The formation age of ores from the Pebble Cu-Au-Mo giant deposit (Alaska,United States)

Zircons from the porphyry-like quartz-diorite boss of the Pebble Cu-Au-Mo deposit (southwest Alaska) have been examined. By their appearance and internal structure (cathode luminescence and electron probing), the zircons have been subdivided into four genetic groups: (1) xenogenic detrital (mainly rounded); (2) magmatogene (protolith crystal in the center and growth zone at the edge); (3) hydrothermally altered (with new-formed regeneration edges in growth zones); (4) metamict-altered (unconsolidated center of the crystal and sectoring in growth zones). Based on SHRIMP U-Pb dating for the principal heterogeneous elements in every group, the following stages of ore formation have been identified for the Pebble deposit: (a) crystallization of quartz diorite-porphyry bosses (95–92 Ma, the concordant age is 94.7 ± 1.5 Ma); (b) late magmatic metasomatic alterations with copper-molybdenum mineralization (92–85 Ma, the concordant age is 90.15 ± 0.78 Ma); (c) postmagmatic argillization with epithermal gold-sulfide mineralization (82–80 Ma, the concordant age is 82.9 ± 2.7 Ma).     

Mid‐Miocene initiation of E‐W extension and recoupling of the Himalaya

The Tibetan plateau is host to numerous ~N‐S striking graben that have accommodated E‐W directed extension. The development of these structures has been interpreted to reflect a variety of different geological processes including plateau collapse, oroclinal bending or mid‐to‐lower crustal flow. New ⁴⁰Ar/³⁹Ar thermochronology and quartz c‐axis data from the Thakkhola graben of west‐central Nepal show that E‐W extension was ongoing at least locally by the early Miocene (ca. 17 Ma). Our new, and previously published chronologic information on the initiation of graben across the orogen shows that they typically developed immediately after cessation of the South Tibetan detachment system, a structural network that facilitated differential southward movement of the upper and middle crust. We interpret this fundamental switch in orogen kinematics to reflect recoupling of the middle and upper Himalayan crust such that the subsequent widespread flow of the mid‐to‐lower crust out of the system to the east forced brittle accommodation in the upper crust.     

Geometry of a convergent zone, Central British Columbia, Canada

The Canadian Cordillera is separable into two major northerly trending tectonic units—the Pacific Orogen and the Columbian Orogen, with the latter further separated into the Omineca Crystalline Belt and the easterly Rocky Mountain Fold and Thrust Belt. Synkinematic metamorphism of Jurassic age within the Omineca Belt is thought to be associated with accretion of westerly terranes of the Pacific Orogen—more specifically the Quesnellia terrane—that was thrust easterly over the Omineca Belt towards the craton. Mylonitic rocks mark the margin between these two belts and this margin is well-exposed near Crooked Lake, central British Columbia.Structural analysis across the zone of convergence between these two terranes indicates that the cratonic basement and the accreted cover sequences have several phases of deformation and metamorphism in common. The initial common phase of deformation, wherein convergence is accomplished, is characterized by easterly verging folds that are superposed by a second common phase having westerly verging folds that deform the zone of convergence and control the present regional map pattern. A final common phase of deformation produced easterly verging folds.Change in vergence direction is interpreted as resulting from change in direction of transport related to subduction process: first obduction of Quesnellia onto the Omineca craton, followed later by easterly subduction of an oceanic Quesnellia below the craton.All evidence of transport direction(s) points to convergence occurring at very high angles to the zone of convergence. There appears to be no evidence of transport parallel with the strike of the zone. If transport has taken place parallel to the strike of the zone, then this transport occurred before convergence or evidence of this motion has been destroyed during the convergence.     

Nature of polymerization and properties of silicate melts and glasses at high pressure

The structures of sodium silicate and aluminosilicate glasses quenched from melts at high pressure (6-10 GPa) with varying degrees of polymerization (fractions of nonbridging oxygen) were explored using solid-state NMR [¹⁷O and ²⁷Al triple-quantum magic-angle spinning (3QMAS) NMR]. The bond connectivity in melts among four and highly coordinated network polyhedra, such as ^[4]Al, ^[5,6]Al, ^[4]Si, and ^[5,6]Si, at high pressure is shown to be significantly different from that at ambient pressure. In particular, in the silicate and aluminosilicate melts, the proportion of nonbridging oxygen (NBO) generally decreases with increasing pressure, leading to the formation of new oxygen clusters that include 5- and 6-coordinated Si and Al in addition to 4-coordinated Al and Si, such as ^[4]Si-O-^[5,6]Si, ^[4]Si-O-^[5,6]Al and Na-O-^[5,6]Si. While the fractions of ^[5,6]Al increase with pressure, the magnitude of this increase diminishes with increasing degrees of ambient-pressure polymerization under isobaric conditions. Incorporating the above structural information into models of melt properties reproduces the anomalous pressure-dependence of O²⁻ diffusivity and viscosity often observed in silicate melts.     

