Mössbauer spectroscopic studies on the iron forms of deep-sea sediments

Mössbauer spectroscopy was applied to characterize the valence states Fe(II) and Fe(III) in sedimentary minerals from a core of the Peru Basin. The procedure in unraveling this information includes temperature-dependent measurements from 275?K to very low temperature (300?mK) in zero–field and also at 4.2?K in an applied field (up to 6.2?T) and by mathematical procedures (least-squares fits and spectral simulations) in order to resolve individual spectral components. The depth distribution of the amount of Fe(II) is about 11% of the total Fe to a depth of 19?cm with a subsequent steep increase (within 3?cm) to about 37%, after which it remains constant to the lower end of the sediment core (at about 40?cm). The steep increase of the amount of Fe(II) defines a redox boundary which coincides with the position where the tan/green color transition of the sediment occurs. The isomer shifts and quadrupole splittings of Fe(II) and Fe(III) in the sediment are consistent with hexacoordination by oxygen or hydroxide ligands as in oxide and silicate minerals. Goethite and traces of hematite are observed only above the redox boundary, with a linear gradient extending from about 20% of the total Fe close to the sediment surface to about zero at the redox boundary. The superparamagnetic relaxation behavior allows to estimate the order of magnitude for the size of the largest goethite and hematite particles within the particle-site distribution, e.g. ～170?Å and ～50?Å, respectively. The composition of the sediment spectra recorded at 300?mK in zero-field, apart from the contributions due to goethite and hematite, resembles that of the sheet silicates smectite, illite and chlorite, which have been identified as major constituents of the sediment in the <2?μm fraction by X-ray diffraction. The specific “ferromagnetic” type of magnetic ordering in the sediment, as detected at 4.2?K in an applied field, also resembles that observed in sheet silicates and indicates that both Fe(II) and Fe(III) are involved in magnetic ordering. This “ferromagnetic” behavior is probably due to the double-exchange mechanism known from other mixed-valence Fe(II)–Fe(III) systems. A significant part of the clay-mineral iron is redox sensitive. It is proposed that the color change of the sediment at the redox boundary from tan to green is related to the increase of Fe(II)–Fe(III) pairs in the layer silicates, because of the intervalence electron transfer bands which are caused by such pairs.     

Climatic interpretation of the recently extended Vostok ice records

A new ice core drilled at the Russian station of Vostok in Antarctica reached 2755 m depth in September 1993. At this depth, the glaciological time scale provides an age of 260 ky BP (±25). We refine this estimate using records of dust and deuterium in the ice and of ¹⁸O of O₂ in the entrapped air. ¹⁸O of O₂ is highly correlated with insolation over the last two climatic cycles if one assumes that the EGT chronology overestimates the increase of age with depth by 12% for ages older than 112 ky BP. This modified age-depth scale gives an age of 244 ky BP at 2755 m depth and agrees well with the age-depth scale of Walbroeck et al. (in press) derived by orbital tuning of the Vostok D record. We discuss the temperature interpretation of this latter record accounting for the influence of the origin of the ice and using information derived from deuterium-excess data. We conclude that the warmest period of stage 7 was likely as warm as today in Antarctica. A remarkable feature of the Vostok record is the high level of similarity of proxy temperature records for the last two climatic cycles (stages 6 and 7 versus stages 1–5). This similarity has no equivalent in other paleorecords.     

Precambrian basement around Wadi Halfa,Sudan: a new perspective on the evolution of the East Saharan Craton

This paper provides new geochemical and isotopic data on the evolution of the western foreland to the Nubian shield of north-east Africa. There is abundant evidence for early to middle Proterozoic crust west of the River Nile, but this was severely affected by the Pan-African ( 500–900 Ma) orogenic cycle. The results are reported of Rb-Sr whole rock and zircon evaporation geochronological studies and whole rock Sm-Nd and feldspar Pb isotopic analyses for four rock units around Wadi Halfa in northernmost Sudan. These results indicate the presence of heterogeneous pre-Pan-African crustal components, preserved in mylonitic gneisses and in conglomerates that unconformably overlie the gneisses. Several episodes of crust formation, inferred from zircon ages, are preserved in the gneisses : 2.6, 2.4, 2.0, 1.7, 1.2 and 0.72 Ga. Nd model ages for the same units are invariably older than the zircon ages, yet still record a predominantly late Archaean and Palaeoproterozoic history, with depleted mantle model ages between 1.3 and 2.8 Ga. The earliest recorded Pan-African magmatic event is about 720 Ma and dates the beginning of collisional deformation. A younger Pan-African volcanic sequence ( 650 Ma) has isotopic compositions of Sr and Nd compatible with derivation from late Prote rozoic asthenospheric mantle. A 530 Ma anorogenic A-type granite also has isotopic compositions suggesting derivation from a primitive source. The inferred tectonic evolution began with rifting to form an oceanic re-entrant. This was followed by subduction leading to collision at about 700 Ma, accompanied by post-orogenic rifting at about 650 Ma.     

