Ageing of Dissolved Halogenated Humic Substances and the Microbiological Influence on this Process

The distribution of halogens in various fractions of humic substances (HS), separated by their molecular weight, was found to be different for the different halogens. This was demonstrated for chlorine, bromine, and iodine in sewage and brown water samples by applying inductively coupled plasma mass spectrometry coupled with size‐exclusion chromatography. Quantification of the different fractions of iodinated humic substances was obtained by quadrupole mass spectrometry in connection with the isotope dilution technique using an ¹²⁹I‐enriched spike solution. Quantitative analysis was not possible for the corresponding chlorine and bromine species because of spectrometric interferences in the quadrupole instrument. The ageing of HS/halogen species was followed with respect to possible transformations of these species in a ground and sewage water sample up to eight weeks. Even if a distinct structural variation of the humic substance was observed with time by measuring the UV absorption, chlorine remained in the same molecular weight fraction and only a small change was found for the HS/bromine species after eight weeks. In contrast to these findings a substantial transformation of HS/iodine compounds took place, which demonstrated that the transfer probability of halogens from one to another HS fraction is increased with decreasing strength of the halogen bond to carbon. By comparing the results of an original sewage water sample with a filtered one and with another one which was enriched by microorganisms cultivated from the same original sample, a strong microbiological influence on the transformation of HS/iodine species was found. A quantitative balance of the corresponding HS/iodine fractions was calculated for an ageing period of eight weeks showing that iodine was preferably transferred to newly formed UV active HS substances of high molecular weight. In total, no iodine was released from the humic substances.     

Coordinated Ocean-ice Reference Experiments (COREs)

Coordinated Ocean-ice Reference Experiments (COREs) are presented as a tool to explore the behaviour of global ocean-ice models under forcing from a common atmospheric dataset. We highlight issues arising when designing coupled global ocean and sea ice experiments, such as difficulties formulating a consistent forcing methodology and experimental protocol. Particular focus is given to the hydrological forcing, the details of which are key to realizing simulations with stable meridional overturning circulations.The atmospheric forcing from [Large, W., Yeager, S., 2004. Diurnal to decadal global forcing for ocean and sea-ice models: the data sets and flux climatologies. NCAR Technical Note: NCAR/TN-460+STR. CGD Division of the National Center for Atmospheric Research] was developed for coupled-ocean and sea ice models. We found it to be suitable for our purposes, even though its evaluation originally focussed more on the ocean than on the sea-ice. Simulations with this atmospheric forcing are presented from seven global ocean-ice models using the CORE-I design (repeating annual cycle of atmospheric forcing for 500 years). These simulations test the hypothesis that global ocean-ice models run under the same atmospheric state produce qualitatively similar simulations. The validity of this hypothesis is shown to depend on the chosen diagnostic. The CORE simulations provide feedback to the fidelity of the atmospheric forcing and model configuration, with identification of biases promoting avenues for forcing dataset and/or model development.     

“Galileo Galilei” (GG) a small satellite to test the equivalence principle of Galileo, Newton and Einstein

“Galileo Galilei” (GG) is a small satellite designed to fly in low Earth orbit with the goal of testing the Equivalence Principle—which is at the basis of the General Theory of Relativity—to 1 part in 10¹⁷. If successful, it would improve current laboratory results by 4 orders of magnitude. A confirmation would strongly constrain theories; proof of violation is believed to lead to a scientific revolution. The experiment design allows it to be carried out at ambient temperature inside a small 1-axis stabilized satellite (250 kg total mass). GG is under investigation at Phase A-2 level by ASI (Agenzia Spaziale Italiana) at Thales Alenia Space in Torino, while a laboratory prototype (known as GGG) is operational at INFN laboratories in Pisa, supported by INFN (Istituto Nazionale di fisica Nucleare) and ASI. A final study report will be published in 2009.     

Advancing fundamental physics with the Laser Astrometric Test of Relativity

The Laser Astrometric Test of Relativity (LATOR) is an experiment designed to test the metric nature of gravitation—a fundamental postulate of the Einstein’s general theory of relativity. The key element of LATOR is a geometric redundancy provided by the long-baseline optical interferometry and interplanetary laser ranging. By using a combination of independent time-series of gravitational deflection of light in the immediate proximity to the Sun, along with measurements of the Shapiro time delay on interplanetary scales (to a precision respectively better than 0.1 picoradians and 1 cm), LATOR will significantly improve our knowledge of relativistic gravity and cosmology. The primary mission objective is i) to measure the key post-Newtonian Eddington parameter γ with accuracy of a part in 10⁹. $\frac{1}{2}(1-\gamma)$ is a direct measure for presence of a new interaction in gravitational theory, and, in its search, LATOR goes a factor 30,000 beyond the present best result, Cassini’s 2003 test. Other mission objectives include: ii) first measurement of gravity’s non-linear effects on light to ～0.01% accuracy; including both the traditional Eddington β parameter and also the spatial metric’s 2nd order potential contribution (never measured before); iii) direct measurement of the solar quadrupole moment J ₂ (currently unavailable) to accuracy of a part in 200 of its expected size of ??10^???7; iv) direct measurement of the “frame-dragging” effect on light due to the Sun’s rotational gravitomagnetic field, to 0.1% accuracy. LATOR’s primary measurement pushes to unprecedented accuracy the search for cosmologically relevant scalar-tensor theories of gravity by looking for a remnant scalar field in today’s solar system. We discuss the science objectives of the mission, its technology, mission and optical designs, as well as expected performance of this experiment. LATOR will lead to very robust advances in the tests of fundamental physics: this mission could discover a violation or extension of general relativity and/or reveal the presence of an additional long range interaction in the physical law. There are no analogs to LATOR; it is unique and is a natural culmination of solar system gravity experiments.     

