Statistical testing of a new testate amoeba‐based transfer function for water‐table depth reconstruction on ombrotrophic peatlands in north‐eastern Canada and Maine,United States

Proxy reconstructions of climatic parameters developed using transfer functions are central to the testing of many palaeoclimatic hypotheses on Holocene timescales. However, recent work shows that the mathematical models underpinning many existing transfer functions are susceptible to spatial autocorrelation, clustered training set design and the uneven sampling of environmental gradients. This may result in over‐optimistic performance statistics or, in extreme cases, a lack of predictive power. A new testate amoeba‐based transfer function is presented that fully incorporates the new recommended statistical tests to address these issues. Leave‐one‐out cross‐validation, the most commonly applied method in recent studies to assess model performance, produced over‐optimistic performance statistics for all models tested. However, the preferred model, developed using weighted averaging with tolerance downweighting, retained a predictive capacity equivalent to other published models even when less optimistic performance statistics were chosen. Application of the new statistical tests in the development of transfer functions provides a more thorough assessment of performance and greater confidence in reconstructions based on them. Only when the wider research community have sufficient confidence in transfer function‐based proxy reconstructions will they be commonly used in data comparison and palaeoclimate modelling studies of broader scientific relevance. Copyright © 2012 John Wiley & Sons, Ltd.     

Precipitation stable isotope variability and subcloud evaporation processes in a semi‐arid region

The stable isotopic (²H/¹H and ¹⁸O/¹⁶O) composition of precipitation has been used for a variety of hydrological and paleoclimate studies, a starting point for which is the behaviour of stable isotopes in modern precipitation. To this end, daily precipitation samples were collected over a 7‐year period (2008–2014) at a semi‐arid site located at the Macquarie Marshes, New South Wales (Australia). The samples were analysed for stable isotope composition, and factors affecting the isotopic variability were investigated. The best correlation between δ ¹⁸O of precipitation was with local surface relative humidity. The reduced major axis precipitation weighted local meteoric water line was δ ²H = 7.20 δ ¹⁸O + 9.1. The lower slope and intercept (when compared with the Global Meteoric Water Line) are typical for a warm dry climate, where subcloud evaporation of raindrops is experienced. A previously published model to estimate the degree of subcloud evaporation and the subsequent isotopic modification of raindrops was enhanced to include the vertical temperature and humidity profile. The modelled results for raindrops of 1.0 mm radius showed that on average, the measured D‐excess (=δ ²H ? 8 δ ¹⁸O) was 19.8‰ lower than that at the base of the cloud, and 18% of the moisture was evaporated before ground level (smaller effects were modelled for larger raindrops). After estimating the isotopic signature at the base of the cloud, a number of data points still plotted below the global meteoric water line, suggesting that some of the moisture was sourced from previously evaporated water. Back trajectory analysis estimated that 38% of the moisture was sourced over land. Precipitation samples for which a larger proportion of the moisture was sourced over land were ¹⁸O and ²H‐enriched in comparison to samples for which the majority of the moisture was sourced over the ocean. The most common weather systems resulting in precipitation were inland trough systems; however, only East Coast Lows contributed to a significant difference in the isotopic values. Copyright © 2016 Australian Nuclear Science and Technology Organisation. Hydrological Processes. © 2016 John Wiley & Sons, Ltd.     

