Pleistocene sediments,soils and landscape evolution at Stebbing,Essex

Pleistocene sediments and soils exposed at Stebbing in central Essex, England are described, analysed and interpreted. The sand and gravel units above Eocene London Clay and Upper Pliocene Red Crag are shown to be a high level member of the Kesgrave Formation, with a surface immediately beneath that of the Westland Green Gravels, which are tentatively assigned to the Pre-Pastonian ‘a’ Stage of the British Quaternary succession. The rubified, argillic soil developed in the surface of these fluvial deposits is a composite of the Valley Farm and Barham Soils and displays micromorphological evidence of several phases of clay illuviation, gleying and clay coating disruption. Originally truncated and buried beneath Anglian gelifluction deposits, cover sand and till, the soil has been exhumed in most places by subsequent erosion. The full succession, however, is preserved within large gulls that formed by periglacial cambering prior to this erosion. More recent loess incorporation and pedogenesis have modified the exhumed soil and the materials within the gulls.     

The Loch Lomond Readvance on north Arran,Scotland: glacier reconstruction and palaeoclimatic implications

Geomorphological mapping of northern Arran provides evidence for two advances of locally nourished glaciers, the younger being attributable to the Loch Lomond Stade (LLS) of ca. 12.9–11.5 k yr BP, primarily through the mutually exclusive relationship between glacial limits and Lateglacial periglacial features. The age of the earlier advance is unknown. Inferred LLS glacier cover comprised two small icefields and eight small corrie or valley glaciers and totalled 11.1 km². ELAs reconstructed using area–altitude balance ratio methods range from 268 m to 631 m for individual glaciers, with an area‐weighted mean ELA of 371 m. ELAs of individual glaciers are strongly related to snow‐contributing areas. The area‐weighted mean ELA is consistent with a north–south decline in LLS ELAs along the west coast of Great Britain. This decline has an average latitudinal gradient of 70 m 100 km^?1, equivalent to a mean southwards ablation‐season temperature increase of ca. 0.42°C 100 km^?1. Mean June–August temperatures at the regional climatic ELA, estimated from chironomid assemblages in SE Scotland, lay between 5.7 ± 0.1°C and 4.1 ± 0.2°C. Empirical relationships between temperature and precipitation at modern glacier ELAs indicate equivalent mean annual precipitation at the ELA lay between 2002 ± 490 mm and 2615 ± 449 mm. These figures suggest that stadial precipitation on Arran fell within a range between +8% and ?33% of present mean annual precipitation. Copyright © 2006 John Wiley & Sons, Ltd.     

Displaced non-Keplerian orbits using impulsive thrust

This paper investigates new families of displaced, highly non-Keplerian orbits in the two-body problem and artificial equilibria in the circular restricted three-body problem. The families of orbits presented extend prior work by using periodic impulses to generate displaced orbits rather than continuous thrust. The new displaced orbits comprise a sequence of individual Keplerian arcs whose intersection is continuous in position, with discontinuities in velocity removed using impulses. For frequent impulses the new families of orbits approximate continuous thrust non-Keplerian orbits found in previous studies. To generate approximations to artificial equilibria in the circular restricted three-body problem, periodic impulses are used to generate a sequence of connected three-body arcs which begin and terminate at a fixed position in the rotating frame of reference. Again, these families of orbits reduce to the families of artificial equilibria found using continuous thrust.     

The lithology of Ogallala gravels and hunter‐gatherer procurement strategies along the Southern High Plains eastern escarpment of Texas,USA

Ogallala gravels are an important lithic material source for stone tool manufacture across the Great Plains. The lithology of eight gravel sample locations along the eastern escarpment of the Southern High Plains has been examined to quantify the composition and variability in Ogallala deposits. In addition, three Ogallala gravel quarry sites have been analyzed to determine how the lithology of Ogallala gravels influenced procurement and tool production strategies. Results indicate deposits of Ogallala gravels differ in their composition related to their position on the landscape, and the types of rocks vary by size and shape. Investigation of the quarry sites has revealed that the lithology of Ogallala gravels had an impact on testing and the initial stages of lithic reduction. Different rock types, however, may have more of an influence on later stages of tool manufacture at nearby campsites and other locations where Ogallala gravels are not as dense. © 2009 Wiley Periodicals, Inc.     