The impact of hydrological conditions on salinisation and nitrate concentration in the coastal Velez River aquifer (southern Spain)

This study reports the impact of hydrological conditions on salinisation and nitrate concentrations of a coastal aquifer located at the Mediterranean Sea, southern Spain. Eighty-two samples of ground- and surface water taken during two extreme hydrological events between 1994 and 1996 at 25 different wells were evaluated with regard to hydrochemistry, focusing on nitrate concentrations and salinisation, which constitute the main hazard of this aquifer. Furthermore, hydrochemical data were analysed by principal component analysis (PCA). Additionally, in 2007 13 ground- and surface water samples taken at 12 different locations were analysed for stable isotopes of D/¹⁸O, and one sample was analysed for ¹⁵N. Since 1993 until present saltwater intrusion was observed only during dry hydrological conditions in 1994; it showed an irregular salinisation pattern probably related to locally elevated hydraulic conductivities. Nitrate concentrations increase significantly during wet hydrologic conditions owing to uptake of nitrate by rising groundwater. Stable isotopes of groundwater reveal an Atlantic origin of the precipitation that recharges the aquifer and a minor amount of groundwater recharge by the water coming from the La Viñuela reservoir, which is used for irrigation over the aquifer. ¹⁵N isotopes point to a considerable input of nitrates derived from organic fertilisers.     

Internal and forced variability along a section between Greenland and Portugal in the CLIPPER Atlantic model

Numerical models are used to estimate the meridional overturning and transports along the paths of two hydrographic cruises, carried out in 1997 and 2002 from Greenland to Portugal. We have examined the influence of the different paths of the two cruises and found that it could explain 0.4 to 2 Sv of difference in overturning (the precise value is model-dependent). Models show a decrease in the overturning circulation between 1997 and 2002, with different amplitudes. The CLIPPER ATL6 model reproduces well the observed weakening of the overturning in density coordinates between the cruises; in the model, the change is due to the combination of interannual and high-frequency forcing and internal variability associated with eddies and meanders. Examination of the -coordinate overturning reveals model–data discrepancies: the vertical structure in the models does not change as much as the observed one. The East Greenland current variability is mainly wind-forced in the ATL6 model, while fluctuations due to eddies and instabilities explain a large part of the North Atlantic Current variability. The time-residual transport of dense water and heat due to eddy correlations between currents and properties is small across this section, which is normal to the direction of the main current.     

南极中山站至Dome A剖面表面雪样氧同位素组成

运用质谱技术 ,测定了南极中山站至 Dome A剖面 1 998/1 999年度表面雪样氧同位素组成。结果表明 ,表面雪样氧同位素组成变化范围相当大 (- 2 2 .5 1‰ - - 5 0 .6 7‰ ) ,且具有随距中山站距离逐渐增大、海拔高度逐渐增加而逐渐减小的趋势。线性回归分析显示表面雪样氧同位素组成与距中山站距离、海拔高度和纬度存在着很好的相关性 ,这实际上反映出稳定同位素组成和温度之间的密切联系     

A high-resolution stellar library for evolutionary population synthesis

We present a library of 1654 high-resolution stellar spectra, with a sampling of 0.3 Å and covering the wavelength range from 3000 to 7000 Å. The library was computed with the latest improvements in stellar atmospheres, incorporating non-local thermodynamic equilibrium (non-LTE) line-blanketed models for hot, massive  ( T _eff≥ 27 500 K)  and line-blanketed models for cool  (3000 ≤ T _eff≤ 4500 K)  stars. The total coverage of the grid is  3000 K ≤ T _eff≤ 55 000 K  and  −0.5 ≤ log g ≤ 5.5  , for four chemical abundance values: twice solar, solar, half solar and 1/10 solar. Evolutionary synthesis models using this library are presented in a companion paper. We tested the general behaviour of the library by calculating and comparing equivalent widths of numerous H and He  i lines, and some of the commonly used metallic indices. We also compared the library with the empirical libraries STELIB and Indo-US. The full set of the synthetic stellar spectra is available from our websites ( http://www.iaa.csic.es/~rosa and http://www.astro.iag.usp.br/~lucimara/library.htm ).     

The emergence of equatorial deep jets in an idealised primitive equation model: an interpretation in terms of basin modes

Ocean circulation models do not generally exhibit equatorial deep jets (EDJs), even though EDJs are a recognised feature of the observed ocean circulation along the equator and they are thought to be important for tracer transport along the equator and even equatorial climate. EDJs are nevertheless found in nonlinear primitive equation models with idealised box geometry. Here we analyse several such model runs. We note that the variability of the zonal velocity in the model is dominated by the gravest linear equatorial basin mode for a wide range of baroclinic vertical normal modes and that the EDJs in the model are dominated by energy contained in vertical modes between 10 and 20. The emergence of the EDJs is shown to involve the linear superposition of several such neighbouring basin modes. Furthermore, the phase of these basin modes is set at the start of the model run and, in the case of the reference experiment, the same basin modes can be found in a companion experiment in which the amplitude of the forcing has been reduced by a factor of 1000. We also argue that following the spin-up, energy must be transferred between different vertical modes. This is because the model simulations are dominated by downward phase propagation following the spin-up whereas our reconstructions imply episodes of upward and downward propagation. The transfer of energy between the vertical modes is associated with a decadal modulation of the EDJs.