Plasmasphere convection patterns observed simultaneously from two ground stations

Whistler data recorded during a 14 h period on 10–11 July 1973 at Siple (L = 4.17) and Sanae (L = 3.98) have been used to compare the apparent plasma convection patterns observed from these Antarctic stations. Two distinct bulges in the plasmasphere are seen at both stations, each bulge corresponding to an apparent outflowed followed by in flow of plasma. These structures do not coincide in U.T. or M.L.T. The first bulge is seen at Siple almost 1 h earlier in M.L.T. than at Sanae and the second bulge almost 3 h earlier. This is interpreted in terms of a fairly rapid westward and inward movement of the plasmasphere structure.     

真核生物mRNA折叠结构与生物功能的理论研究

简要介绍和评述了预测ＲＮＡ折叠结构（主要是ＲＮＡ二级结构）的理论方法,对以ＲＮＡ二级结构为基础的ＲＮＡ三级结构的构建方法和分子力学进行了初步探索和研究。真核细胞前体ｍＲＮＡ中内含子的剪接过程涉及剪接位点（内含子的５′、３′剪接位点和分枝点）的核苷序列与一些小蛋白质分子之间特定的专一相互作用。对大量内含子、外显子－内含子－外显子以及外显子－外显子的核苷酸片段二级结构的分析表明,剪接位点大多位于二级结构的环区。剪接位点的这种结构分布特征与剪接过程的化学反应机制相符合,并可以作为识别剪接位点的一种结构信号。对ｍＲＮＡ和由其编码的蛋白质折叠结构进行比较研究后发现,两者之间存在着相关性：两者的二级结构单元（即ｍＲＮＡ二级结构的发夹,蛋白质中α－螺旋和β－折叠片）数基本上相同;蛋白质转角区域与ｍＲＮＡ二级结构的环区对应;两者的结构元素在空间上的排布相一致等。详细分析密码子在ｍＲＮＡ二级结构中的分布还发现,密码子在ＲＮＡ二级结构中的分布规律与氨基酸的构象性质有一定联系。这些结果提示,ｍＲＮＡ与蛋白质之间除了存在一维线性遗传关系外,很可能还存在着某种三维结构的遗传关系     

墨西哥湾西北部陆坡气体水合物资源评价

气体水合物是一种似冰状的结晶物质 ,烃类和非烃类气体赋存于水分子笼形格架内。全球海底气体水合物储集层可能含有２×１０１４（Ｓｏｌｏｖｉｅｗ，２０００）～７．６×１０１７ ｍ３（Ｄｂｒｙｎｉｎ等，１９８１）的甲烷。目前 ,在墨西哥湾西北部陆坡水深４４０～＞２４００ｍ处采集了５０个热成因和细菌成因的气体水合物样品。通过活塞柱状取样和科学考察深潜器 ,研究者已经从海底取到细菌成因Ⅰ型构造的甲烷水合物和热成因Ⅱ型和Ｈ型的气体水合物。近年来 ,ＧＯＭ (墨西哥湾 )深水区已经成为对石油勘探具有重要意义的地区。１９９９…     

Wave diffraction and near-trapping by a multi-column gravity-based structure

This paper is concerned with the diffraction of water waves by offshore structures, with the ultimate aim of proposing tools for guiding airgap design. The diffraction of monochromatic waves by an array of four bottom mounted cylinders and a gravity-based structure is studied in detail using linear and second order theory. The phenomenon of near-trapping is investigated, allowing guidelines for airgap design to be established. When contemplating airgap design, however, it is crucially important that consideration is given to the largest waves in a sea state. Therefore, in this study a design wave, called NewWave, is proposed as a realistic model for large ocean waves and is used as the incident wave field in the wave-structure diffraction analysis.     

An inventory of factors that affect polysaccharide production by Phaeocystis globosa

Phaeocystis material contains polysaccharides that are built from at least eight different monosaccharides. Differences have been reported between the carbohydrate composition of different Phaeocystis species, and also between samples taken from Phaeocystis globosa blooms in different areas. In order to elucidate factors that could play a role in determining variation in carbohydrate composition and production, a number of Phaeocystis globosa strains were studied under laboratory conditions. Although there was a clear distinction of a northern and a southern cluster in the Phaeocystis globosa strains based on RAPD analysis, the differences in the composition of the mucopolysaccharides were relatively small. The contribution of glucose, however, ranged from 7–85% of total sugars. A strain that was cultured in seawaters of diverse origin produced polysaccharides of a different composition, suggesting the effect of environmental factors. The presence of bacteria affected neither the amount, nor the composition of the carbohydrates that were produced by Phaeocystis globosa. Glucose is part of both the intracellular polysaccharide pool and of the mucopolysaccharides in the colony matrix. Using specific digestion of the intracellular chrysolaminaran by laminarinase, the distribution of polysaccharides over different pools could be assessed. During growth of an axenic, mucus-producing strain, the portion of glucose present as chrysolaminaran appeared to increase. The polyglucose that was not digested by laminarinase remains unidentified. This study shows that environmental factors rather than strain differences determine differences in the sugar composition of Phaeocystis globosa, especially with respect to the glucose content of the material. A difference in the contribution of glucose could be correlated to the portion of cells in the culture that are not in the colonies. Our study emphasises that for studying polysaccharide dynamics in Phaeocystis globosa it is important to be able to discriminate between the different polysaccharide pools. Preliminary results of an enzymatic approach were promising