An experimental study of phase equilibria in the systems H2O–CO2–CaCl2 and H2O–CO2–NaCl at high pressures and temperatures (500–800?°C, 0.5–0.9?GPa): geological and geophysical applications

Phase equilibria in the ternary systems H₂O–CO₂–NaCl and H₂O–CO₂–CaCl₂ have been determined from the study of synthetic fluid inclusions in quartz at 500 and 800 °C, 0.5 and 0.9 GPa. The crystallographic control on rates of quartz overgrowth on synthetic quartz crystals was exploited to prevent trapping of fluid inclusions prior to attainment of run conditions. Two types of fluid inclusion were found with different density or CO₂ homogenisation temperature (T_h(CO₂)): a CO₂-rich phase with low T_h(CO₂), and a brine with relatively high T_h(CO₂). The density of CO₂ was calibrated using inclusions in the binary system H₂O–CO₂. Mass balance calculations constrain tie lines and the miscibility gap between brines and CO₂-rich fluids in the H₂O–CO₂–NaCl and H₂O–CO₂–CaCl₂ systems at 500 and 800 °C, and 0.5 and 0.9 GPa. The miscibility gap in the CaCl₂ system is larger than in the NaCl system, and solubilities of CO₂ are smaller. CaCl₂ demonstrates a larger salting-out effect than NaCl at the same P–T conditions. In ternary systems, homogeneous fluids are H₂O-rich and of extremely low salinity, but at medium to high concentrations of salts and non-polar gases fluids are unlikely to be homogeneous. The two-phase state of crustal fluids should be common. For low fluid-rock ratios the cation compositions of crustal fluids are buffered by major crustal minerals: feldspars and micas in pelites and granitic rocks, calcite (dolomite) in carbonates, and pyroxenes and amphiboles in metabasites. Fluids in pelitic and granitic rocks are Na-K rich, while for carbonate and metabasic rocks fluids are Ca-Mg-Fe rich. On lithological boundaries between silicate and carbonate rocks, or between pelites and metabasites, diffusive cation exchange of the salt components of the fluid will cause the surfaces of immiscibility to intersect, leading to unmixing in the fluid phase. Dispersion of acoustic energy at critical conditions of the fluid may amplify seismic reflections that result from different fluid densities on lithological boundaries.Editorial responsibility: I. Parsons     

Hydrocarbons generated by hydropyrolysis of suspended marine particulate organic matter: Relationship to the oceanography of the Black Sea and the Rhodes Gyre

The suspended particulate organic matter, SPOM, in the autumnal Black Sea has been characterised using catalytic hydropyrolysis (HyPy) of the total (bound plus free) lipid material. The technique, which generates maximum yields of volatile products from sediments, kerogens and phytoplankton, was followed using gas chromatography and gas chromatography/mass spectrometry. The generated alkanes were dominated by n-C₁₈, hypothesised to arise predominantly from unsaturated C₁₈ fatty acids. Steranes were generated from reductive conversion of free and bound sterols. The generation of branched alkanes and especially of hopanes provided formal evidence for the participation of bacteria in the mineralisation of the SPOM. Whereas similar distributions of n-alkanes were generated from SPOM sampled from different depths of the comparatively well-stirred Rhodes Gyre (eastern Mediterranean), mineralisation of the SPOM at each depth of the central Black Sea produced characteristic changes in the composition and concentration of the HyPy products. Depth profiles of the n-alkanes generated from SPOM in the region of the Rim Current were affected by the local hydrography. Polynuclear aromatic hydrocarbons (PAHs) of anthropogenic origin were present in the surface waters of the central Black Sea. Some methyl benzenes, thiophenes and pyrroles were also generated.     

Compositional Zoning of the Bishop Tuff

Compositional data for >400 pumice clasts, organized accordingto eruptive sequence, crystal content, and texture, providenew perspectives on eruption and pre-eruptive evolution of the>600 km³ of zoned rhyolitic magma ejected as the Bishop Tuffduring formation of Long Valley caldera. Proportions and compositionsof different pumice types are given for each ignimbrite packageand for the intercalated plinian pumice-fall layers that eruptedsynchronously. Although withdrawal of the zoned magma was lesssystematic than previously realized, the overall sequence displaystrends toward greater proportions of less evolved pumice, morecrystals (0·5–24 wt %), and higher FeTi-oxide temperatures(714–818°C). No significant hiatus took place duringthe 6 day eruption of the Bishop Tuff, nearly all of which issuedfrom an integrated, zoned, unitary reservoir. Shortly beforeeruption, however, the zoned melt-dominant portion of the chamberwas invaded by batches of disparate lower-silica rhyolite magma,poorer in crystals than most of the resident magma but slightlyhotter and richer in Ba, Sr, and Ti. Interaction with residentmagma at the deepest levels tapped promoted growth of Ti-richrims on quartz, Ba-rich rims on sanidine, and entrapment ofnear-rim melt inclusions relatively enriched in Ba and CO₂.Varied amounts of mingling, even in higher parts of the chamber,led to the dark gray and swirly crystal-poor pumices sparselypresent in all ash-flow packages. As shown by FeTi-oxide geothermometry,the zoned rhyolitic chamber was hottest where crystal-richest,rendering any model of solidification fronts at the walls orroof unlikely. The main compositional gradient (75–195ppm Rb; 0·8–2·2 ppm Ta; 71–154 ppmZr; 0·40–1·73% FeO*) existed in the melt,prior to crystallization of the phenocryst suite observed, whichincluded zircon as much as 100 kyr older than the eruption.The compositions of crystals, though themselves largely unzoned,generally reflect magma temperature and the bulk compositionalgradient, implying both that few crystals settled or were transportedfar and that the observed crystals contributed little to establishingthat gradient. Upward increases in aqueous gas and dissolvedwater, combined with the adiabatic gradient (for the 5 km depthrange tapped) and the roofward decline in liquidus temperatureof the zoned melt, prevented significant crystallization againstthe roof, consistent with dominance of crystal-poor magma earlyin the eruption and lack of any roof-rind fragments among theBishop ejecta, before or after onset of caldera collapse. Amodel of secular incremental zoning is advanced wherein numerousbatches of crystal-poor melt were released from a mush zone(many kilometers thick) that floored the accumulating rhyoliticmelt-rich body. Each batch rose to its own appropriate levelin the melt-buoyancy gradient, which was self-sustaining againstwholesale convective re-homogenization, while the thick mushzone below buffered it against disruption by the deeper (non-rhyolitic)recharge that augmented the mush zone and thermally sustainedthe whole magma chamber. Crystal–melt fractionation wasthe dominant zoning process, but it took place not principallyin the shallow melt-rich body but mostly in the pluton-scalemush zone before and during batchwise melt extraction. KEY WORDS: Bishop Tuff; ignimbrite; magma zonation; mush model; rhyolite     