Tropical Pacific – mid-latitude teleconnections in medieval times

Terrestrial and marine late Holocene proxy records from the western and central US suggest that climate between approximately 500 and 1350 a.d. was marked by generally arid conditions with episodes of severe centennial-scale drought, elevated incidence of wild fire, cool sea surface temperatures (SSTs) along the California coast, and dune mobilization in the western plains. This Medieval Climate Anomaly (MCA) was followed by wetter conditions and warming coastal SSTs during the transition into the “Little Ice Age” (LIA). Proxy records from the tropical Pacific Ocean show contemporaneous changes indicating cool central and eastern tropical Pacific SSTs during the MCA, with warmer than modern temperatures in the western equatorial Pacific. This pattern of mid-latitude and tropical climate conditions is consistent with the hypothesis that the dry MCA in the western US resulted (at least in part) from tropically forced changes in winter NH circulation patterns like those associated with modern La Niña episodes. We examine this hypothesis, and present other analyses showing that the imprint of MCA climate change appears in proxy records from widely distributed regions around the planet, and in many cases is consistent with a cool medieval tropical Pacific. One example, explored with numerical model results, is the suggestion of increased westerlies and warmer winter temperatures over northern Europe during medieval times. An analog technique for the combined use of proxy records and model results, Proxy Surrogate Reconstruction (PSR), is introduced.     

Radio planetary nebulae in the Magellanic Clouds

We report the extragalactic radio-continuum detection of 15 planetary nebulae (PNe) in the Magellanic Clouds (MCs) from recent Australia Telescope Compact Array+Parkes mosaic surveys. These detections were supplemented by new and high-resolution radio, optical and infrared observations which helped to resolve the true nature of the objects. Four of the PNe are located in the Small Magellanic Cloud (SMC) and 11 are located in the Large Magellanic Cloud (LMC). Based on Galactic PNe the expected radio flux densities at the distance of the LMC/SMC are up to ∼2.5 and ∼2.0 mJy at 1.4 GHz, respectively. We find that one of our new radio PNe in the SMC has a flux density of 5.1 mJy at 1.4 GHz, several times higher than expected. We suggest that the most luminous radio PN in the SMC (N S68) may represent the upper limit to radio-peak luminosity because it is approximately three times more luminous than NGC 7027, the most luminous known Galactic PN. We note that the optical diameters of these 15 Magellanic Clouds (MCs) PNe vary from very small (∼0.08 pc or 0.32 arcsec; SMP L47) to very large (∼1 pc or 4 arcsec; SMP L83). Their flux densities peak at different frequencies, suggesting that they may be in different stages of evolution. We briefly discuss mechanisms that may explain their unusually high radio-continuum flux densities. We argue that these detections may help solve the 'missing mass problem' in PNe whose central stars were originally  1–8 M_⊙  . We explore the possible link between ionized haloes ejected by the central stars in their late evolution and extended radio emission. Because of their higher than expected flux densities, we tentatively call this PNe (sub)sample –'Super PNe'.     

Li-bearing, disordered Mg-rich tourmaline from a pegmatite-marble contact in the Austroalpine basement units (Styria, Austria)

Pale-blue to pale-green tourmalines from the contact zone of Permian pegmatites to mica schists and marbles from different localities of the Austroalpine basement units (Rappold Complex) in Styria, Austria, are characterized. All these Mg-rich tourmalines have small but significant Li contents, up to 0.29 wt% Li₂O, and can be characterized as dravite, with FeO contents of ?~?0.9–2.7 wt%. Their chemical composition varies from ^X (Na_0.67Ca_0.19?K_0.02?_0.12) ^Y (Mg_1.26Al_0.97Fe²⁺ _0.36Li_0.19Ti⁴⁺ _0.06Zn_0.01?_0.15) ^Z (Al_5.31?Mg_0.69) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.66(OH)_0.34], with a?=?15.9220(3), c?=?7.1732(2) Å to ^X (Na_0.67Ca_0.24?K_0.02?_0.07) ^Y (Mg_1.83Al_0.88Fe²⁺ _0.20Li_0.08Zn_0.01Ti⁴⁺ _0.01?_0.09) ^Z (Al_5.25?Mg_0.75) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.87(OH)_0.13], with a?=?15.9354(4), c?=?7.1934(4) Å, and they show a significant Al-Mg disorder between the Y and the Z sites (R1?=?0.013–0.015). There is a positive correlation between the Ca content and?<?Y-O?>?distance for all investigated tourmalines (r?≈?1.00), which may reflect short-range order configurations including Ca and Fe²⁺, Mg, and Li. The tourmalines have X_Mg (X_Mg?=?Mg/Mg?+?Fe_total) values in the range 0.84–0.95. The REE patterns show more or less pronounced negative Eu and positive Yb anomalies. In comparison to tourmalines from highly-evolved pegmatites, the tourmaline samples from the border zone of the pegmatites of the Rappold Complex contain relatively low amounts of total REE (~8–36 ppm) and Th (0.1–1.8 ppm) and have low La_N/Yb_N ratios. There is a positive correlation (r?≈?0.91) between MgO of the tourmalines and the MgO contents of the surrounding mica schists. We conclude that the pegmatites formed by anatectic melting of mica schists and paragneisses in Permian time. The tourmalines crystallized from the pegmatitic melt, influenced by the metacarbonate and metapelitic host rocks.     

