strengthen the technical basis and range of applicability of the active fracture model.     

Influence of Shallow Geology on Volatile Organic Chemical Attenuation from Groundwater to Deep Soil Gas

Vapor intrusion pathway evaluations commonly begin with a comparison of volatile organic chemical (VOC) concentrations in groundwater to generic, or Tier 1, screening levels. These screening levels are typically quite low reflecting both a desired level of conservatism in a generic risk screening process as well as limitations in understanding of physical and chemical processes that impact vapor migration in the subsurface. To study the latter issue, we have collected detailed soil gas and groundwater vertical concentration profiles and evaluated soil characteristics at seven different sites overlying chlorinated solvent contaminant plumes. The goal of the study was to evaluate soil characteristics and their impacts on VOC attenuation from groundwater to deep soil gas (i.e., soil gas in the unsaturated zone within 2 feet of the water table). The study results suggest that generic screening levels can be adjusted by a factor of 100× at sites with fine‐grained soils above the water table, as identified by visual observations or soil air permeability measurements. For these fine‐grained soil sites, the upward‐adjusted screening levels maintain a level of conservatism while potentially eliminating the need for vapor intrusion investigations at sites that may not meet generic screening criteria.     

Living on the Edge: Increasing Patch Size Enhances the Resilience and Community Development of a Restored Salt Marsh

Foundation species regulate communities by reducing environmental stress and providing habitat for other species. Successful restoration of biogenic habitats often depends on restoring foundation species at appropriate spatial scales within a suitable range of environmental conditions. An improved understanding of the relationship between restoration scale and environmental conditions has the potential to improve restoration outcomes for many biogenic habitats. Here, we identified and tested whether inundation/exposure stress and spatial scale (patch size) can interactively determine (1) survival and growth of a foundation species, Spartina alterniflora and (2) recruitment of supported fauna. We planted S. alterniflora and artificial mimics in large and small patches at elevations above and below local mean sea level (LMSL) and monitored plant survivorship and production, as well as faunal recruitment. In the first growing season, S. alterniflora plant survivorship and stem densities were greater above LMSL than below LMSL regardless of patch size, while stem height was greatest in small patches below LMSL. By the third growing season, S. alterniflora patch expansion was greater above LMSL than below LMSL, while stem densities were higher in large patches than small patches, regardless of location relative to LMSL. Unlike S. alterniflora, which was more productive above LMSL, sessile marine biota recruitment to mimic plants was higher in patches below LMSL than above LMSL. Our results highlight an ecological tradeoff at ~LMSL between foundation species restoration and faunal recruitment. Increasing patch size as inundation increases may offset this tradeoff and enhance resilience of restored marshes to sea-level rise.