Fiji’s fisheries: their contribution to development and their future

The industrial fisheries of Fiji have had mixed fortunes. The fresh fish export industry has grown rapidly in importance so that fisheries is now the third most valuable export industry; its positive effect on the economy is mainly in the increase in the purchase of goods and services, such as air freight. The present ‘hands off’ policy by government in the fresh fish export industry should continue until the industry matures. In the longer run, ad valorem royalties should be considered as a mean of capturing resource rents. The government-owned export cannery has been in financial decline, and the maintenance of the social benefits of regional employment generated by the cannery has come at a high cost to government coffers. The future of the cannery, now leased to a private operator, is clouded by the uncertainty of the continuity of concessional access to European markets beyond the year 2000. The main task faced by government is the management of fisheries and fish stocks. The management of the inshore fisheries — vital to the needs of a large proportion of the population — needs additional resources. The capability for management of the industrial fisheries, necessary to maximise long term public benefits, would be enhanced by full cost recovery through a user pays policy. This article is based on a paper presented to the Fiji Update seminar, held at the National Centre for Development Studies, the Australian National University, Canberra, on 19 June 1998. The author wishes to thank Mr Krishna Swamy, Senior Fisheries Officer in the Fiji Fisheries Division, and Mr Grahame Southwick, Managing Director of the Fiji Fish Company Ltd, for their generous provision of information for the preparation of this paper; and Mr Joeli Veitayaki, Coordinator of the Ocean Resources Management Programme, University of the South Pacific, for helpful comments. Any errors or omissions are the author’s responsibility, however.     

Observations of the evolution of the aerosol, cloud and boundary‐layer characteristics during the 1st ACE‐2 Lagrangian experiment

During the 1st Lagrangian experiment of the North Atlantic Regional Aerosol Characterisation Experiment (ACE‐2), a parcel of air was tagged by releasing a smart, constant level balloon into it from the Research Vessel Vodyanitskiy . The Meteorological Research Flight's C‐130 aircraft then followed this parcel over a period of 30 h characterising the marine boundary layer (MBL), the cloud and the physical and chemical aerosol evolution. The air mass had originated over the northern North Atlantic and thus was clean and had low aerosol concentrations. At the beginning of the experiment the MBL was over 1500 m deep and made up of a surface mixed layer (SML) underlying a layer containing cloud beneath a subsidence inversion. Subsidence in the free troposphere caused the depth of the MBL to almost halve during the experiment and, after 26 h, the MBL became well mixed throughout its whole depth. Salt particle mass in the MBL increased as the surface wind speed increased from 8 m s⁻¹ to 16 m s⁻¹ and the accumulation mode (0.1μm to 3.0 μm) aerosol concentrations quadrupled from 50 cm⁻³ to 200 cm⁻³. However, at the same time the total condensation nuclei (>3 nm) decreased from over 1000 cm⁻³ to 750 cm⁻³. The changes in the accumulation mode aerosol concentrations had a significant effect on the observed cloud microphysics. Observational evidence suggests that the important processes in controlling the Aitken mode concentration which, dominated the total CN concentration, included, scavenging of interstitial aerosol by cloud droplets, enhanced coagulation of Aitken mode aerosol and accumulation mode aerosol due to the increased sea salt aerosol surface area, and dilution of the MBL by free tropospheric air.