Climate change perception in Romania

Theoretical and Applied Climatology - In the last decades, anthropogenic drivers have significantly influenced the natural climate variability of Earth’s atmosphere. Climate change has become...     

Accumulation and distribution of petroleum hydrocarbons found in mussels (Mytilus galloprovincialis) in the canals of Venice, Italy

Petroleum contamination was assessed in indigenous and transplanted mussels for three types of environments within the Venice Lagoon and its associated interior canals. Indigenous and transplanted mussels were least impacted by petroleum contamination at open-water stations, but more affected in partially-enclosed areas indicating that physical processes of tidal or wind activities can remove organic contaminants such as petroleum from these areas more effectively. Limited tidal flushing of the interior canals resulted in contaminated locations unable to support indigenous mussels. Clean mussels transplanted to these highly impacted sites accumulated the highest levels of petroleum hydrocarbons. The distribution of polycyclic aromatic hydrocarbons (PAHs) indicated mainly combustion-related activities from sources such as the nearby industrial zones and boat traffic, with some evidence of fresher petroleum inputs. Total hydrocarbons found in all mussels could be related to concentrations found in the surrounding sediments as reported in an earlier study.     

Sodium fluoride ion-pairs in seawater

Laboratory investigations were conducted on the formation of NaF° ion-pairs at the ionic strength of seawater using specific ion electrodes. Sodium and fluoride ion electrodes produced results which are consistent with the ion-pairing model for these ionic interactions. The stoichiometric association constant for NaF°, $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$, was determined at 15, 25, and 35°C. It was assumed that $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$ was a function of temperature, pressure, and ionic strength but not of solution composition. The value for $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$ at 25°C and I = 0.7 m is 0.045 ± 0.006. $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$ increased with decreasing temperature. This result was used to recompute values of $\text{K}{}^1{}_{\mathrm{<mtext>MgF</mtext>}}$ and $\text{K}{}^1{}_{\mathrm{<mtext>CaF</mtext>}}$ accounting for the presence of NaF° ion-pairs. The value for $\text{K}{}^1{}_{\mathrm{<mtext>NaF</mtext>}}$ indicates that 1.1% of the fluoride in seawater is ion-paired with sodium at 25°C and 35‰ salinity. This fraction increases to approximately 2% at the lower temperatures found in the deep ocean. The percentage of free fluoride in natural seawater was measured at 15, 25, and 35°C to verify the speciation calculated from equilibrium constants.     

The infrared colors of main sequence stars: how much circumstellar debris is normal?

We have been awarded NASA Key Project observing time on ISO, in order to establish the true frequency of far-infrared excesses in a volume-limited sample of main sequence and related stars, and address the relative success or failure of single stars in processes related to the forming of planetary systems. For a volume-limited subset of main sequence and related stars, PHT03 measurements at 3.6, 11.5, 20 and 60 micron will be obtained, using a 120 arsec aperture in all cases to eliminate possible companion confusion with differing apertures, to ascertain spectral energy distributions. For the M dwarfs, 100 micron observations will also be obtained. For some, brighter sources, more extensive wavelength coverage and improved spatial resolution will be attempted, using CAM and SWS. Spatially over-sampled PHOT observations will be made at 60 micron of the brightest and nearest Vega-like sources to measure the characteristic sizes of the emitting regions and obtain some information regarding their shapes and orientations. The goal is not a map, but scan profiles along 3 position angles which can be deconvolved to find the intrinsic size and shape of the half-maximum contour of the emitting region. Photometry of selected lines of sight through the zodiacal dust will also be carried out to look for outer solar system (Kuiper Belt) material. Observation at a range of wavelengths, ecliptic latitudes and at 2 epochs is designed to help untangle foreground Zodiacal from background Kuiper flux, not necessarily to look for individual macroscopic objects.     

