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51.
Olivine metagabbros from the Adirondacks usually contain both clear and spinel-clouded plagioclase, as well as garnet. The latter occurs primarily as the outer rim of coronas surrounding olivine and pyroxene, and less commonly as lamellae or isolated grains within plagioclase. The formation of garnet and metamorphic spinel is dependent upon the anorthite content of the plagioclase. Plagioclase more sodic than An38±2 does not exhibit spinel clouding, and garnet rarely occurs in contact with plagioclase more albitic than An36±4. As a result of these compositional controls, the distribution of spinel and garnet mimics and visually enhances original igneous zoning in plagioclase. Most features of the arrangement of clear (unclouded) plagioclase, including the shells or moats of clear plagioclase which frequently occur inside the garnet rims of coronas, can be explained on the basis of igneous zoning. The form and distribution of the clear zones may also be affected by the metamorphic reactions which have produced the coronas, and by redistribution of plagioclase in response to local volume changes during metamorphism.Authors listed alphabeticallyPublished by permission of the Director, New York State Museum, Journal Series Number 299 相似文献
52.
Gold mineralization at Hutti is confined to a series of nine parallel, N–S to NNW–SSE trending, steeply dipping shear zones.
The host rocks are amphibolites and meta-rhyolites metamorphosed at peak conditions of 660±40°C and 4±1 kbar. They are weakly
foliated (S1) and contain barren quartz extension veins. The auriferous shear zones (reefs) are typically characterized by four alteration
assemblages and laminated quartz veins, which, in places, occupy the entire reef width of 2–10 m, and contain the bulk of
gold mineralization. A <1.5 m wide distal chlorite-sericite (+biotite, calcite, plagioclase) alteration zone can be distinguished
from a 3–5 m wide proximal biotite-plagioclase (+quartz, muscovite, calcite) alteration zone. Gold is both spatially and temporally
associated with disseminated arsenopyrite and pyrite mineralization. An inner chlorite-K-feldspar (+quartz, calcite, scheelite,
tourmaline, sphene, epidote, sericite) alteration halo, which rims the laminated quartz veins, is characterized by a pyrrhotite,
chalcopyrite, sphalerite, ilmenite, rutile, and gold paragenesis. The distal chlorite-sericite and proximal biotite-plagioclase
alteration assemblages are developed in microlithons of the S2–S3 crenulation cleavage and are replaced along S3 by the inner chlorite-K-feldspar alteration, indicating a two-stage evolution for gold mineralization. Ductile D2 shearing, alteration, and gold mineralization formed the reefs during retrograde evolution and fluid infiltration under upper
greenschist to lower amphibolite facies conditions (560±60°C, 2±1 kbar). The reefs were reactivated in the D3 dextral strike-slip to oblique-slip environment by fault-valve behavior at lower greenschist facies conditions (ca. 300–350°C),
which formed the auriferous laminated quartz veins. Later D4 crosscutting veins and D5 faults overprint the gold mineralization. The alteration mineralogy and the structural control of the deposit clearly points
to an orogenic style of gold mineralization, which took place either during isobaric cooling or at different levels of the
Archean crust. From overlaps in the tectono-metamorphic history, it is concluded that gold mineralization occurred during
two tectonic events, affecting the eastern Dharwar craton in south India between ca. 2550 – 2530 Ma: (1) The assemblage of
various terranes of the eastern block, and (2) a tectono-magmatic event, which caused late- to posttectonic plutonism and
a thermal perturbation. It differs, however, from the pre-peak metamorphic gold mineralization at Kolar and the single-stage
mineralization at Ramagiri. Notably, greenschist facies gold mineralization occurred at Hutti 35–90 million years later than
in the western Dharwar craton.
Editorial handling: G. Beaudoin 相似文献
53.
Albite gneisses containing up to 8.7 percent Na2O and as little as 0.1% K2O comprise a significant part of the Proterozoic Lyon Mountain Gneiss in the Ausable Forks Quadrangle of the northeastern Adirondacks, New York State. Two distinct types of albite gneisses are present. One is a trondhjemitic leucogneiss (LAG) consisting principally of albite (Ab95–Ab98) and quartz with minor magnetite and, locally, minor amounts of amphibole or acmiterich pyroxene. LAG probably originated by metamorphism of a rhyolitie or rhyodacitic ash-flow tuff with A-type geochemical affinities, following post-depositional analcitization in a saline or saline-alkaline environment. The other type is a mafic albite gneiss (MAG) containing albite and pyroxene along with 0–45 percent quartz, minor amphibole, and titanite. MAG locally displays pinstripe banding and contains albite (Ab98) megacrysts up to 5 cm across. Its precursor may have been a sediment composed of diagenetic analcite or albite, dolomite, and quartz. Both types of albite gneiss are interlayered with granitic gneisses (LMG) of variable composition derived from less altered tuffs. A potassium-rich (up to 9.7% K2O) microcline gneiss facies may have had a protolith rich in diagenetic K feldspar. We propose that the albite gneisses and associated granitic gneisses are the granulite-facies metamorphic equivalent of a bimodal, dominantly felsic, volcanic suite with minor intercalated sediments, probably including evaporites. The volcanics were erupted in an anorogenic setting, such as an incipient or failed intracontinental rift. Deposition took place in a closed-basin, playa lake environment, where diagenetic alteration resulted in redistribution of the alkalis and strong oxidation. 相似文献
54.
