3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.     

Weathering of ilmenite from Chavara deposit and its comparison with Manavalakurichi placer ilmenite,southwestern India

The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10^?6 m³ kg^?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb₂O₅ (0.28%), Cr₂O₃ (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO₂ (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe³⁺/Fe²⁺ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene.     

Characterization of permineralized kerogen from an Eocene fossil fern

The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state ¹³C nuclear magnetic resonance spectroscopy (¹³C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, ¹³C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants.     

Late Ordovician stratigraphy northwest of the Sugarloaf,mid-Wales — a discussion

Several modifications are proposed to the Ordovician stratigraphy recently proposed by Mackie and Smallwood (1987), based in particular on the recognition of a major Mynydd Trawsnant anticline on the northwest flank of the Tywi structure and on field relationships indicating the Foel Formation directly to overlay the Caradoc black shale succession and directly to underlay the Craig Las Formation. The Clyn Glas Formation is suggested to have accumulated at a slope base rather than a shelf–slope break.     

On the propagation of chromospheric condensations in solar flares (II)

We study the evolution of the mass motion velocity in the chromospheric condensation, when it propagates into the deeper atmosphere. The condensation is represented by a shock-like structure. Its momentum equation can be solved after some approximations. The computations are carried out for two cases, i.e., the case that the gas pressure just behind the condensation front is constant and the case that the pressure increase at the top of the condensation is constant. The results show that the duration of the condensation in the second case is considerably longer than that in the first case. The most evident difference of the velocity evolution between the two cases appears in their later phase. A comparison of the results in this paper with the dynamic simulations indicates that the second case may be closer to the real situation.     

Energy release in a prominence-loaded flaring loop

Zaitsev and Stepanov (1991, 1992) proposed a mechanism for energy release in solar flares that involves the intrusion of dense prominence material into a coronal loop. The resulting non-steady state conditions are claimed to increase the resistance of the loop by 8–10 orders of magnitude. It is shown here that the dramatic increase in resistance calculated by Zaitsev and Stepanov depends on a gross overestimate of the of the magnitude of the magnetic force in the loop prior to the flare trigger. A more realistic estimate of the increase due to the mechanism suggests that it is by no more than about four orders of magnitude. As a consequence, the prominence-loading mechanism does not provide a tenable flare model.     

Spectrophotometric observations of variable stars

We present the results of our visual and near-infrared spectrophotometric observations for 77 variable stars obtained during 1971–1991 in Chile, Armenia, and Bolivia. The quasi-monochromatic, extraatmospheric fluxes from the stars are given in absolute energy units (W m^?2 m^?1) at all wavelengths of the spectral range at 2.5-nm intervals.     

Photospheric Magnetic Field: Relationship Between North–South Asymmetry and Flux Imbalance

Photospheric magnetic fields were studied using the Kitt Peak synoptic maps for 1976?–?2003. Only strong magnetic fields (B>100 G) of the equatorial region were taken into account. The north–south asymmetry of the magnetic fluxes was considered as well as the imbalance between positive and negative fluxes. The north–south asymmetry displays a regular alternation of the dominant hemisphere during the solar cycle: the northern hemisphere dominated in the ascending phase, the southern one in the descending phase during Solar Cycles 21?–?23. The sign of the imbalance did not change during the 11 years from one polar-field reversal to the next and always coincided with the sign of the Sun’s polar magnetic field in the northern hemisphere. The dominant sign of leading sunspots in one of the hemispheres determines the sign of the magnetic-flux imbalance. The sign of the north–south asymmetry of the magnetic fluxes and the sign of the imbalance of the positive and the negative fluxes are related to the quarter of the 22-year magnetic cycle where the magnetic configuration of the Sun remains constant (from the minimum where the sunspot sign changes according to Hale’s law to the magnetic-field reversal and from the reversal to the minimum). The sign of the north–south asymmetry for the time interval considered was determined by the phase of the 11-year cycle (before or after the reversal); the sign of the imbalance of the positive and the negative fluxes depends on both the phase of the 11-year cycle and on the parity of the solar cycle. The results obtained demonstrate the connection of the magnetic fields in active regions with the Sun’s polar magnetic field in the northern hemisphere.     

Comments on the BDT-FRW solutions with a cosmological constant

Some critical comments are made on the power-law solutions recently given by Pimentel (1985) on the basis of the Brans-Dicke field equations for Friedmann-Robertson-Walker space-times.