Tectonically driven fluid flow and associated low-grade metamorphism during the Alpine compression in the eastern Iberian Chain (Spain)

Fluid inclusions and clay mineralogy of the Permo-Triassic rocks from the Espina and Espadà Ranges (SE Iberian Chain, Spain) have been investigated to establish their relationship with hydrothermal fluid circulation during the Alpine Orogeny. Primary fluid inclusions in quartz-filled tension gashes in Permo-Triassic sandstones reveal maximum temperatures around 230 °C and very constant salinities of 8.5% wt. eq. NaCl. Secondary fluid inclusions found in quartz from the Santonian Ba–Cu–Hg deposits show similar compositional and thermodynamic characteristics, denoting an Alpine recrystallization. Clay mineral composition of Permo-Triassic mudrocks is characterized by pyrophyillite, indicating low-grade metamorphic conditions. Field observations and experimental data suggest that the crystallization of quartz in tension gashes, the formation of secondary fluid inclusions and the development of the metamorphism are contemporaneous and related to fluid circulation during the Alpine compression. Fluid flow took place along the Hercynian fault system that was reactivated during the Mesozoic rift stage and inverted during the Alpine deformation.     

Conditions of carbonation and wehrlitization of lithospheric peridotite upon interaction with carbonatitic melts

Study of the mechanism of carbonation and wehrlitization of harzburgite upon metasomatism by carbonatitic melts of various genesis was carried out. Experiments with durations of 60–150 h were performed at 6.3 GPa and 1200°C. The data showed that carbonatite with MgO/CaO > 0.3 percolating into the peridotitic lithosphere may provide crystallization of magnesite in it. The influence of all studied carbonatites results in wehrlitization of peridotite. The compositions of melts formed by interaction with harzburgite (～2 wt % SiO₂, Ca# = 36–47) practically do not depend on the composition of the initial carbonatite. Based on the data obtained, we conclude that the formation of magnesite-bearing and magnesite-free metasomatized peridotites may have a significant influence on the CO₂ regime in the further generation of kimberlitic magmas of groups I and II.     

Boninitic geochemical characteristics of high-Mg mafic dykes from the Singhbhum Granitoid Complex,Eastern India

Acta Geochimica - The high-Mg mafic dykes from the Singhbhum Granitoid Complex in East India have geochemical characteristics [e.g., enrichment of the large ion lithophile elements and light rare...     

A large-scale meandering submarine canyon: outcrop example from the late Proterozoic Adelaide Geosyncline, South Australia

The late Proterozoic Adelaide Geosyncline, along with overlying Cambrian strata, comprises a thick sequence of sediments and sparse volcanics which accumulated in a major rift and passive margin setting. During late syn-rift or early post-rift phases, large volumes of terrigenous and carbonate sediments of the late Proterozoic Umberatana and Wilpena Groups and Cambrian Hawker Group filled the rift. Submarine canyon development was related to at least four of these depositional cycles, the most notable of which resulted in incision and subsequent filling of the major (several kilometres in width and up to 1.5 km deep) submarine canyons by the Wonoka Formation. The Wonoka Formation canyons are not obviously fault controlled. They are interpreted to have been eroded by turbidity currents during a relative low-stand of sea-level. They were subsequently filled by a fining-upwards suite of sediments which reflects subsequent relative rise of sea-level and carbonate platform development. Ultimately the canyon complex was buried by north-westerly progradation of overlying fluvial and slope sequences (Billy Springs Beds and possibly correlative upper Pound Subgroup). It is considered likely that more distal elements of this prograding clastic wedge provided the necessary material for canyon erosion, prior to canyon filling and ultimate burial by what may have been elements of the same depositional cycle. It is considered possible that the series of isolated outcrops of canyon cross-sections within the Wonoka Formation are sections of a single canyon thalweg developed within a considerably broader zone of slope degradation. If this interpretation is correct, then the gorge-like Patsy Springs Canyon lies in more proximal regions of the basin-slope, whereas 40 km to the north-east the lower slope is cut by the Fortress Hill Canyon Complex. Palaeocurrent analyses of channel-fill turbidites within the canyons imply that the Fortress Hill Complex is in fact the outcropping western edge of a sinuous, incised canyon thalweg. The Wonoka Formation canyons, containing basal sedimentary breccias but only minor conglomerates, are considered typical of passive margin canyon development. They are contrasted with the generally highly conglomeratic channel-fills observed in outcropping Tertiary and Cretaceous examples of active margin canyons and upper fan valleys.     