Uncertainties in determining microbial biomass C using the chloroform fumigation–extraction method

We tested the accuracy of the chloroform fumigation–extraction method, which is commonly used to determine soil biomass C concentrations. Accurate and precise determination of total microbial biomass is important in order to characterize soil properties and to develop predictive metal transport models for soils. Two natural soils, and individual soil components, including silica sand, montmorillonite, kaolinite, a humic acid, and Bacillus subtilis bacterial cells, were fumigated for 24 h. Following the fumigation, C from fumigated and unfumigated samples was extracted using a 0.5 M K₂SO₄ solution. The difference between the C content in the fumigated and unfumigated samples ideally represents C due to biomass because the fumigation procedure should lyse cells and release biomass C. We observed increased C release upon fumigation for bacteria-only samples, confirming the ability of fumigation to lyse cells. There was no difference in extracted C concentration between fumigated and unfumigated samples of silica sand and of humic acid, confirming that the fumigation process does not introduce additional organic C to samples of these soil components. However, the fumigated clay samples both showed increased C release relative to the unfumigated controls, indicating that significant concentrations of the fumigant, chloroform, adsorbed onto the clay minerals studied here. Additionally, we found significant chloroform remaining in the extracts from two fumigated natural soils. Attempts to remove the chloroform from the soils or soil components prior to extraction by increasing the evacuation time, or to remove chloroform in the extracts by sparging them vigorously with nitrogen gas, both failed. This research reveals that chloroform gas may adsorb significantly to clays and the clay fraction of natural soils. Thus, the fumigation–extraction method must be corrected to account for the added chloroform C and accurately assess the concentration of biomass C in soils that contain significant concentrations of clays.     

Three‐dimensional architecture and hydrostratigraphy of cross‐cutting buried valleys using airborne electromagnetics,glaciated Central Lowlands,Nebraska, USA

Buried valleys are characteristic features of glaciated landscapes, and their deposits host important aquifers worldwide. Understanding the stratigraphic architecture of these deposits is essential for protecting groundwater and interpreting sedimentary processes in subglacial and ice‐marginal environments. The relationships between depositional architecture, topography and hydrostratigraphy in dissected, pre‐Illinoian till sheets is poorly understood. Boreholes alone are inadequate to characterize the complex geology of buried valleys, but airborne electromagnetic surveys have proven useful for this purpose. A key question is whether the sedimentary architecture of buried valleys can be interpreted from airborne electromagnetic profiles. This study employs airborne electromagnetic resistivity profiles to interpret the three‐dimensional sedimentary architecture of cross‐cutting buried valleys in a ca 400 km² area along the western margin of Laurentide glaciation in North America. A progenitor bedrock valley is succeeded by at least five generations of tunnel valleys that become progressively younger northward. Tunnel‐valley infills are highly variable, reflecting under‐filled and over‐filled conditions. Under‐filled tunnel valleys are expressed on the modern landscape and contain fine sediments that act as hydraulic barriers. Over‐filled tunnel valleys are not recognized in the modern landscape, but where they are present they form hydraulic windows between deep aquifer units and the land surface. The interpretation of tunnel‐valley genesis herein provides evidence of the relationships between depositional processes and glacial landforms in a dissected, pre‐Illinoian till sheet, and contributes to the understanding of the complex physical hydrology of glacial aquifers in general.     

The Orientational Relaxation of Bipolar Active Regions

In the mean, bipolar active regions are oriented nearly toroidally, according to Hale's polarity law, with a latitude-dependent tilt known as Joy's Law. The tilt angles of individual active regions deviate from this mean behavior and change over time. It has been found that on average the change is toward the mean angle at a rate characteristic of 4.37 days (Howard, 1996). We show that this orientational relaxation is consistent with the standard model of flux tube emergence from a deep dynamo layer. Under this scenario Joy's law results from the Coriolis effect on the rising flux tube (D'Silva and Choudhuri, 1993), and departures from it result from turbulent buffeting of the tubes (Longcope and Fisher, 1996). We show that relaxation toward Joy's angle occurs because the turbulent perturbations relax on shorter time scales than the perturbations from the Coriolis force. The turbulent perturbations relax more rapidly because they are localized to the topmost portion of the convection zone while the Coriolis perturbations are more widely distributed. If a fully-developed active region remains connected to the strong toroidal magnetic field at the base of the convection zone, its tilt will eventually disappear, leaving it aligned perfectly toroidally. On the other hand, if the flux becomes disconnected from the toroidal field the bipole will assume a tilt indicative of the location of disconnection. We compare models which are connected and disconnected from the toroidal field. Only those disconnected at points very deep in the convection zone are consistent with observed time scale of orientational relaxation.     