Assessing Winter Wheat Responses to Climate Change Scenarios: A Simulation Study in the U.S. Great Plains 总被引:3,自引:0,他引:3
Hard red winter wheat (Triticum aestivum L.) is a major crop in the Great Plains region of the U.S. The goal of this assessment effort was to investigate the influence of two contrasting global climate change projections (U.K. Hadley Center for Climate Prediction and Research and Canadian Centre for Climate Modelling and Analysis) on the yield and percent kernel nitrogen content of winter wheat at three locations in Nebraska. These three locations represent sub-humid and semi arid areas and the transition between these areas and are also representative of major portions of the winter wheat growing areas of the central Great Plains. Climate scenarios based on each of the projections for each location were developed using the LARS-WG weather generator along with data from automated weather stations. CERES-Wheat was used to simulate the responses for two contrasting cultivars of wheat using two sowing dates. The first sowing date represented current sowing dates appropriate for each location. The second sowing date was later and represents the approximate date when the mean air temperature from the climate scenarios is the same as the mean air temperature from the actual climate data at the current sowing dates. The yield and percent kernel nitrogen content using the two climate scenarios generally decrease going from the sub-humid eastern to the semi arid western parts of Nebraska. Results from these simulations indicate that yield and percent kernel nitrogen content using the two climate scenarios could not both be maintained at levels currently simulated. Protein content (directly related to kernel nitrogen content) and end-use quality are the primary determinants for the use of hard red winter wheat in baked goods. Nitrogen management and new cultivars, which can enhance the uptake and translocation of nitrogen, will be proactive steps to meet the challenges of global climate change as represented by these climate scenarios. 相似文献
55.
Mark P. S. Krekeler Julie Morton Jill Lepp Cynthia M. Tselepis Mikhail Samsonov Lance E. Kearns 《Environmental Geology》2008,55(1):123-147
Clay-rich mine tailings from phosphate mine operations in Florida are a major environmental and economic problem. Options
for reclamation and restoration for these tailings are very limited and are fundamentally restricted by poor physical properties
such as low mechanical strength, low hydraulic conductivity, and heavy metal content. The major control on these bulk physical
properties is the mineralogy of the materials. Eight continuous push borings were obtained to investigate stratigraphy, mineralogy,
aspects of geochemistry, and bulk properties of a deposit of clay-rich mine tailings from a phosphate mine near Bartow, Florida
that ceased operations in the early 1970s. Stratigraphy is dominated by laminated clay-rich sediment with minor units of silt
and sand. An intact kaolinite liner occurs near the impoundment walls and the impoundment floor has approximately 4 m of relief.
Moisture content varies from 4.35 to 57.40 wt% and organic content varies from 0.41 to 9.53 wt%. Bulk XRF investigation indicates
that the P2O5 concentrations vary from approximately 4 to 21 wt%. A very strong correlation (r
2 = 0.92) between CaO and P2O5 indicates that apatite is a major control on the phosphate. The strong correlation (r
2 = 0.77) of Al2O3 and TiO2 suggests that the source materials for this deposit are comparatively uniform. A number of heavy metal elements and trace
elements occur. Cr, V, Ni, Cu are interpreted to be in phosphate minerals, largely apatite. Sr and Pb are interpreted to be
in both phyllosilicates and phosphate minerals. Two populations of apatite were observed in the clay-sized fraction, one that
was Fe and Si- bearing and another that was only Si-bearing. Fe-bearing apatite had Fe2O3 contents that varied from 0.38 to 5.32 wt% and SiO2 contents that varied from 0.90 to 3.32 wt%. The other apatite population had a wider range of SiO2 contents that varied from 0.77 to 8.80 wt%. TEM imaging shows that apatite grains are dominantly single crystals with lesser
amounts of aggregates. Wavellite commonly occurs as individual or clusters of lath-like crystals and the chemical composition
differs from the pure aluminium phosphate end member with average concentrations of components being that of CaO (1.57 wt%),
Fe2O3 (1.98 wt%), SiO2 (5.94 wt%). In the clay-sized phosphate minerals investigated no fluorine was found above detection limit (approximately
0.15 wt%), nor was any uranium, radium, heavy metal, or REE element detected. The phyllosilicate mineralogy of the deposit
is dominated by smectite (montmorillonite with lesser amounts of nontronite), palygorskite, illite and kaolinite. No systematic
variation in the relative proportions of phyllosilicates was observed in the clay deposit. Energy dispersive spectroscopy
EDS analysis indicates that chemical compositions of phyllosilicates are somewhat typical but overall are enriched with respect
to Fe compared to theoretical end members. The relative enrichment of Fe is interpreted to be a primary sedimentary feature.
