Experimental study of a low-alkali tholeiite at 1–5 kbar: optimal condition for the crystallization of high-An plagioclase in hydrous arc tholeiite

We conducted melting experiments on a low-alkali tholeiite (SiO₂ ~52 wt%, MgO ~6.5 wt%, CaO/Na₂O~4.4, Al₂O₃/SiO₂ ~0.33) under both H₂O-undersaturated and H₂O-saturated conditions to investigate the effect of H₂O on the Ca–Na partitioning between plagioclase and melt. Experiments were performed in the temperature and pressure ranges of 1,000–1,300°C and 1–5 kbar, respectively, with varying H₂O contents of 0–12wt%. Redox condition was 0–2 log unit above NNO (nickel–nickel oxide) buffer. Temperature-bulk H₂O diagrams for the low-alkali tholeiite are constructed at 1, 2, and 5 kbar, and compositions of near-liquidus plagioclase and coexisting melt are determined. To exclude the effect of melt composition (CaO/Na₂O and Al₂O₃/SiO₂ ratios) on plagioclase composition and to reveal the effect of H₂O on An (=100×Ca/(Ca+Na)) content and (=(Ca/Na)_pl/(Ca/Na)_melt), we focused on the composition of near-liquidus plagioclases which crystallized from melts with nearly constant CaO/Na₂O and Al₂O₃/SiO₂ ratios. Our experimental results show that, at each experimental pressure, An content of the near-liquidus plagioclase and the K_D^Ca-Na almost linearly increases as H₂O content in melt increases. Each of the An content and the variations in a low-alkali tholeiitic system (CaO/Na₂O~4.0–4.5, Al₂O₃/SiO₂ ~0.27–0.33) can be described by one equation using temperature, pressure, and melt H₂O content as parameters. An content and of liquidus plagioclase increases with increasing melt H₂O and with decreasing pressure, elucidating that nearly H₂O-saturated conditions of 2–3 kbar is optimal for the crystallization of the most An-rich plagioclase (>An₈₈). We suggest this pressure condition of 2–3 kbar, corresponding to depth of 7–11 km, plays an important role for the origin of An-rich plagioclase in H₂O-rich low-alkali tholeiite. At pressures more than ca. 4 kbar, crystallization of liquidus Ca-rich clinopyroxene decreases the CaO/Na₂O ratio of liquid, thus prohibiting the crystallization of high-An plagioclase from hydrous tholeiite.     

Chronology and products of the 2000 eruption of Miyakejima Volcano, Japan

Lateral migration of magma away from Miyakejima volcanic island, Japan, generated summit subsidence, associated with summit explosions in the summer of 2000. An earthquake swarm beneath Miyakejima began on the evening of 26 June 2000, followed by a submarine eruption the next morning. Strong seismic activity continued under the sea from beneath the coast of Miyakejima to a few tens of kilometers northwest of the island. Summit eruptive event began with subsidence of the summit on 8 July and both explosions and subsidence continued intermittently through July and August. The most intense eruptive event occurred on 18 August and was vulcanian to subplinian in type. Ash lofted into the stratosphere fell over the entire island, and abundant volcanic bombs were erupted at this time. Another large explosion took place on 29 August. This generated a low-temperature pyroclastic surge, which covered a residential area on the northern coast of the island. The total volume of tephra erupted was 9.3×10⁶ m³ (DRE), much smaller than the volume of the resulting caldera (6×10⁸ m³). Migration of magma away from Miyakejima was associated with crustal extension northwest of Miyakejima and coincident shrinkage of Miyakejima Island itself during July–August 2000. This magma migration probably caused stoping of roof rock into the magma reservoir, generating subsurface cavities filled with hydrothermal fluid and/or magmatic foam and formation of a caldera (Oyama Caldera) at the summit. Interaction of hydrothermal fluid with ascending magma drove a series of phreatic to phreatomagmatic eruptions. It is likely that new magma was supplied to the reservoir from the bottom during waning stage of magmas migration, resulting in explosive discharge on 18 August. The 18 August event and phreatic explosions on 29 August produced a conduit system that allowed abundant SO₂ emission (as high as 460 kg s^–1) after the major eruptive events were over. At the time of writing, inhabitants of the island (about 3,000) have been evacuated from Miyakejima for more than 3 years.     

Proximal–distal fall deposit correlation of VEI-5 tephra (Towada-Chuseri) from Towada volcano,northeast Japan

A tephra layer offers an isochronous surface in sediments, thus serving as a key bed and/or an age marker. Recent high-resolution sediment research (e.g. varved sediments) has revealed optically invisible tephra fingerprints and provided high-precision tephra ages. However, a tephra-based correlation cannot succeed without detailed knowledge of the tephra characteristics in a proximal area to correlate with tephra in high-resolution sediments in remote areas. Here we documented the detailed characteristics of Towada-Chuseri (To-Cu) tephra, which is associated with the Middle Holocene volcanic explosivity index 5 eruption of Towada volcano, northeast Japan. We used To-Cu tephra samples to achieve the proximal–distal correlation of three members: Chuseri pumice (Cu), Kanegasawa pumice (Kn) and Utarube ash (Ut). These distal occurrences correlate with proximal To-Cu tephra based on volcanic glass morphology and refractive index, as well as on major element composition of volcanic glass shards. Refractive indices allow the preliminary correlation of each member, and major element composition helps in distinguishing Ut from the other members. Glass morphology provides additional support. These correlations reveal that To-Cu, especially Cu, covered central to northeast Japan while confirming that To-Cu is the representative tephra in the Middle Holocene of the Tohoku region.     