137Cs and 210Po in Pacific walrus and bearded seal from St. Lawrence Island, Alaska

The activity concentration of Cesium-137 ((137)Cs) and naturally-occurring Polonium-210 ((210)Po) were measured in the muscle tissue, kidney and liver of Pacific walrus (Odobenus rosmarus divergens) and bearded seal (Erignathus barbatus) collected by native hunters from the Bering Sea during May 1996. The mean (137)Cs concentrations in muscle, liver and kidney of Pacific walrus were 0.07, 0.09 and 0.07 Bq kg(-1) (n=5, wet weight), respectively, and 0.17, 0.10, and 0.17 Bq kg(-1) (n=2, wet weight), respectively, in bearded seal. In general, (137)Cs tissue concentrations are significantly lower than those previously reported for mammals from other regions. By comparison, (210)Po activity concentrations are more variable and appear to be higher level compared with mammal data from other regions. The mean (210)Po concentration in the muscle tissue, liver and kidney of Pacific walrus (n=5, wet weight) were 28.7, 189, and 174 Bq kg(-1), respectively. This compares with (210)Po concentration values (n=2, wet weight) of 27, 207 and 68 Bq kg(-1) measured in the muscle tissue, liver and kidney, of bearded seal, respectively. Estimated concentration factors--as defined by the radionuclide concentration ratio between the target tissue to that in sea water--were two to three orders of magnitude higher for (210)Po that those of (137)Cs. We conclude from radiological dose estimates that ingestion of (137)Cs in foods derived from walrus and seal will pose no threat to human health. This work has important implications for assessment of risks of Alaskan coastal communities concerned about the dumping of nuclear waste in the Russia Arctic.     

Chemical forms of iron in the Connecticut River estuary

The ‘dissolved’ iron (that passed through a 0·4-μm filter) varied nonconservatively with salinity in the Connecticut River estuary. However, the total iron appeared to be conservative. Measurements of Fe(II) and Fe(III) showed that oxidation of Fe(II) was not a factor in the decrease of ‘dissolved’ iron in the low salinity region. A solubility model and analyses based on different pore-size filters indicated that a substantial amount of the ‘dissolved’ iron in the low salinity region was colloidal iron. The coagulation of fine colloidal particles led to the non-conservative behavior of ‘dissolved’ iron during estuarine mixing, but it did not necessarily lead to removal of total iron from the waters. Particulate iron was 80–90% of the total iron and it covaried with the total suspended matter during mixing and sediment resuspension. The residence time of water in the Connecticut River estuary was too short to allow removal of iron from the water column within the estuary.     

Propagating radial waves of travel cost in a grid

To calculate the minimum cost of travel to each location within a geographical area from a specified set of locations, most geographic information systems represent that area as a rectangular grid of discrete cells, each indicating the cost of traversing that cell's particular location. These increments of cost are then accumulated by proceeding from cell to adjacent cell in a manner that resembles the propagation of waves. Because this propagation is limited to the eight directions associated with each cell's eight neighbors, however, it is often misdirected, and travel costs are therefore often overestimated. This article discusses the context, precedent, design, implementation, performance, and implications of a new algorithm that eliminates such problems in a straightforward manner. It does so by retaining the octangular propagation mechanism of earlier algorithms while keeping track of the particular locations at which propagated waves of accumulating travel cost either refract or diffract. The approach also holds promise for significant improvement in areas ranging from dispersion modeling and shape analysis to interpolation and the delineation of cost-minimizing paths.