Toxic metal contamination in the lateral lakes of the Coeur d'Alene River valley, Idaho

 The 11 lateral lakes of Coeur d'Alene River valley in northern Idaho have received heavy metal contamination from over a century of upstream mining. The lateral lakes lie within the flood plain of the Coeur d'Alene River, and in their bottom sediments is preserved a stratigraphic record of the upstream mining operations. To characterize the contaminated sediments in the lateral lakes, sampling techniques, including the Livingston piston corer and the Huttenen freeze box, have been developed by Quaternary geologists to preserve the vertical stratigraphy in the samples. From 26 cm to over 55 cm of undisturbed tailing sediments, commonly with “varve-like” features, have been found in each of the lateral lakes, with maximum concentrations by weight of lead at 3.8%, zinc at 3.4%, arsenic at 340 mg/kg, cadmium at 120 mg/kg and mercury at 7 mg/kg. The contamination in the lakes appears to be restricted to the shallow subsurface and heavy metal concentrations generally drop to background levels within a meter of depth. Received: 22 May 1998 · Accepted: 21 September 1998     

Multiproxy analysis of a new terrestrial and a marine Cretaceous-Paleogene (K-Pg) boundary site from New Zealand

An integrated study of palynology, Mössbauer spectroscopy, mineralogy and osmium isotopes has led to the detection of the first K-Pg boundary clay layer in a Southern Hemisphere terrestrial setting. The K-Pg boundary layer was independently identified at centimetre resolution by all the above mentioned methods at the marine K-Pg boundary site of mid-Waipara and the terrestrial site of Compressor Creek (Greymouth coal field), New Zealand. Mössbauer spectroscopy shows an anomaly of Fe-containing particles in both K-Pg boundary sections: jarosite at mid-Waipara and goethite at Compressor Creek. This anomaly coincides with a turnover in vegetation indicated by an interval dominated by fern spores and extinction of key pollen species in both sections. In addition to the terrestrial floristic changes, the mid-Waipara section reveals a turnover in the dinoflagellate assemblages and the appearance of global earliest Danian index species. Geochemical data reveal relatively small iridium enrichments in the boundary layers of 321 pg/g at mid-Waipara and 176 pg/g at Compressor Creek. Unradiogenic ¹⁸⁷Os/¹⁸⁸Os values of the boundary clay reveal the presence of a significant extraterrestrial component. We interpret the accumulation of Fe nano-phases at the boundary as originating from both the impactor and the crystalline basement target rock. The goethite and jarosite are interpreted as secondary phases formed by weathering and diagenesis. The primary phases were probably controlled by the initial composition of the vapor plume and condensation kinetics rather than condensation thermodynamics. This investigation indicates that identification of Fe in nano-phases by Mössbauer spectroscopy is an accurate and cost-effective method for identifying impact event horizons and it efficiently complements widely used biostratigraphic and geochemical methods.     

The stability of the pristine magnetopause

A MHD theory of combined Kelvin-Helmholtz (KH) and Rayleigh-Taylor (RT) instabilities for a transition layer with two different scale lengths (Δ and δ for the variation of velocity/magnetic fields and density, respectively) is presented. The study is motivated by reports of magnetopauses with no low latitude boundary layer, in which a sharp density drop over a distance δ?Δ is observed (“pristine” magnetopauses (J. Geophys. Res. 101 (1996) 49). The theory ignores compressibility effects and applies to subsonic regions of the dayside magnetopause. The RT effect is included to account for temporary periods of acceleration of the magnetopause, caused by sudden changes of the solar wind dynamic pressure. For small wavelengths λ, such that δ?λ?Δ, a WKB solution shows that the velocity gradient operates, together with magnetic tensions, to attenuate or even stabilize the Rayleigh-Taylor instability within a certain wavelength range. An exact dispersion relation for flute modes, valid for all λ, in the form of a fourth order polynomial for the complex frequency ω, is obtained from a model with a constant velocity gradient, dV/dy within Δ, and with δ→0. Flute modes are possible because of the existence of bands of very small magnetic shear on the dayside magnetopause (J. Geophys. Res. 103 (1998) 6703). The exact solution allows for a study of the change of the action of the velocity gradient with λ from the long-λ range where dV/dy is KH destabilizing to the short-λ range where dV/dy produces a stabilizing effect. Both, the WKB approximation and the well known tangential discontinuity model (Δ→0) are recovered as limiting cases of the exact solution. Properties of the KH and RT instabilities, for different density ratios on either side of the magnetopause, are described. For flute modes, at very small λ the RT instability grows faster and becomes the dominant effect. However, it is shown that the growth rate remains bounded at a finite value as λ→0, when a theory with a finite δ model is considered. To study configurations with finite, arbitrary, δ/Δ ratios, the MHD perturbation equations are solved numerically, using hyperbolic tangent functions for both the density and velocity transitions across the magnetopause. To examine the influence of different δ/Δ ratios on the growth rates of KH and RT, calculations are performed for different δ/Δ, with and without acceleration, and for two different density ratios. It is found that the general features exhibited by the constant dV/dy model, are confirmed by these numerical solutions. The stability of pristine magnetopauses, and the possibility of observing some theoretical predictions during magnetopause crossings in ongoing missions, are discussed.