Ca content in smectite minerals is high and may inhibit stabilization using lime or similar methods. The high percentages
of montmorillonite and palygorskite explain the high bulk water contents observed. This investigation provides fundamentally
new details regarding clay tailing deposits from closed phosphate mines in central Florida which can be used in restoration
and reclamation efforts. 相似文献
56.
Sarah J. Nelson Kenneth B. Johnson Kathleen C. Weathers Cynthia S. Loftin Ivan J. Fernandez Jeffrey S. Kahl David P. Krabbenhoft 《Applied Geochemistry》2008
Atmospheric mercury (Hg) is delivered to ecosystems via rain, snow, cloud/fog, and dry deposition. The importance of snow, especially snow that has passed through the forest canopy (throughfall), in delivering Hg to terrestrial ecosystems has received little attention in the literature. The snowpack is a dynamic system that links atmospheric deposition and ecosystem cycling through deposition and emission of deposited Hg. To examine the magnitude of Hg delivery via snowfall, and to illuminate processes affecting Hg flux to catchments during winter (cold season), Hg in snow in no-canopy areas and under forest canopies measured with four collection methods were compared: (1) Hg in wet precipitation as measured by the Mercury Deposition Network (MDN) for the site in Acadia National Park, Maine, USA, (2) event throughfall (collected after snowfall cessation for accumulations of >8 cm), (3) season-long throughfall collected using the same apparatus for event sampling but deployed for the entire cold season, and (4) snowpack sampling. Estimates (mean ± SE) of Hg deposition using these methods during the 91-day cold season in 2004–2005 at conifer sites showed that season-long throughfall Hg flux (1.80 μg/m2) < snowpack Hg (2.38 ± 0.68 μg/m2) < event throughfall flux (5.63 ± 0.38 μg/m2). Mercury deposition at the MDN site (0.91 μg/m2) was similar to that measured at other no-canopy sites in the area using the other methods, but was 3.4 times less than was measured under conifer canopies using the event sampling regime. This indicates that snow accumulated under the forest canopy received Hg from the overstory or exhibited less re-emission of Hg deposited in snow relative to open areas. The soil surface of field-scale plots were sprayed with a natural rain water sample that contained an Hg tracer (202Hg) just prior to the first snowfall to explore whether some snowpack Hg might be explained from soil emissions. The appearance of the 202Hg tracer in the snowpack (0–64% of the total Hg mass in the snowpack) suggests that movement of Hg from the soil into the snowpack is possible. However, as with any tracer study the 202Hg tracer may not precisely represent the reactivity and mobility of natural Hg in soils. 相似文献
57.
Donna L. Whitney Christian Teyssier Seth C. Kruckenberg Valerie L. Morgan Lindsay J. Iredale 《Lithos》2008,101(3-4):218-232
Kilometer-scale lenses of quartz-rich metasedimentary rocks crop out in a discontinuous belt along the southern margin of the Menderes Massif, Turkey, and preserve evidence for high-pressure–low-temperature (HP–LT) metamorphism related to subduction of a continental margin during Alpine orogeny. Kyanite schist, quartzite, and quartz veins contain kyanite + phengite + Mg-chlorite, and the veins also contain magnesiocarpholite. A deformed carbonate metaconglomerate juxtaposed with the quartzite-dominated unit does not contain HP index minerals, and likely represents the tectonized boundary of the siliceous rocks with adjacent marble. The HP–LT rocks (10–12 kbar, 470–570 °C) record different pressure conditions than the adjacent, apparently lower pressure Menderes metasedimentary sequence. Despite this difference there is disagreement as to whether these HP–LT rocks are part of the Menderes sequence or are related to the tectonically overlying Cycladic blueschist unit. If the former, the entire southern Menderes Massif experienced HP–LT metamorphism but the evidence has been obliterated from most rocks; if the latter, rocks recording different metamorphic-kinematic conditions experienced different tectonic histories and were tectonically juxtaposed during thrusting. Based on observations and data in this study, the second model better accounts for the differences in P–T-deformation histories of the southern Menderes Massif rocks, and suggests that the HP–LT rocks are not part of the Menderes cover sequence. 相似文献
58.
