Equilibrium and disequilibrium degassing of a phonolitic melt (Vesuvius AD 79 “white pumice”) simulated by decompression experiments

Equilibrium and disequilibrium degassing of a volatile phase from a magma of K-phonolitic composition was investigated to assess its behavior upon ascent. Decompression experiments were conducted in Ar-pressurized externally heated pressure vessels at superliquidus temperature (1050 °C), in the pressure range 10–200 MPa using pure water as fluid phase. All experiments were equilibrated at 200 MPa and then decompressed to lower pressures with rates varying from 0.0028 to 4.8 MPa/s. Isobaric saturation experiments were performed at the same temperature and at 900–950 °C to determine the equilibrium water solubility in the pressure range 30–250 MPa. The glasses obtained from decompression experiments were analyzed for their dissolved water content, vesicularity and bubble size distribution. All decompressed samples presented a first event of bubble nucleation at the capsule–melt interface. Homogeneous bubble nucleation in the melt only occurred in fast-decompressed experiments (4.8 and 1.7 MPa/s), for ΔP ≅ 100 MPa. For these decompression rates high water over-saturations were maintained until a rapid exsolution was triggered at ΔP > 150 MPa. For slower rates (0.0028, 0.024, 0.17 MPa/s) the degassing of the melt took place by diffusive growth of the bubbles nucleating at the capsule–melt interface. This process sensibly reduced water over-saturation in the melt, preventing homogeneous nucleation to occur. For decompression rates of 0.024 and 0.17 MPa/s low water over-saturations were attained in the melt, gradually declining toward equilibrium concentrations at low pressures. A near-equilibrium degassing path was observed for a decompression rate of 0.0028 MPa/s. Experimental data combined with natural pumice textures suggest that both homogeneous and heterogeneous bubble nucleations occurred in the phonolitic magma during the AD 79 Vesuvius plinian event. Homogeneous bubble nucleation probably occurred at a depth of ∼ 3 km, in response to a fast decompression of the magma during the ascent.     

Comparison between Pollutant Concentration in the Samples of Fog and Rime Water Collected at Mt. Milešovka

The article aims at showing the differences in concentration of pollutants that are contained in the samples of fog and/or low cloud water in comparison with the water from rime. The results follow from the fog and rime measurements made at Mt. Mileovka (eské Stedohoí Mountains). They are compared with the results of other studies that also report the differences in fog and rime chemistry.     

The Seashell Wastes as Biosorbent for Reactive Dye Removal from Textile Effluents

This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L^?1), dye concentration (50–300 mg L^?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L^?1, dye initial concentration of 50–50 mg L^?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters.     

The influence of local topography for wind direction on Mars: two examples of dune fields in crater basins

In this work, we perform an analysis of large dark dunes within Moreux Crater and Herschel Crater on Mars using High Resolution Imaging Science Experiment (HiRISE) and Context Camera (CTX) data sets. These data allow us to conduct a detailed analysis of dune morphology and slip faces, concluding that the studied dune fields are influenced by topographically‐controlled complex wind directions. Our morphological analysis reveals that inside Moreux Crater in particular, the topographic setting dominates the wind flow direction, leading to the development of a sand transport pathway encircling the central peak of the crater. The dune fields in Herschel Crater are also affected by winds controlled by variable topography as suggested by the presence of complex dunes and dune fields. Our analysis indicate that the studied dune systems is not the result of paleo‐wind regimes. Furthermore, we perform thermal inertia measurements using thermal emission spectrometer (TES) data, which indicate that the studied dune fields consist of medium sand 250–500 µm in diameter. Copyright © 2012 John Wiley & Sons, Ltd.     

Discriminating the long distance dispersal of fine ash from sustained columns or near ground ash clouds: The example of the Pomici di Avellino eruption (Somma-Vesuvius,Italy)

Ash samples from tephra layers correlated with the Pomici di Avellino (Avellino Pumice) eruption of Somma-Vesuvius were collected in distal archives and their composition and particle morphology investigated in order to infer their behaviour of transportation and deposition. Differences in composition and particle morphologies were recognised for ash particles belonging to the magmatic Plinian and final phreatomagmatic phases of the eruption. The ash particles were dispersed in opposite directions during the two different phases of the eruption, and these directions are also different from that of coarse-grained fallout deposits. In particular, ash generated during magmatic phase and injected in the atmosphere to form a sustained column shows a prevailing SE dispersion, while ash particles generated during the final phreatomagmatic phase and carried by pyroclastic density currents show a general NW dispersion. These opposite dispersions indicate an ash dispersal influenced by both high and low atmosphere dynamics. In particular, the magmatic ash dispersal was first driven by stratospheric wind towards NE and then the falling particles encountered a variable wind field during their settling, which produced the observed preferential SE dispersal. The wind field encountered by the rising ash clouds that accompanied the pyroclastic density currents of the final phreatomagmatic phase was different with respect to that encountered by the magmatic ash, and produced a NW dispersal. These data demonstrate how ash transportation and deposition are greatly influenced by both high and low atmosphere dynamics. In particular, fine-grained particles transported in ash clouds of small-scale pyroclastic density currents may be dispersed over distances and cover areas comparable with those injected into the stratosphere by Plinian, sustained columns. This is a point not completely addressed by present day mitigation plans in case of renewal of activity at Somma-Vesuvius, and can yield important information also for other volcanoes potentially characterised by explosive activity.     

