Organic compounds in produced waters from coalbed natural gas wells in the Powder River Basin,Wyoming, USA

The organic composition of produced water samples from coalbed natural gas (CBNG) wells in the Powder River Basin, WY, sampled in 2001 and 2002 are reported as part of a larger study of the potential health and environmental effects of organic compounds derived from coal. The quality of CBNG produced waters is a potential environmental concern and disposal problem for CBNG producers, and no previous studies of organic compounds in CBNG produced water have been published. Organic compounds identified in the produced water samples included: phenols, biphenyls, N-, O-, and S-containing heterocyclic compounds, polycyclic aromatic hydrocarbons (PAHs), aromatic amines, various non-aromatic compounds, and phthalates. Many of the identified organic compounds (phenols, heterocyclic compounds, PAHs) are probably coal-derived. PAHs represented the group of organic compounds most commonly observed. Concentrations of total PAHs ranged up to 23 μg/L. Concentrations of individual compounds ranged from about 18 to <0.01 μg/L. Temporal variability of organic compound concentrations was documented, as two wells with relatively high organic compound contents in produced water in 2001 had much lower concentrations in 2002.     

Kinematics of the Danakil microplate

A refinement and extrapolation of recent motion estimates for the Danakil microplate, based on ancient kinematic indicators in the Afar region, describes the evolution of a microplate in the continental realm. The Danakil horst is an elevated part of this microplate, exposing a Precambrian basement within the Afar depression, the site of the Nubia-Somalia-Arabia triple junction. We compare evidence for strike- or oblique-slip faults in data from the Afar depression and southern Red Sea to small circles about published poles of rotation for the Danakil microplate with respect to Nubia. A reconstruction about the preferred pole reunites lengths of a Precambrian shear zone on the Nubia and Danakil sides and preserves a uniform basement fabric strike through Nubia, Danakil and Yemen. Since at least magnetic chron C5 (∼11 Ma) Danakil rotated about a different pole with respect to Nubia than either Somalia or Arabia, but between chrons C5 and C2A Nubia-Danakil motion was a close approximation to Nubia-Somalia motion. Since C2A relative motions of the Danakil microplate have been independent of movements on any of the neighbouring plate boundaries. We relate this to the onset of oceanic-type accretion within Afar. The resulting eastwards acceleration of Danakil was accommodated by westwards propagation of the Gulf of Aden rift that became the new, discrete, plate boundary between the Danakil microplate and the Somalia plate. Present-day activity suggests that the Red Sea and Aden rifts will link through Afar, thereby isolating the Danakil horst as a microcontinent on the Arabian margin.     

Isotopic study of sulfate sources and residence times in a subalpine watershed

Stable sulfur and oxygen isotope ratios and naturally occurring ³⁵S_SO4 activities were used to examine sulfate sources, address the role of sulfur dynamics, and estimate residence times of atmospherically derived sulfate in Loch Vale Watershed, Colorado. In 1996, surface water samples from small streams flowing through talus, forest, and wetland areas had '³⁴S_SO4 values ranging from 1.8 to 3.7‰. Values of '¹⁸O_SO4 at the three sites ranged from -1.3 to 3.7‰. Average '³⁴S_SO4 and '¹⁸O_SO4 values in Loch Vale precipitation (1991-1999) are higher (5.2 and 13.6, respectively) than surface water values, indicating that some of the deposited sulfate is transformed and/or mixed with other sulfur sources in the watershed (e.g. mineral and organic sulfur). Sulfate ages determined by ³⁵S_SO4 activities support this and show that deposited sulfate may be stored on a timescale of 1 year or more prior to being released to surface waters.     

Counterclockwise P-T-t trajectory from the metamorphic sole of a Neo-Tethyan ophiolite (Turkey)

The Kiziltepe ophiolitic thrust sheet in the Bolkar Mountains of Turkey occurs between two subparallel ophiolite belts bounding the Tauride carbonate platform and represents a remnant of the Cretaceous Neo-Tethyan oceanic lithosphere. It is underlain by foliated amphibolite that represents a metamorphic sole developed at the inception of an intra-oceanic subduction zone in the Neo-Tethys 92-90 Ma. Blueschist-facies overprinting of the amphibolite indicates that the metamorphic sole was dragged deeper into the subduction zone where it experienced increasing P/T with cooling. Regional tectonic constraints suggest a Maastrichtian age for the timing of this blueschist-facies metamorphism. Sodic amphibole-rich veins and crossite/Mg-riebeckite rims on hornblende suggest that growth of blueschist-facies minerals was facilitated by infiltration of fluid along fractures and grain boundaries. We infer a counterclockwise P-T-t trajectory during which metamorphism was accompanied/succeeded by rapid uplift along the northern edge of the Tauride belt in Late Cretaceous-early Tertiary time.     

