Factors affecting the Nd3+ (REE3+) luminescence of minerals

In this paper, possibilities and limits of the application of REE³⁺ luminescence (especially the Nd^{3+ 4}F_3/2 → ⁴I_9/2 emission) as structural probe are evaluated. Important factors controlling the Nd³⁺ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO₄), xenotime–(Y) (YPO₄), monazite–(Ce) (CePO₄) and their synthetic analogues. Based on these examples we review in short that (1) REE³⁺ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE³⁺-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd³⁺-related centres are found to be promising candidates.     

Chemical Dynamics and Evaluation of Biogeochemical Processes in Alpine River Kamniška Bistrica, North Slovenia

Biogeochemical processes were investigated in alpine river—Kamni?ka Bistrica River (North Slovenia), which represents an ideal natural laboratory for studying anthropogenic impacts in catchments with high weathering capacity. The Kamni?ka Bistrica River water chemistry is dominated by HCO₃ ^?, Ca²⁺ and Mg²⁺, and Ca²⁺/Mg²⁺ molar ratios indicate that calcite weathering is the major source of solutes to the river system. The Kamni?ka Bistrica River and its tributaries are oversaturated with respect to calcite and dolomite. pCO₂ concentrations were on average up to 25 times over atmospheric values. δ¹³C_DIC values ranged from ?12.7 to ?2.7 ‰, controlled by biogeochemical processes in the catchment and within the stream; carbonate dissolution is the most important biogeochemical process affecting carbon isotopes in the upstream portions of the catchment, while carbonate dissolution and organic matter degradation control carbon isotope signatures downstream. Contributions of DIC from various biogeochemical processes were determined using steady state equations for different sampling seasons at the mouth of the Kamni?ka Bistrica River; results indicate that: (1) 1.9–2.2 % of DIC came from exchange with atmospheric CO₂, (2) 0–27.5 % of DIC came from degradation of organic matter, (3) 25.4–41.5 % of DIC came from dissolution of carbonates and (4) 33–85 % of DIC came from tributaries. δ¹⁵N values of nitrate ranged from ?5.2 ‰ at the headwater spring to 9.8 ‰ in the lower reaches. Higher δ¹⁵N values in the lower reaches of the river suggest anthropogenic pollution from agricultural activity. Based on seasonal and longitudinal changes of chemical and isotopic indicators of carbon and nitrogen in Kamni?ka Bistrica River, it can be concluded that seasonal changes are observed (higher concentrations are detected at low discharge conditions) and it turns from pristine alpine river to anthropogenic influenced river in central flow.     

Earthquake Swarms and Accompanying Phenomena in Intraplate Regions: A Review

The western part of the Bohemian Massif has played an exceptional role in recent geodynamic activity of the region. It is characterised by repeated occurrences of earthquake swarms and by other manifestations of deep tectonic processes (CO ₂ emissions, anomalous ³ He content, mineral waters, mofettes, etc.). The purpose of this paper is to introduce some other intraplate regions with earthquake swarm occurrence (French Massif Central; Colli Albani and Vulsini Mts., central Italy; Southern Apennines, Italy; the Danville and Long Valley regions, California; central Arkansas), and with artificially induced earthquake swarms (Larderello, Italy, geothermal field; Coso, California, geothermal field; NE Bavaria, Germany, deep drilling project). Although these areas represent different tectonic environments, the manifestations of recent geodynamic and/or man-made activity are similar in many aspects. This coincidence most probably issues from a common cause of both tectonic and artificially induced earthquake swarms – intrusions/injections of fluids. Since the regions with earthquake swarm occurrence of tectonic origin are situated as a rule in the close neighbourhood of Quaternary volcanoes, the intruding fluids seem to be derived from magma recently transported to upper crustal layers.     

PROJECTIONS OF CLIMATE CHANGE FOR THE CZECH REPUBLIC

The paper deals with a selection of the climatological baseline, GCM validity and construction of the climate change scenarios for an impact assessment in the Czech territory. The period of 1961–1990 has been selected as the climatological baseline. The corresponding database includes more than 50 monthly mean temperature and precipitation series, and 16 time series of daily meteorological data that contain also the solar radiation data. The 1× CO₂ outputs produced by four GCMs, provided by the CSMT (GISS, GFD30, GFD01, and CCCM), were compared with observed temperature and precipitation conditions in western and central Europe with a particular attention devoted to the Czech territory. The GCM ability to simulate annual cycles of temperature, precipitation and radiation was thoroughly examined. The GISS and CCCM were selected as a basis for constructing climate change scenarios as they simulated reasonably the observed patterns. According to the GISS variant, 2× CO₂ climate assumes a higher winter and lower summer warming, and an increase in annual precipitation amounts. A dangerous combination of the summer temperature increase and declining precipitation amounts is a specific feature of the CCCM scenario. An incremental scenario for temperature and precipitation is based on the combination of prescribed changes in both annual means and annual courses.     

X-ray observations of limb flare loops and post-flare coronal arch

We present observations of another post-flare arch following an eruptive flare, detected in X-ray lines above the western solar limb on 2 May 1985.     

Analytical computation of atmospheric drag effects

An analytical interpretation of the satellite orbital element perturbations under influence of a drag has been developed. Some useful formulae for the perturbations of the semi-major axis are given. The agreement with observed values is very good.     

Rr CrB and Algol – The First and Last Star in Zdeněk Kopal’s Life with Binaries

Several important turning points appeared in the personal life and scientific career of Zdeněk Kopal, every time, when he entered a new field of research. Four particular periods of his life will be commented in the present paper: the studies in Prague and early observations in the variable star programme of the Czech Astronomical Society; the first lectures on close binaries at Harvard; the intermezzo of lunar research; and the last period after 1989, when Zdeněk Kopal returned several times to Prague University.