M. -S. Krienitz R. B. Trumbull A. Hellmann J. Kolb F. M. Meyer M. Wiedenbeck 《Mineralium Deposita》2008,43(4):421-434
We determined the boron isotope and chemical compositions of tourmaline from the Hira Buddini gold deposit within the Archean
Hutti-Maski greenstone belt in southern India to investigate the evolution of the hydrothermal system and to constrain its
fluid sources. Tourmaline is a minor but widespread constituent in the inner and distal alteration zones of metabasaltic and
metadacite host rocks associated with the hydrothermal gold mineralization. The Hira Buddini tourmaline belongs to the dravite–schorl
series with variations in Al, Fe/(Fe+Mg), Ca, Ti, and Cr contents that can be related to their host lithology. The total range
of δ11B values determined is extreme, from −13.3‰ to +9.0‰, but 95% of the values are between −4 and +9‰. The boron isotope compositions
of metabasalt-hosted tourmaline show a bimodal distribution with peak δ11B values at about −2‰ and +6‰. The wide range and bimodal distribution of boron isotope ratios in tourmaline require an origin
from at least two isotopically distinct fluid sources, which entered the hydrothermal system separately and were subsequently
mixed. The estimated δ11B values of the hydrothermal fluids, based on the peak tourmaline compositions and a mineralization temperature of 550°C,
are around +1 and +10‰. The isotopically lighter of the two fluids is consistent with boron released by metamorphic devolatilization
reactions from the greenstone lithologies, whereas the 11B-rich fluid is attributed to degassing of I-type granitic magmas that intruded the greenstone sequence, providing heat and
fluids to the hydrothermal system.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
59.
Deformation-induced polymorphic transformation: experimental deformation of kyanite, andalusite, and sillimanite 总被引:1,自引:0,他引:1
Eric T. Goergen Donna L. Whitney Mark E. Zimmerman Takehiko Hiraga 《Tectonophysics》2008,454(1-4):23-35
Torsion experiments were performed on the Al2SiO5 polymorphs in the sillimanite stability field to determine basic rheological characteristics and the effect of deformation on polymorphic transformation. The experiments resulted in extensive transformation of andalusite and kyanite to sillimanite. No transformation occurred during the hot-press (no deformation) stage of sample preparation, which was carried out at similar P–T conditions and duration as the torsion experiments. Experiments were conducted on fine-grained (< 15 µm) aggregates of natural andalusite, kyanite and sillimanite at 1250 °C, 300 MPa, and a constant shear strain rate of 2 × 10− 4/s to a maximum shear strain of 400%. Electron back-scattered diffraction (EBSD) analysis of the experiments revealed development of lattice-preferred orientations, with alignment of sillimanite and andalusite [001] slightly oblique to the shear plane. The kyanite experiment could not be analyzed using EBSD because of near complete transformation to sillimanite. Very little strain ( 30%) is required to produce widespread transformation in kyanite and andalusite. Polymorphic transformation in andalusite and kyanite experiments occurred primarily along 500 µm wide shear bands oriented slightly oblique and antithetic to the shear plane and dominated by sub-µm (100–150 nm) fibrolitic sillimanite. Shear bands are observed across the entire strain field preserved in the torsion samples. Scanning transmission electron microscope imaging shows evidence for transformation away from shear bands; e.g. fibrolitic rims on relict andalusite or kyanite. Relict grains typically have an asymmetry that is consistent with shear direction. These experimental results show that sillimanite is by far the weakest of the polymorphs, but no distinction can yet be made on the relative strengths of kyanite and andalusite. These observations also suggest that attaining high bulk strain energy in strong materials such as the Al2SiO5 polymorphs is not necessary for triggering transformation. Strain energy is concentrated along grain boundaries, and transformation occurs by a dynamic recrystallization type process. These experiments also illustrate the importance of grain-size sensitive creep at high strains in a system with simultaneous reaction and deformation. 相似文献
60.
Climate change is one of the most compelling challenges for science communication today. Societal reforms are necessary to reduce the risks posed by a changing climate, yet many people fail to recognize climate change as a serious issue. Unfortunately, the accumulation of scientific data, in itself, has failed to compel the general public on the urgent need for pro-environmental policy action. We argue that certain metaphors for the human-environment relationship can lead people to adopt a more nuanced and responsible conception of their place in the natural world. In two studies, we tested properties of multiple metaphors with the general public (study 1) and experts on climate change (study 2). The metaphor “the earth is our home” resonated with climate experts as well as diverse subpopulations of the general public, including conservatives and climate-change deniers. 相似文献