Impact of Turbidity on TCE and Degradation Products in Ground Water

Elevated particulate concentrations in ground water samples can bias contaminant concentration data. This has been particularly problematic for metal analyses where artificially increased turbidity levels can affect metals concentrations and confound interpretation of the data. However, few studies have been conducted to determine the impact of particulates on trichloroethylene (TCE), cis-dichloroethylene (c-DCE), and vinyl chloride concentrations.
Laboratory batch studies and field investigations were conducted to evaluate the effects of suspended solids on VOC concentrations in ground water samples analyzed by purge-and-trap gas chromatography. Three different solids were used to assess the effects of suspended particulates. The solids were aquifer material from a field site in North Carolina and two reference clay minerals (kaolinite and Namontimorillonite). During the laboratory portion of this study, the solids were used to determine effects on TCE concentrations under controlled laboratory conditions.
The same solids were used in a field study to compare the laboratory results with field results. Solids were added to the sample vials prior it) sample collection to intentionally increase turbidity levels in the water samples. Results of the study indicate essentially no decrease in TCE, c-DCH, or vinyl chloride concentrations due to increased turbidity levels.     

Landscape evolution of the Five Islands of south Louisiana: scientific policy and salt dome utilization and management

The Five Islands of south central Louisiana are piercement-type salt domes uplifted from several kilometers depth as the surrounding strata experiences regional subsidence. In general, the domes are nearly circular in plan with maximum land surface elevations 23–52 m asl. Geomorphic evidence of salt-induced uplift includes surface lineations, aligned gullies, excessively steep land surface topography, and shear fractures in surficial sediments. Evidence of subsidence includes sinkhole ponds a few hectares in area, broad topographic saddles over tens of hectares in size, and kilometer-scale collapse structures.On each of the Five Islands, Peoria Loess and silty colluvium bury a paleosol developed in the Late Pleistocene Prairie Complex of the Lower Mississippi Valley. The loess represents a single genetic unit of eolian origin, is typically thickest on lower side slopes, and is thin or absent on ridge crests. The silty colluvium around the perimeter of the islands is a reworked loess derived from higher elevations. Shear fractures with high-angle average dips occur in both Peoria Loess and the Prairie Complex. Conjugate shear pairs probably develop from extensional stress associated with vertical uplift of the underlying salt.Prairie Complex deposition and initial soil development in a low-relief alluvial plain of the Mississippi River predates the latest emergence of the Five Islands. Loess and colluvial stratigraphy indicate that the domes were emergent during loess deposition. Gully incision, shearing of Quaternary sediments, and the distribution of colluvium indicate continued uplift after loess deposition. Sinkholes and collapse structures are influenced by salt dissolution and corrasion, whereas broad subsidence areas and topographic saddles form over areas of structural weakness within the salt.Five Islands landscape evolution is controlled by the interaction of driving and resisting forces that operate over various time scales. Diapiric uplift is a driving force of net upwards motion, and the external and internal salt dome hydrology are driving forces of solution and corrasion. The structure and lithology of the internal salt stocks and the surrounding sediments are heterogeneous and have variable strength. Collectively, this interaction produces both uplift and subsidence features across the salt dome landscape.Resource use at the Five Islands correlate with instability of both underground facilities and the surface landscape. Uplift of the Five Islands has continued since at least the Late Pleistocene, is probably still active at present, and periods of tectonic and geomorphic instability are possible in the future. Sediments overlying salt domes record discrete periods of surface uplift and periods of episodic and incremental subsidence that is common where salt domes pierce surficial sediment. The rate, magnitude, and pattern of landscape modification by salt domes have implications for the safe utilization of mineral extraction and geostorage facilities. Geomorphic evaluation of salt dome landscapes can help to develop policies that ensure safe salt dome utilization. Salt dome resource planning should include detailed characterization of internal and external stratigraphy and structure; modeling of geomorphic, soil and rock mechanic, and hydrologic processes; routine and emergency planning at operating facilities; and closure and post-closure plans.     

Estimating Stable Measured Values and Detecting Anomalies in Groundwater Geochemistry Time Series Data Across the Athabasca Oil Sands Area,Canada

Regional groundwater monitoring in the Athabasca region of Alberta, Canada, provides information on groundwater quality and geochemical changes over time, including data useful for evaluating potential impacts of industrial activity such as oil sands mining and in situ operations. Data collected from over 5000 wells from the 1950s to 2014, including 161 wells from government’s monitoring network, were used to develop and apply bootstrap techniques for the detection of changes in groundwater geochemistry over time and at specific points in time. Increasing temporal anomalies were identified in Cl, TDS, B, and naphthenic acids in the McMurray formation across 2003 and 2008, while decreasing anomalies were found for SO₄. Temporal variance for 15 indicators was quantified for a smooth bootstrap approach to arrive at stable values representative of the most recent samples taken from wells in the study area. Stable values revealed sampling bias in the Devonian, Grand Rapids, Empress, Channel Beverly, and Muriel Lake formations suggesting expansion of sampling may be necessary. Although temporal anomalies were found in the McMurray formation, sampling bias was not identified. The entropy and relative magnitude of time series were evaluated to identify candidate wells for continued observations, which consist of wells with low measurements and low entropy that are near active industry lease boundaries. Temporal anomalies, stable values, and entropy were combined into type-well information to provide plots for visual inspection and interpretation. Stable values are useful for regional mapping, for detecting future changes and trends, and for identifying areas of interest warranting further investigation.