Radar detectability of asteroids: A survey of opportunities for 1977 through 1987

The capability of Earth-based radar to study asteroids is assessed with respect to determining the number of detectible objects and the number of detectable events during the next 10 years. Bar graphs have been prepared showing the number of events and objects falling into 5-db detectability slots based both on estimates of minimum distance and on direct calculations using known orbital elements. These indicate that the Goldstone radar system operating at 3.5-cm wavelength should be able to detect roughly 18 different asteroids at 34 favorable opportunities during the next 10 years. The Arecibo radar system operating at 12.5-cm wavelength may be able to detect 60 asteroids at approximately 97 favorable opportunities in the 10-year period. This sample is sufficiently large that classification of types and correlation with optical data should be possible. The detectability margin for many objects should be large enough to permit more refined analysis of the radar spectrograms. Estimates of the average surface roughness, rotation rate, and direction of the polar axis, as well as estimates of range and Doppler frequency offsets, which can be used to refine the orbital elements, should be otainable for many objects. Equations are given which indicate the variances expected for measurements of cross section, center frequency, and bandwidth measured either singly or jointly. These are functions of the noise-to-signal ratio and other physical parameters such as the backscattering law. Curves are given based on backscattering functions of the form cosⁿθ.     

Provenance and pathways of late Quaternary turbidites in the deep-water Agadir Basin,northwest African margin

A series of individual turbidites, correlated over distances >100 km, are present in the recent fill of the Agadir Basin, offshore northwest Africa. The aim here is to unravel multiple turbidite source areas and flow pathways, and show how turbidite provenance studies contribute to interpretation of flow processes. Agadir Basin turbidites are sourced from four main areas, with the majority originating from the siliciclastic Morocco Shelf; their sand-mud distribution is strongly controlled by flow sediment volume, with relatively low-volume flows dying out within the Agadir Basin and large-volume flows bypassing significant sediment volumes to basins further downslope. Two large-volume volcaniclastic turbidites are attributed to a Canary Islands landslide source, while several small mud-dominated turbidites are interpreted to be locally sourced from hemipelagic-draped seamounts (e.g. Turbidite AB10). Finally, Turbidite AB1 (∼1 ka) is only present in the western Agadir Basin, and is linked to recent “re-activation” of the Sahara Slide headwall. The muddy suspension clouds of three large-volume flows, all linked to large-scale landslides, have covered huge areas of seafloor and flowed along or even slightly upslope for long distances. It is proposed that northeastwards-flowing bottom currents have aided transport of these dilute flow fractions into and across the Agadir Basin.     

Speculations about the Upper Miocene change in abyssal Pacific dissolved bicarbonate δ13C

New data from three Tasman Sea cores support Keigwin's [1] observation that the δ¹³C of Pacific benthic foraminifera (and by inference bottom-water TCO₂) decreased by 0.7‰ at about 6.5 Myr B.P. Simple box models are developed and used to test several hypotheses about the cause of the δ¹³C decrease. We favor the idea that the δ¹³C shift was due to a rapid change in TCO₂ cycling within the oceans (such as would result from either a decrease in upwelling rate, or an increase in the fraction of PO₄^3? reaching the deep oceans in particulate organic matter and a corresponding drop in the preformed PO₄^3? concentration). The δ¹³C decrease across the shift might reflect either a global decrease in upwelling rate, or a different abyssal circulation pattern before the shift.     

Evolution of the Galicia Interior Basin over the last 60 ka: sedimentary processes and palaeoceanographic implications

The Galicia Interior Basin (GIB; NW Iberian Peninsula) is located near a critical transition between the subtropical (temperate) and subpolar (cold) gyres of the North Atlantic. It therefore witnesses oceanographic changes driven by global climatic events. This study reports on the recent (latest Pleistocene) sedimentary, palaeoceanographic and palaeoclimatic history of the basin. We integrated analysis of deep‐sea sediment cores retrieved from an E–W transect across the GIB. The analysis indicated three types of sedimentary processes recording glacial (Marine Isotope Stage 2–4) and deglacial events: along‐slope bottom currents (forming contourite deposits), pelagic and hemipelagic sedimentation, and gravitational dislocation. Variation in depositional patterns and sedimentation rates indicate distinctive transport (along‐slope and down‐slope) and depositional processes. These in turn reflect climatic and oceanographic drivers. We interpret changes in sea level from core evidence showing changes in sediment supply. The cores exhibited conspicuous sedimentary evidence of Heinrich events (HEs). The stratigraphic intervals associated with HEs showed significant lateral variation. We suggest that the lateral variation may result from the development of an oceanographic boundary between surface water masses with different temperature and salinity parameters or changes in surface currents which may have introduced relatively warmer water into the GIB during the last glacial period.