On Tension Failure of 2-D Rock Specimens and Associated Acoustic Emission

Summary To understand the failure mechanism of quasi-brittle materials like rock under tensile stress, observations on the failure process of granite and marble plate specimens under tension are summarized and presented. Micro- and macro-failure properties of rock plates under uniaxial tension have been characterized by using an acoustic emission technique. Acoustic emission signals associated with micro-fractures are captured to locate the sources. An algorithm based on arrival time difference is developed for this purpose. The results reveal clearly the failure processes of rock which include initiation, nucleation and propagation of micro-fractures when the axial stress is close to the peak strength of rock. It is believed that the difference in heterogeneity between granite and marble specimens leads to different fracture shapes and different behaviors of associated acoustic emissions. Numerical simulation of acoustic emissions for two-dimensional tensile test is also carried out. The simulated characteristics are in good agreement with the experimental results.     

Hydrothermal fabrication of WO<Subscript>3</Subscript>-modified TiO<Subscript>2</Subscript> crystals and their efficiency in photocatalytic degradation of FCF

WO₃-modified TiO₂ polyscale crystals were fabricated successfully using the hydrothermal technique. The as-prepared samples were characterized using powder X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, photoluminescence spectroscopy and UV–vis spectroscopy. The photocatalytic application of these synthesized samples was confirmed by photocatalytic degradation of fast green dye solution under sunlight and UV irradiation. The degradation efficiency was analyzed by measuring the parameters such as percent transmittance, chemical oxygen demand and percent decomposition of the dye solution. It was noted that the photodegradation efficiency of the samples varies with added amounts of WO₃ content. The highest photodegradation efficiency was obtained using 2WT sample where the pace of decomposition was 70.5% under UV light and 81.3% under sunlight.     

A model of the quiet solar atmosphere

The solar atmosphere may be divided into a number of isolated active components and a quiet residue. On the largest scale the latter is dominated by a general dipole magnetic field of strength 1–2 G; its observable components are flux concentrations in supergranule boundary regions (SBRs), spicules, mottles and polar plumes. The velocity field in the SBRs is discussed. There are continuous gas streaming motions up and down between the photosphere and the corona; spicules may be mainly downward moving gas.A unifying model is developed of these various components, as well as the heating mechanism of the whole quiet atmosphere. Highly ordered velocity fields of the cell, together with a gravitational wave, cause a vertical magnetic force tube to collapse below a critical level; the result is an upward eruption of a vortex ring at the Alfvén velocity. The complex mass velocity pattern may explain spicules, mottles and plumes, as well as unobservable streaming motions.The quiet atmosphere is divided into regions above SBRs and those above the inner parts of the cells. Hydromagnetic eruptions from the former may account for the entire heat requirement of the atmosphere. The model atmosphere has a chromosphere-corona transition layer which bulges upwards above the SBRs and so conforms with EUV data. The energy and mass balances in this solar atmosphere are considered, and it is also shown to be consistent with the radio data.     

Toxicity of tributyltin in the marine mollusc Mytilus edulis

Our previous studies have demonstrated that tributyltin (TBT) is genotoxic to the early life stages of marine mussels and worms. Here, the toxicity of TBT to adult organisms was determined using a suite of biomarkers designed to detect cytotoxic, immunotoxic and genotoxic effects. Exposure of adult mussels, Mytilus edulis, to environmentally realistic concentrations of TBTO for 7 days resulted in a statistically significant decrease in cell viability at concentrations of 0.5 μg/l and above. TBT had no effect on phagocytic activity or antioxidant capacity (FRAP assay). There was a statistically significant increase in DNA damage detected using the comet and micronucleus assays between the controls and 0.5, 1 and 5 μg/l of TBTO (P > 0.0005). Furthermore there was a strong correlation between DNA strand breaks (comet assay) and formation of micronuclei (P = 0.0005; R² = 61.5%). Possible mechanisms by which TBT could damage DNA either directly or indirectly are discussed including the possibility that TBT is genotoxic due to its ability to disrupt calcium homeostasis.