Toxicity of polynuclear aromatic hydrocarbons to the polychaete Neanthes arenaceodentata

The toxicity of ten polynuclear aromatic hydrocarbons (PNAs) to Neanthes arenaceodentata was studied in replicate 96 h bioassays with specific hydrocarbons in solution. Relative solubilities for each PNA were derived in short-term equilibration experiments. Disappearance of representative di-, tri, tetra- and pentacyclic-aromatic hydrocarbons from test solutions was also characterized by ultraviolet spectrophotometry. PNA toxicity and residence time in test solutions were directly related to molecular weight (MW), while relative solubility is inversely related to MW. 96 h TL_m values for the diaromatic PNAs naphthalene, 2,6-dimethylnaphthalene, and 2,3,6-trimethylnaphthalene were 3.8, 2.6 and 2.0 ppm, respectively. Phenanthrene, fluorene and 1-methylphenanthrene (triaromatics) exhibited 96 h TL_m values of 0.6, 1.0 and 0.3 ppm, respectively. None of the tetra- and pentacyclic-aromatics (chrysene, 3,4-benzo(a)pyrene, 1,2,5,6-dibenzanthracene) were toxic up to the highest concentration tested (1 ppm), excepting fluoranthene, with a 96 h TL_m of 0.5 ppm. PNA toxicity appears to be related to both solubility and residence time in test solutions.     

Geochemical influences on H40/1 bacteriophage inactivation in glaciofluvial sands

Geochemical heterogeneities may cause spatial variations in virus inactivation rates resulting from interactions with minerals leading to differences in natural disinfection capacity within an aquifer. Column studies investigating the interaction of the bacteriophage H40/1 with natural sands sampled from the Kappelen test site (Kappelen), Bern, Switzerland indicated that inactivation rates are higher for adsorbed bacteriophages than for those suspended in groundwater. Moreover, breakthrough curves obtained from field-based tracer tests at Kappelen indicated that the adsorbed H40/1 is inactivated in-situ at comparable rates. Statistical analyses of mineralogical data failed to demonstrate significant spatial variations in aquifer composition either across the site or with depth. In contrast hydrochemical analyses of groundwater samples collected at Kappelen demonstrated that iron-reducing groundwater occurs below aerobic waters. Tracer breakthrough curves indicate that H40/1 survival is not affected by variable redox conditions. Investigation results suggest that spatial geochemical variability does not significantly affect H40/1s inactivation rate at Kappelen.     

Oxygen isotope analyses of fine silica grains using laser-extraction technique: Comparison with oxygen isotope data obtained from ion microprobe analyses and application to quartzite and silcrete cement investigation

The laser fluorination technique reported here for analyzing the oxygen isotope composition (δ¹⁸O) of fine quartz size fractions 50-20, 20-10, 10-5, 5-2, 2-1 and <1 μm has been validated by comparison with the ion microprobe technique. It yields accurate δ¹⁸O data with an external precision better than 0.15‰. This is a significant methodological improvement for isotopic studies dealing with materials such as soil or biogenic oxides and silicates: particles are often too small and recovered in insufficient amount to be easily handled for ion microprobe analysis. Both techniques were used to investigate δ¹⁸O composition of a Cretaceous quartzite and silcrete sequence from the South-East of France. Quartzite cements average 31.04 ± 1.93‰. They formed from Mid-Cretaceous seawater. Higher in the series, silcretes cements average 26.66 ± 1.36‰. They formed from Upper- or post-Upper-Cretaceous soil water and groundwater. Oxygen isotope data show that the silicification steps from one mineralogical phase to another and from one layer to another (including from an upper pedogenic silcrete to a lower groundwater silcrete) occurred in a closed or weakly evaporating hydrological system.     

Domains of spit evolution in the Goro area, Po Delta, Italy

Goro lagoon was formed during the 19th century in the southern part of the Po Delta. Its origin is related to the growth of a spit system, which progressively occluded the southernmost interdistributary bay from the sea. The development of the spits is due to the morphological prominence of the Po Delta which causes a divergent littoral drift, enhanced by wave refraction over the delta front. During the last century the spit was abandoned, destroyed, and re-constructed several times because of the development of newer spits seawards. Using historical maps and aerial photographs, three different periods are recognised, featuring distinctive spit growth styles: parallel, fan-shaped and branched. The different domains of spit evolution are related to several factors, mainly to the mutual influence of sediment discharge, sand mining along the Po river, wave action over the delta front, human-induced subsidence and direct human interventions along the spits and for flood-control.     

