Probing the magma plumbing of Erebus volcano,Antarctica, by open-path FTIR spectroscopy of gas emissions

Gas emissions from Erebus volcano, Antarctica, were measured by open-path Fourier transform infrared spectroscopy to understand degassing of its magmatic system. Two degassing phonolite lava lakes were present in the summit crater during observation in December 2004. We report analyses of H₂O, CO₂, CO, SO₂, HF, HCl and OCS, (in order of molar abundance) in the plumes. Variations in the proportions of these species strongly reflect the dynamics of degassing, and sourcing of gas from different depths in the magmatic network. The highest observed ratios of CO₂ and H₂O are consistent with gas extracted from the melt at a depth of up to ∼ 2 km below the lava lakes. Magma degassing above this depth contributes to a higher H₂O/CO₂ proportion in the airborne plume. The ratio therefore reflects the balance of deeper vs. shallower contributions of volatiles and, possibly, a combination of closed- and open-system degassing. We observe a strong contrast in HF content in emissions from the two lava lakes, which we attribute to differing levels of magma ascent and/or cooling and crystallization of the magma supply. Fluxes of all gas species were determined using independent SO₂ flux determinations and measured gas ratios. In the case of CO₂ and water, ∼ 1 and ∼ 0.4 m³ s^− 1, respectively, of parental basanite magma are required to sustain the calculated output. The discrepancy between the two figures is readily explained by sequestration of part of the magma supply at depth such that it only partially degasses its complement of water.     

Attenuation of P- and S-waves in limestones

Ultrasonic compressional- and shear-wave attenuation measurements have been made on 40, centimetre-sized samples of water- and oil-saturated oolitic limestones at 50 MPa effective hydrostatic pressure (confining pressure minus pore-fluid pressure) at frequencies of about 0.85 MHz and 0.7 MHz respectively, using the pulse-echo method. The mineralogy, porosity, permeability and the distribution of the pore types of each sample were determined using a combination of optical and scanning electron microscopy, a helium porosimeter and a nitrogen permeameter. The limestones contain a complex porosity system consisting of interparticle macropores (dimensions up to 300 microns) and micropores (dimensions 5–10 microns) within the ooids, the calcite cement and the mud matrix. Ultrasonic attenuation reaches a maximum value in those limestones in which the dual porosity system is most fully developed, indicating that the squirt-flow mechanism, which has previously been shown to occur in shaley sandstones, also operates in the limestones. It is argued that the larger-scale dual porosity systems present in limestones in situ could similarly cause seismic attenuation at the frequencies of field seismic surveys through the operation of the squirt-flow mechanism.     

Environmental Stewardship in UK agriculture: A comparison of the environmentally sensitive area programme and the Countryside Stewardship Scheme in South East England

Research into the adoption of Environmental Land Management Schemes (ELMS) has typically sought to identify the defining characteristics of participants and the ‘barriers to entry’ that dissuade others from joining. More recently, attention has focused on the motivation of participants and non-participants in helping to understand patterns of participation. This paper compares the pattern of participation in two distinct schemes operating in South East England. Indirect evidence suggests that scheme design and implementation is influencing the type of farmer joining and their motivation for doing so. Results from a survey of farmers also support the idea that the schemes are recruiting from different sections of the farming community. ESA farmers are largely motivated by financial gain, whereas those enrolling land in the Countryside Stewardship Scheme have more clearly defined conservation motives. Although there is also a ‘core’ of resistant non-participants, further changes to the design and delivery of policy could encourage a large number of ‘potential enrolers’ to join.     

Infrared and Raman spectra of lunar samples from Apollo 11, 12 and 14

We report the room temperature infrared reflectance spectra of several lunar surface rocks in the form of polished slices or butt ends. The spectra were obtained over the frequency range 20-2000 cm^–1 throughout the mid and far infrared (5-500µ) region of the electromagnetic spectrum where the fundamental internal and lattice vibrational modes of all minerals and rocks occur.Some fines samples were examined as pressed pellets and their reflectivities compared with the bulk samples. Several terrestrial minerals and rocks were also investigated. Kramers-Kronig analyses of these reflectance spectra were undertaken and the dispersion of the dielectric response ( and ) and the optical constants (n andk) have been determined over this frequency range. The low frequency and high frequency (infrared) dielectric constants were also calculated from the reflectance data.Raman light scattering measurements were made on all the samples supplied from the first three Apollo missions. Large background scattering proved to be the greatest experimental problem. Successful spectra in nearly all cases were obtained from small crystalline inclusions imbedded in the main ground mass. Some crystalline bulk rocks containing many very fine inclusions gave identifiable spectra and at least three different types were obtained.Supported by NASA Grant NGR 22-011-069 and by a Northeastern University Grant for Basic Research.     