Multiplatform observation of the surface circulation in the Gulf of Naples (Southern Tyrrhenian Sea)

The Gulf of Naples (Southern Tyrrhenian Sea) is a highly urbanised area, where human activities and natural factors (e.g. river runoff, exchanges with adjacent basins) can strongly affect the water quality. In this work we show how surface transport can influence the distribution of passively drifting surface matter, and more in general if and how the circulation in the basin can promote the renovation of the surface layer. To this aim, we carried out a multiplatform analysis by putting together HF radar current fields, satellite images and modelling tools. Surface current fields and satellite images of turbidity patterns were used to initialise and run model simulations of particle transport and diffusion. Model results were then examined in relation to the corresponding satellite distributions. This integrated approach permits to investigate the concurrent effects of surface dynamics and wind forcing in determining the distribution of passive tracers over the basin of interest, identifying key mechanisms supporting or preventing the renewal of surface waters as well as possible areas of aggregation and retention.     

Magnetic field transforms with low sensitivity to the direction of source magnetization and high centricity

Magnetic data interpretation faces difficulties due to the various shapes of magnetic anomalies and the positions of their extrema with respect to the causative bodies for different directions of the source magnetization. The well‐known transforms — reduction to the pole, pseudogravity field, and analytic signal (total gradient) — help in reducing the problem. Another way to achieve the required effect is the transformation of magnetic data, ΔT or Z, into values of the anomalous magnetic intensity T. In this respect, we have found some transforms based on differential operators such as the gradient of T and its modulus R = |?T|, the Laplacian L = ?²T, the product T ?²T and its square root Q, and the Laplacian ?²(T²) and its square root E, to be useful. They are slightly sensitive to the magnetization orientation and their extrema occur above the sources. For a 2D anomaly of a homogeneous causative body, the proposed transforms do not depend on the inclination of magnetization. In the 3D case, such independence does not exist even for the elementary field of a point dipole. The influence of the magnetization direction is estimated by an integral coefficient of sensitivity. This coefficient takes values of up to 2.0 for ΔT or Z anomalies, while their transforms T, R, E, Q and L have values of less than 0.28, 0.29, 0.24, 0.16 and 0.07, respectively, i.e. on average, 10 times less. The estimation of the centricity is carried out using the relative deviation of the principal extremum of the anomaly or its transforms from the epicentre of the model body at a depth equal to 100 units. For a ΔT anomaly this deviation is up to 67%; for the L transform it is less than 8%; for Q, E, R and T it is less than 10%, 15%, 20% and 25%, respectively. The proposed transforms take only non‐negative values. With respect to their shape, the peripheral magnetic extrema are removed, the anomalous configuration is simplified and the resolution of complicated interference patterns is improved. Their calculation does not require additional data for the direction of magnetization, which is an essential advantage over the reduction‐to‐the‐pole and pseudogravity‐field transforms. A joint analysis of the measured field and its transforms T, E and L offers possibilities for more confident separation of the anomalous effects and direct correlation to their sources. The model tests performed and the 3D field applications to real magnetic data confirm the useful properties of the transforms suggested here.     

Magnetic data analysis at low latitudes using magnitude transforms

Magnitude transforms include magnitude magnetic anomalies (MMA), their gradients and Laplacians. They can be calculated from the total magnetic anomalies or other component anomalies. Magnitude magnetic anomalies have a space distribution different from that of the component anomalies. Their values are non‐negative and their respective patterns are similar to the positive gravity anomalies. Magnitude transforms are an effective tool for magnetic data analysis due to their simplified pattern and direct correlation with the space location of the source. They have advantages over the traditionally used reduction‐to‐the‐pole (RTP) transform, especially at low magnetic latitudes. The calculation of magnitudes of the anomalous field requires the total field data to be transformed into the component anomalies, while the reduction‐to‐the‐pole transform also includes a rotation of the magnetization vector, the orientation of which is usually assumed. For equal latitudes, the transfer functions of component‐component transforms in the frequency domain show better stability than the component‐component‐rotation transfer function. This is illustrated by a comparison of analytical expressions, and synthetic models of magnetic fields. The Dixon seamount case shows the possibilities for an improved data analysis and more confident source recognition at low latitudes using magnetic transforms.     

A new method for the determination of the specific kinetic energy (SKE) released to pyroclastic particles at magmatic fragmentation: theory and first experimental results

Brittle magmatic fragmentation plays a crucial role in explosive eruptions. It represents the starting point of hazardous explosive events that can affect large areas surrounding erupting volcanoes. Knowing the initial energy released during this fragmentation process is fundamental for the understanding of the subsequent dynamics of the eruptive gas-particle mixture and consequently for the forecasting of the erupting column’s behavior. The specific kinetic energy (SKE) of the particles quantifies the initial velocity shortly after the fragmentation and is therefore a necessary variable to model the gas-particle conduit flow and eruptive column regime. In this paper, we present a new method for its determination based on fragmentation experiments and identification of the timings of energy release. The results obtained on compositions representative for basaltic and phonolitic melts show a direct dependence on magma material properties: poorly vesiculated basaltic melts from Stromboli show the highest SKE values ranging from 7.3 to 11.8 kJ/kg, while experiments with highly vesiculated samples from Stromboli and Vesuvius result in lower SKE values (3.1 to 3.8 kJ/kg). The described methodology presents a useful tool for quantitative estimation of the kinetic energy release of magmatic fragmentation processes, which can contribute to the improvement of hazard assessment.