Some Morphological Aspects and Hydrological Characterization of the Tagus Floods in the Santarém Region, Portugal

In Portugal, few studies have been made of the historical floods of the RiverTagus (the longest in the Iberian Peninsula). This fact led to the study of theLower Tagus (Santarém region) using written historical documents,cartographic documents and hydrological data, consisting mainly of waterlevel records. With the support of the historical documents and the analysisof all the maps, it was possible to verify that the human intervention has beenfundamental in the morphological changes of the Tagus' channel. It becameaware that the river changed from a braided to a single channel with alternatebars. From the hydrological data, return periods for the floods were determined,using the Pearson Type 3 distribution. The selection of the most important floods,from 1855 to 1998, enabled to build a ``flood hazard scale' for this region.     

Evaluating accuracy for two empirical methods in predicting settlement of drilled shafts

Several theoretical, empirical and semi-empirical methods are available in the literature to predict settlement of drilled shafts in sandy soils. In the Arabian Gulf countries, specifically in the United Arab Emirates, equations and procedure from the rest of the world are being used in analysis and design of drilled shafts without proper validation. It is the aim of this study to assess the applicability and evaluate the accuracy of two well known, and commonly used methods for pile prediction in the United Arab Emirates (UAE), namely Vesic (1977) and Poulos (1979), via comparison with data from field pile load tests conducted on shafts drilled in the region. Some of these tests were conducted for the purpose of this study, while others were made available through the courtesy of International Piling Contractors who are active in the region (e.g. Bauer International and Swiss Borings). Pile load test data were analyzed to back-calculate the model parameters related to settlement under different loading stages. Geological data and soil properties were obtained from studies conducted at the relevant sites. An effort is made to correlate soil properties with the prediction models. Statistical analysis is conducted to assess the accuracy of the results obtained from the two methods at different stages of loading via those obtained from pile load tests. Moreover, a detailed parametric study is conducted to assess the effect of the related parameters on the predicted pile settlement and the estimated settlement at different stages of loading. The study concluded with a recommendation of the most appropriate models and procedures to be followed for predicting the settlement of drilled shafts in the UAE, together with useful charts and correlation relations. Results showed that settlement values predicted by Vesic (1977) and Poulos (1979) overestimates the true values. This revised version was published online in July 2006 with corrections to the Cover Date.     

Mineral dissolution in the Cape Cod aquifer, Massachusetts, USA: I . Reaction stoichiometry and impact of accessory feldspar and glauconite on strontium isotopes, solute concentrations, and REY distribution

To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between ⁸⁷Sr/⁸⁶Sr and Sr concentration is observed. At all depths, the ⁸⁷Sr/⁸⁶Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-⁸⁷Sr/⁸⁶Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-⁸⁷Sr/⁸⁶Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic ⁸⁷Sr because of its young Pleistocene age. The low ⁸⁷Sr/⁸⁶Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater chemistry, even in relatively simple aquifers, may be complicated by solute contributions from “exotic” accessory minerals such as glauconite. To detect such peculiarities, groundwater studies should combine the study of elemental concentration and isotopic composition of several solutes that show different geochemical behavior.     

A vibrational spectroscopic study of the oxidation of pyrite by molecular oxygen

In situ flow-through attenuated total reflectance (ATR) Fourier transform infrared (FTIR) spectroscopy has been used to investigate the formation, and step-wise oxidation, of sulfoxyanions at the pyrite surface during oxidation by molecular oxygen. The surface was studied under two different pH regimes (pH 2.5 and pH 5.6) and under two light conditions (dark and ultraviolet light). It was experimentally observed that multiple sulfoxyanions were present at the pyrite surface during oxidation by molecular oxygen, spectroscopically illustrating the concept of sulfur step-wise oxidation. The results from photochemical experiments were complex and suggest a dependence on both pH and surface speciation.     