Buoy measured wind, wind stress and wind stress curl over the shelf off Bodega Bay, California

An array of five buoys and three coastal stations is used to characterize the winds, stress, and curl of the wind stress over the shelf off Bodega Bay, California. The wind and wind stress are strong and persistent in the summer and weak in the winter. In the summer, wind and stress decrease strongly across the shelf, toward the coast. Combinations of buoys are used to compute the curl of the wind stress over different portions of the shelf. The mean summer 2001 curl of the wind stress over the array depends upon the area selected, varying between −1.32×10⁻⁶ and +7.80×10⁻⁶ Pa m⁻¹. The winter 2002 wind-stress curl also depends on location, varying from −2.06×10⁻⁶ to +2.78×10⁻⁶ Pa m⁻¹. Mean monthly curl of the wind stress is a maximum in the summer and a minimum near zero in the winter. In both the summer and the winter, the correlation between the wind-stress curl for different portions of the shelf varies between moderate negative, though insignificance, to high positive. A wind measurement at a single point can be poorly related to the measured curl of the wind stress at other locations over the shelf. The measurements show that the use of one wind measurement to characterize the curl of the wind stress over the shelf without further investigation of the local wind-stress curl structure is risky.     

The Eldgjá eruption: timing,long-range impacts and influence on the Christianisation of Iceland

The Eldgjá lava flood is considered Iceland’s largest volcanic eruption of the Common Era. While it is well established that it occurred after the Settlement of Iceland (circa 874 CE), the date of this great event has remained uncertain. This has hampered investigation of the eruption’s impacts, if any, on climate and society. Here, we use high-temporal resolution glaciochemical records from Greenland to show that the eruption began in spring 939 CE and continued, at least episodically, until at least autumn 940 CE. Contemporary chronicles identify the spread of a remarkable haze in 939 CE, and tree ring-based reconstructions reveal pronounced northern hemisphere summer cooling in 940 CE, consistent with the eruption’s high yield of sulphur to the atmosphere. Consecutive severe winters and privations may also be associated with climatic effects of the volcanic aerosol veil. Iceland’s formal conversion to Christianity dates to 999/1000 CE, within two generations or so of the Eldgjá eruption. The end of the pagan pantheon is foretold in Iceland’s renowned medieval poem, V?luspá (‘the prophecy of the seeress’). Several lines of the poem describe dramatic eruptive activity and attendant meteorological effects in an allusion to the fiery terminus of the pagan gods. We suggest that they draw on first-hand experiences of the Eldgjá eruption and that this retrospection of harrowing volcanic events in the poem was intentional, with the purpose of stimulating Iceland’s Christianisation over the latter half of the tenth century.     

High‐frequency precipitation and stream water quality time series from Plynlimon,Wales: an openly accessible data resource spanning the periodic table

This scientific briefing announces the availability of a new multi‐element high‐frequency water quality data set that is openly accessible to the research community. The data set comprises up to 2 years of 7‐hourly water quality data for two streams and one rainfall site in the Upper Severn catchment at Plynlimon in Mid‐Wales. The measurements cover 50 analytes ranging from H⁺ to U and spanning six orders of magnitude in concentration, including major, minor and trace elements as well as nutrients, and they complement decades of weekly measurements of the same analytes at the Upper Severn. Together, the weekly and 7‐hourly time series provide a unique data set for studying both long‐term trends and short‐term dynamics. The data show complex behaviour over a wide range of timescales, challenging our understanding of catchment processes and informing future modelling efforts. Copyright © 2013 John Wiley & Sons, Ltd.