Ceilometer observations of aerosol layer structure above the Petit Lubéron during ESCOMPTE's IOP 2

A modified ceilometer has been used during the second Intensive Observation Period (IOP) of the “Expérience sur Site pour COntraindre les Modèles de Pollution atmosphériques et de Transport d'Émission” (ESCOMPTE) to perform continuous remote observations of aerosol accumulations in the first 3 km of the atmosphere. These observations encompassed an episode of intense particulate and photochemical pollution. The submicronic particles density, measured at an altitude of 600 m, went from a very low point of a few tens of particles per cubic centimeter (at the end of a Mistral episode in the free atmosphere) to a high point of more than 4500 particles per cubic centimeter (when pollutants were trapped by thermal inversions).The main result is that this instrument enables a fine documentation of the mixing layer height and of aerosol particles stratifications and circulation. Airborne aerosol measurements have been made above the mountainous region of Mérindol in order to validate in situ the remote sensing measurements. Ozone measurements near the summit of the mountains as well as in the valley were performed in order to correlate aerosol accumulation and ozone concentration. As a notable example, the two-layer aerosol stratification seen in the first 2 days of IOP 2b in that part of the ESCOMPTE domain confirms the results of another team which used backtrajectories. The low-altitude pollution for this timeframe had a local origin (the Fos industrial area), whereas above 500 m, the air masses had undergone regional-scale transport (from north-eastern Spain).The second major result is the highlighting of a pattern, in sea breeze conditions and in this part of the ESCOMPTE experiment zone, of nocturnal aerosol accumulation at an altitude of between 500 and 2000 m, followed by high ozone concentration the next day.     

GIS-ILA:THE GIS FOR ITALIAN LOGISTICS IN ANTARCTICA

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Resonant Fly-by Missions to Near Earth Asteroids

The authors here propose a mission scenario, aimed at close exploration of a Near-Earth Asteroid, exploiting low-V resonant trajectories. These trajectories allow repeated fly-bys of a chosen target. A selection procedure, which has been used to find some interesting mission opportunities in the 2005-2015 time frame, is described and the corresponding detailed mission profiles are derived, using an indirect optimization method.     

The rainfall intensity–duration control of shallow landslides and debris flows: an update

A global database of 2,626 rainfall events that have resulted in shallow landslides and debris flows was compiled through a thorough literature search. The rainfall and landslide information was used to update the dependency of the minimum level of rainfall duration and intensity likely to result in shallow landslides and debris flows established by Nel Caine in 1980. The rainfall intensity–duration (ID) values were plotted in logarithmic coordinates, and it was established that with increased rainfall duration, the minimum average intensity likely to trigger shallow slope failures decreases linearly, in the range of durations from 10 min to 35 days. The minimum ID for the possible initiation of shallow landslides and debris flows was determined. The threshold curve was obtained from the rainfall data using an objective statistical technique. To cope with differences in the intensity and duration of rainfall likely to result in shallow slope failures in different climatic regions, the rainfall information was normalized to the mean annual precipitation and the rainy-day normal. Climate information was obtained from the global climate dataset compiled by the Climate Research Unit of the East Anglia University. The obtained global ID thresholds are significantly lower than the threshold proposed by Caine (Geogr Ann A 62:23–27, 1980), and lower than other global thresholds proposed in the literature. The new global ID thresholds can be used in a worldwide operational landslide warning system based on global precipitation measurements where local and regional thresholds are not available..     

Tropical sea-surface temperatures during the last glacial period: a view based on alkenones in Indian Ocean sediments

The qualitification of tropical temperatures during the last glacial cycle (0-150 kyr BP) is a controversial issue since different proxies seem to provide conflicting informations. To obtain a complementary point of view, we use the alkenone method to estimate sea-surface temperatures and focus our work on deep-sea sediments recovered from the tropical Indian Ocean. We present alkenone data obtained in two cores which cover in detail the last deglaciation and in about twenty cores distributed between 20°S and 20°N that were chosen to evaluate the temperature contrast of the last glacial-interglacial transition. Our results indicate that Indian Ocean tropical temperatures remained an average within 1.5-2.5°C of their present values during the last glaciation. At 10°N the last deglaciation is characterized by two warming steps which is similar to the classical deglacial chronology observed in the North Atlantic area. At 20°S the deglacial warming occurred at ca. 15 cal kyr BP, lagging significantly (5-4 kyr) behind the Antarctic warming, but in phase with northern hemisphere time series.