Transport electrification: A key element for energy system transformation and climate stabilization

This paper analyzes the role of transport electrification in the broader context of energy system transformation and climate stabilization. As part of the EMF27 model inter-comparison exercise, we employ the MESSAGE integrated assessment modeling framework to conduct a systematic variation of availability, cost, and performance of particular energy supply technologies, thereby deriving implications for feasibility of climate stabilization goals and the associated costs of mitigation. In addition, we explore a wide range of assumptions regarding the potential degree of electrification of the transportation sector. These analyses allow us to (i) test the extent to which the feasible attainment of stringent climate policy targets depends on transport electrification, and (ii) assess the far-reaching impacts that transport electrification could have throughout the rest of the energy system. A detailed analysis of the transition to electricity within the transport sector is not conducted. Our results indicate that while a low-carbon transport system built upon conventional liquid-based fuel delivery infrastructures is destined to become increasingly reliant on biofuels and synthetic liquids, electrification opens up a door through which nuclear energy and non-biomass renewables can flow. The latter has important implications for mitigation costs.     

Reconnaissance report on landslide disasters in northeast Japan following the M 9 T��hoku earthquake

An earthquake of M_w 9.0 struck the Pacific coast in northeast Japan on March 11, 2011 and was followed by a hugely damaging tsunami along 500 km of the Japanese coastline. An inland aftershock of M. 7.0 occurred on April 11; during which, surface fault ruptures appeared on land. A large variety of landslide disasters resulted from these earthquakes in various parts of northeastern Honshu, Japan. The full extent of the landslides is still being determined. This brief report introduces some of the landslide phenomena so far investigated by the Japanese Landslide Society. These are (1) failure of a water reservoir embankment dam in Sukagawa, Fukushima prefecture, (2) landslides and surface seismic fault rupture from the April 11 aftershock in Iwaki, Fukushima, (3) a concentration of surface failures at Matsushima Bay in Miyagi prefecture, and (4) small landslides on modified slopes in residential areas around Sendai city.     

N-body simulations of the Magellanic stream

A suite of high-resolution N -body simulations of the Magellanic Clouds–Milky Way system are presented and compared directly with newly available data from the H  i Parkes All-Sky Survey (HIPASS). We show that the interaction between Small Magellanic Clouds (SMC) and Large Magellanic Clouds results in both a spatial and kinematical bifurcation of both the stream and the leading arm. The spatial bifurcation of the stream is readily apparent in the HIPASS data, and the kinematical bifurcation is also tentatively identified. This bifurcation provides strong support for the tidal disruption origin for the Magellanic stream. A fiducial model for the Magellanic Clouds (MCs) is presented upon completion of an extensive parameter survey of the potential orbital configurations of the MCs and the viable initial boundary conditions for the disc of the SMC. The impact of the choice of these critical parameters upon the final configurations of the stream and leading arm is detailed.     

Distribution of gold and silver and its relation with hypogene ore minerals in the Esperanza porphyry deposit,Antofagasta Region,Chile

Modes of occurrence of Au‐ and Ag‐bearing phases and their relation with associated hypogene ore minerals were examined with the objective to elucidate Au‐Ag distribution at the Esperanza porphyry deposit in the Eocene Centinela copper belt, using ore‐microscope modal analysis, semi‐quantitative analyses by automated mineralogy, electron probe microanalysis, and secondary ion mass spectrometer. The Esperanza hypogene mineralization is characterized by early‐stage chalcopyrite‐rich veinlets in the potassic alteration zone and later polymetallic stage with tennantite and galena in the chlorite‐sericitic alteration zone. Only the early‐stage chalcopyrite contains fine‐grained electrum (Au₆₈Ag₃₂ ‐ Au₈₁Ag₁₉) and hessite (Ag₂Te), and thus yields positive correlations in Cu vs. Au and Cu vs. Ag grades that are clearly recognized in the hypogene sulfide zone. The early‐stage chalcopyrite grains frequently exhibit polysynthetic twinning suggestive of inversion from intermediate solid solution. These features suggest that the fine‐grained electrum and hessite are products exsolved in the cooling process with the intermediate solid solution to chalcopyrite inversion. In contrast, tennantite and galena of the later‐stage mineralization contain no detectable Ag, and it is thus proposed that the early‐stage inverted chalcopyrite is the principal storage of economically important precious metals.     

Rapid Alkalization in Lake Inawashiro, Fukushima, Japan: Implications for Future Changes in the Carbonate System of Terrestrial Waters

The global carbon cycle, one of the important biogeochemical cycles controlling the surface environment of the Earth, has been greatly affected by human activity. Anthropogenic nutrient loading from urban sewage and agricultural runoff has caused eutrophication of aquatic systems. The impact of this eutrophication and consequent photosynthetic activity on CO₂ exchange between freshwater systems and the atmosphere is unclear. In this study, we focused on how nutrient loading to lakes affects their carbonate system. Here, we report results of surveys of lakes in Japan at different stages of eutrophication. Alkalization due to photosynthetic activity and decreases in PCO₂ had occurred in eutrophic lakes (e.g., Lake Kasumigaura), whereas in an acidotrophic lake (Lake Inawashiro) that was impacted by volcanic hot springs, nutrient loading was changing the pH and carbon cycling. When the influence of volcanic activity was stronger in the past in Lake Inawashiro, precipitation of volcanic-derived iron and aluminum had removed nutrients by co-precipitation. During the last three decades, volcanic activity has weakened and the lake water has become alkalized. We inferred that this rapid alkalization did not result just from the reduction in acid inputs but was also strongly affected by increased photosynthetic activity during this period. Human activities affect many lakes in the world. These lakes may play an important part in the global carbon cycle through their influence on CO₂ exchange between freshwater and the atmosphere. Biogeochemical changes and processes in these systems have important implications for future changes in aquatic carbonate systems on land.