Initial Al/Al in carbonaceous-chondrite chondrules: too little Al to melt asteroids

We report ²⁶Mg excesses correlated with Al/Mg ratios in five chondrules from the primitive CO3.0 chondrite Yamato 81020 that yield a mean initial ²⁶Al/²⁷Al ratio of only (3.8 ± 0.7) × 10⁻⁶, about half that of ordinary chondrite (OC) chondrules. Even if asteroids formed immediately after chondrule formation, this ratio and the mean Al content of CO chondrites is only capable of raising the temperature of a well-insulated CO asteroid to 940 K, which is more than 560 K too low to produce differentiation. The same ratio combined with the higher Al content of CV chondrites results in a CV asteroid temperature of 1100 K. We calculate that the mean initial ²⁶Al/²⁷Al ratio of about 7.4 × 10⁻⁶ found in LL chondrules is only able to produce small amounts of melting, too little to produce differentiation. These results cast serious doubt on the viability of ²⁶Al as the heat source responsible for asteroid differentiation. Inclusion of ⁶⁰Fe raises temperatures about 160 K, but this increment is not enough to cause differentiation, even of an LL-chondrite asteroid.     

Beryllium-10 in Australasian tektites: Constraints on the location of the source crater

By using accelerator mass spectrometry we have measured the ¹⁰Be concentrations of 86 Australasian tektites. Corrected to the time of tektite production ∼0.8 My ago, the ¹⁰Be concentrations (10⁶ atom/g) range from 59 for a layered tektite from Huai Sai, Thailand, to 280 for an australite from New South Wales, Australia. The average value is 143 ± 50. When tektites are sorted by country, their average measured ¹⁰Be concentrations increase slowly with increasing distance from Southeast Asia, the probable location of the tektite producing event, from 59 ± 9 for 6 layered tektites from Laos to 136 ± 20 for 20 splash-form tektites from Australia. The lowest ¹⁰Be concentrations for tektites fall on or within a contour centered off the shore of Vietnam, south of the Gulf of Tonkin (107°E; 17°N), but also encompassing two other locations in the area of northeastern Thailand previously proposed for the site of a single tektite-producing impact. The ¹⁰Be concentrations of layered tektites show only a weak anticorrelation (R ∼ −0.3) with the numbers of relict crystalline inclusions.Loosely consolidated, fine-grained terrestrial sediments or recently consolidated sedimentary rocks are the most likely precursor materials. Dilution of sediments with other kinds of rock raises problems in mixing and is not supported by petrographic data. Sedimentary columns that have the right range of ¹⁰Be concentrations occur off the coasts of places where sedimentation rates are high relative to those in the deep sea. A single impact into such a region, 15 to 300 m thick, could have propelled near-surface, high-¹⁰Be material farthest—to Australia—while keeping the deeper-lying, low-¹⁰Be layers closer to home. We do not rule out, however, other proposed mechanisms for tektite formation.     

Observed features of a two-phase stellar wind from WR 136 in the vicinity of NGC 6888

A number of features are detected outside the nebula NGC 6888, within 1.2° (30 pc) of the star WR 136, which can be explained in a two-phase stellar-wind model. These include regions with fine filamentary gas structure that do not contain sources of stellar wind, extended radial “streams,” ultra-compact HII regions with high-velocity gas motions, and high-velocity gas motions outside the envelope of NGC 6888. The two-phase wind consists of a rarefied component and dense compact condensations, or “bullets.” The bullets generate cylindrical shocks in the interstellar gas, resulting in the presence of high-velocity gas up 20–30 pc from the star, outside the cavity formed by the rarified component of the wind.     

A model for superoutbursts in SU UMa-type binaries

We suggest a new mechanism for the superoutbursts in SU UMa binaries, in which the increase in the accretion rate resulting in a superoutburst is associated with the formation of a spiral “precessional” wave in the inner parts of the disk, where gas-dynamical perturbations are negligible. The existence of such waves was suggested by us previously. The results of three-dimensional gas-dynamical simulations have shown that a considerable increase in the accretion rate (by up to an order of magnitude) is associated with the formation of the precessional wave. The features of the precessional spiral wave can explain both the energy release in the superoutburst and all its observational manifestations. One distinguishing feature of superoutbursts in SU UMa-type stars is the formation of a “superhump” in the light curve. Our model reproduces well both the formation of a superhump and its observational features, including its period, which is up to 3–7% longer than the orbital period, and the detectability of the superhump independent of the orbital inclination of the binary.     

A Sequence of Pan-African and Hercynian Events Recorded in Zircons from an Orthogneiss from the Hercynian Belt of Western Central Iberia--an Ion Microprobe U-Pb Study

Sensitive high-resolution ion microprobe U–Pb dating showsthat a biotite orthogneiss from the Hercynian belt of westerncentral Iberia contains 1000–300 Ma zircon. Older, 1000–570Ma ages within this range represent inherited, detrital materialamong which four age components may be recognized: