I/I ratios in surface waters of the English Lake District

Accelerator Mass Spectrometry (AMS) was used to measure ¹²⁹I/¹²⁷I ratios in surface sea, lake, and river water samples collected in 2004 and 2005 from the English Lake District and from SW Scotland, areas which are in relatively close proximity to the Sellafield nuclear fuel reprocessing plant in NW England. The ¹²⁹I/¹²⁷I ratios in surface water collected from the shore of the Irish Sea were in the range 2.8 × 10⁻⁶ to 8.2 × 10⁻⁶. These ratios are one order of magnitude higher than that of seawater collected from the Irish Sea in 1992, correlating with the increase in ¹²⁹I content of the Sellafield liquid effluent discharge over the last decade. The ¹²⁹I/¹²⁷I ratios in lakes in the Lake District were in the range 0.7 × 10⁻⁶ to 6.4 × 10⁻⁶ and decreased exponentially as a function of distance from Sellafield. Consideration of the relative variation of stable I concentrations and ¹²⁹I/¹²⁷I ratios suggests that Sellafield gaseous discharges may be the dominant source of ¹²⁹I to the lakes.     

Odd zonal harmonics in the geopotential, from analysis of 28 satellite orbits

Summary. The geopotential is usually expressed as an infinite series of spherical harmonics, and the odd zonal harmonics are the terms independent of longitude and antisymmetric about the equator: they define the 'pear-shape' effect. The coefficients J ₃, J ₅, J ₇, … of these harmonics have been evaluated by analysing the variations in eccentricity of 28 satellite orbits from near-equatorial to polar. Most of the orbits from our previous determination in 1974 are used again, but three new orbits are added, including two at inclinations between 62° and 63°, which have been specially observed for more than five years by the Hewitt cameras. With the help of the new orbits and revised theory, we have obtained sets of J -coefficients with standard deviations about 40 per cent lower than before. A 9-coefficient set is chosen as representative, and is as follows (all × 10⁹): J ₃=– 2530 ± 4, J ₅=–245 ± 5, J ₇=–336 ± 6, J ₉=–90 ± 7, J ₁₁= 159 ± 9, J ₁₃=–158 ± 15, J ₁₅=– 20 ± 15, J ₁₇=– 236 ± 14, J ₁₉=– 27 ± 19. With this set of values, the pear-shape asymmetry of the geoid (north polar minus south polar radius) amounts to 45.1 m instead of the previous 44.7 m. The accuracy of the longitude-averaged geoid profile is estimated as 50 cm, except at latitudes above 86°. The geoid profile and predicted amplitude of the oscillation in eccentricity are compared with those from other sources.     

Trend-surface analysis of structure and thickness of Bulli Seam, Sydney Basin, New South Wales

Methods are presented which permit the analysis of structural and thickness variations of a stratigraphic interval into a number of components and testing of the components for relationship between structure and thickness. The methods are tested first in the axial region of the South Bulli Syncline area where the Bulli Seam is known to be thicker. Maps of the residual values from the structural and thickness first-degree trends are similar and there is a significant inverse relationship between the residuals. Data from the area where the Bulli Seam occurs also give seam structural and thickness residuals which have a significant inverse relationship. Local exceptions to this relationship are present but in most instances are due to laccolithic doming or changes in lithology of the Bulli Seam. A number of the trend components of structural and thickness variation also show an inverse relationship. It is postulated that most of the present structures defined at the Bulli Seam horizon were active during deposition of the Bulli Seam, and within the limit of the conditions suitable for peat accumulation, controlled thickness of the Bulli Seam. Thickness changes in overlying units suggest that a major part of the warping of the Bulli Seam horizon had occurred by the end of the Triassic Period.     

High-resolution Imaging of the Upper Solar Chromosphere: First Light Performance of the Very-high-Resolution Advanced ULtraviolet Telescope

The Very-high-resolution Advanced ULtraviolet Telescope (VAULT) experiment was successfully launched on 7 May 1999 on a Black Brant sounding rocket vehicle from White Sands Missile Range. The instrument consists of a 30 cm UV diffraction limited telescope followed by a two-grating, zero-dispersion spectroheliograph tuned to isolate the solar L emission line. During the flight, the instrument successfully obtained a series of images of the upper chromosphere with a limiting resolution of 0.33 arc sec. The resulting observations are the highest-resolution images of the solar atmosphere obtained from space to date. The flight demonstrated that sub-arc second ultraviolet images of the solar atmosphere are achievable with a high-quality, moderate-aperture space telescope and associated optics. Herein, we describe the payload and its in-flight performance.     

Export of Acidity in Drainage Water from Acid Sulphate Soils

Disturbed acid sulphate soils are potent sources of acidity in coastal waterways. Monitoring studies of the drainage water for sites at East Trinity, Cairns and Pimpama, south-east Queensland indicate that considerable acidity is found in the drainage water from these sites. Hydrogen (H⁺), ferrous (Fe²⁺) and aluminium (Al) ions are the dominant acid cations involved. When drainage water is mixed with fresh or marine waters the effect of H⁺ on acidity generation is immediate. Aluminium can release acidity on hydrolysis, while the oxidation of Fe²⁺ to Fe³⁺ both acidifies and removes dissolved oxygen from the water. Strongly acidic waters with low levels of dissolved oxygen concentration are undesirable for most forms of aquatic life. Export of acidity from acid sulphate soil is likely to have a major effect on inshore fisheries and breeding grounds especially in periods of flood following drought or periods of low rainfall, where large volumes of acidity can be flushed/leached into sensitive aquatic/marine habitats. Impacts may include low dissolved oxygen, fish kills, epizootic ulceration syndrome and damage to oysters. During the processes of oxidation and hydrolysis, iron and aluminium flocs form, that can smother benthic communities. Heavy metals are found in the drainage water at elevated levels and may also be of concern for aquatic organisms. Chronic effects such as habitat degradation, mortality of marine worms, bivalves, invasion of acid tolerant species (both plant and animal) and avoidance of habitat have been documented elsewhere. These areas require further research.