10Be and 26Al exposure‐age dating of bedrock surfaces on the Aran ridge,Wales: evidence for a thick Welsh Ice Cap at the Last Glacial Maximum

This paper presents results of the analysis of paired cosmogenic isotopes (¹⁰Be and ²⁶Al) from eight quartz‐rich samples collected from ice‐moulded bedrock on the Aran ridge, the highest land in the British Isles south of Snowdon. On the Aran ridge, comprising the summits of Aran Fawddwy (905 m a.s.l.) and Aran Benllyn (885 m a.s.l.), ²⁶Al and ¹⁰Be ages indicate complete ice coverage and glacial erosion at the global Last Glacial Maximum (LGM). Six samples from the summit ridge above 750–800 m a.s.l. yielded paired ¹⁰Be and ²⁶Al ages ranging from 17.2 to 34.4 ka, respectively. Four of these samples are very close in age (¹⁰Be ages of 17.5 ± 0.6, 17.5 ± 0.7, 19.7 ± 0.8 and 20.0 ± 0.7 ka) and are interpreted as representing the exposure age of the summit ridge. Two other summit samples are much older (¹⁰Be ages of 27.5 ± 1.0 and 33.9 ± 1.2 ka) and these results may indicate nuclide inheritance. The ²⁶Al/¹⁰Be ratios for all samples are indistinguishable within one‐sigma uncertainty from the production rate ratio line, indicating that there is no evidence for a complex exposure history. These results indicate that the last Welsh Ice Cap was thick enough to completely cover the Aran ridge and achieve glacial erosion at the LGM. However, between c. 20 and 17 ka ridge summits were exposed as nunataks at a time when glacial erosion at lower elevations (below 750–800 m a.s.l.) was achieved by large outlet glaciers in the valleys surrounding the mountains. Copyright © 2011 John Wiley & Sons, Ltd.     

M and Mg values in igneous rocks: proposed usage and a comment on currently employed Fe2O3 corrections

It is proposed that the ‘M value’ of an igneous rock should be 100Mg/(Mg + ΣFe) and that the ‘Mg value’ should be 100Mg/(Mg + Fe²⁺). A plea is made to standardize any necessary corrections for Fe₂O₃ so that $\text{Fe}{}_2\text{O}{}_3\text{(Fe}{}_2\text{O}{}_3\text{+ FeO)}\text{= 02}$ for basic rocks.     

Metal ion complex formation constants of some sedimentary humic acids with Zn(II), Cu(II) and Cd(II)

Metal ion complex formation constants were determined for several sedimentary humic acids (SHA) derived from a fresh water lake and several coastal marine environments, using a method based on size exclusion chromatography. Only one type of binding site was observed in all cases, and conditional log K_f values of between 5 and 7 (at pH 8, I = 0.01 M) were found. Elemental composition of the SHA was similar to soil HA, except that nitrogen content was significantly higher in the SHA. Other chemical properties of the SHA were consistent with those reported by other workers. While spectroscopic measurements indicated that the SHA may have contained significant amounts of polysaccharide compounds which were not removed by conventional separation and purification procedures, analysis indicated only very low levels of polysaccharides were present in the SHA.