A New Ionosphere Monitoring Technology Based on GPS

Although global positioning system (GPS) was originally planned as a satellite-based radio-navigation system for military purposes, civilian users have significantly increased their access to the system for both, commercial and scientific applications. Almost 400 permanent GPS tracking stations have been stablished around the globe with the main purpose of supporting scientific research. In addition, several GPS receivers on board of low Earth orbit satellites fitted with special antennas that focus on Earth's horizon, are tracking the radio signals broadcasted by the high-orbiting GPS satellites, as they rise and set on Earth horizon. The data of these ground and space-born GPS receivers, readily accessible through Internet in a ‘virtual observatory’ managed by the International GPS Service, are extensively used for many researches and might possibly ignite a revolution in Earth remote sensing. By measuring the changes in the time it takes for the GPS signals to arrive at the receiver as they travel through Earth's atmosphere, scientists can derive a surprising amount of information about the Earth's ionosphere, a turbulent shroud of charged particles that, when stimulated by solar flares, can disrupt communications around the world. This contribution presents a methodology to obtain high temporal resolution images of the ionospheric electron content that lead to two-dimensional vertical total electron content maps and three-dimensional electron density distribution. Some exemplifying results are shown at the end of the paper.     

Global nature of the Paleoproterozoic Lomagundi carbon isotope excursion: A review of occurrences in Brazil,India, and Uruguay

Positive carbon isotope excursion is reported from Paleoproterozoic carbonates of the Aravalli Supergroup (northwestern India), the Minas Supergroup (Brazil), and new sections of the Paso Severino Formation (Uruguay). The 2.42 Ga Gandarela Formation, Minas Gerais, Brazil, contains red carbonate-facies BIF grading into dolostones and limestones and yielding δ¹³C values ranging from −1.6 to +0.4‰ V-PDB. The positive C-isotope excursion (up to + 11‰ V-PDB) in marine shallow-water carbonates in India and Brazil (Jhamarkotra Formation in northwestern India, and Cercadinho and Fecho do Funil formations in Minas Gerais State, Brazil) is comparable to that observed in 2.22–2.1 Ga carbonate successions worldwide that were deposited during the Lomagundi excursion. In Uruguay, δ¹³C values up to +11.6‰ V-PDB in the deep-water Paso Severino Formation of the Piedra Alta Terrane are compatible with deposition at ca. 2.15 Ga, as indicated by the 2146 ± 7 Ma U–Pb age of dacites occurring at the top of the unit. Negative δ¹³C values are also present in carbonates of the Paso Severino Formation, but an origin related to organic-matter remineralization cannot be ruled out. Thin carbonate beds in the Rio Itapicuru greenstone belt, Bahia State, Brazil, are associated, as in the Paso Severino Formation, with deep-water black shales and have carbon isotope values up to +9‰ V-PDB. High metamorphic grade carbonates of the Jacurici terrane in the Medrado-Ipueira area, Bahia, Brazil, have carbon isotope values up to +6.9‰ V-PDB, consistent with their minimum age of 2085 ± 5 Ma inferred from the intrusive contact with and the age of the Medrado norite. No evidence was found in India, Brazil, or Uruguay for Paleoproterozoic glacial events recognized in the 2.45–2.22 Ga sedimentary successions worldwide. Unconformities between the Gandarela and Cercadinho formations in Brazil and the banded gneissic Complex and the Lower Aravalli Supergroup in India might explain the absence of glacial record. Compositional and isotopic data presented here for studied Paleoproterozoic carbonate successions allow their integration into the global record of the Paleoproterozoic evolution as well as correlation with other successions of similar age. The study highlights the global nature of the Lomagundi excursion. Furthermore, it indicates that the Lomagundi excursion is recorded in both shallow-water (Aravalli and Minas supergroups) and deep-water carbonates (Paso Severino Formation and Rio Itapicuru greenstone belt) negating a significant impact of stromatolite productivity and hypersaline conditions on carbon isotope values of carbonates deposited in shallow-water, open-marine and isolated basins.     

Flotation of galena. Influence of grain size,of pulp deoxygenation,and of cleaning with ammonium acetate

The flotation of < 10, 10–20, and 20–40 μm galena fractions was studied. For uncleaned galena a given collector coverage produced better floatability with increasing grain size. Nitrogen had a detrimental effect only for the < 10 μm fraction, producing at a given collector coverage a recovery smaller than that obtained with air.Galena cleaned with 400 g/l ammonium acetate had very poor floatability, although xanthate abstraction was fairly high; this confirms that strong xanthate adsorption is necessary for flotation. Formation of monothiocarbonate was small in all cases, which points to a very minor influence, if any, of this compound in the flotation process.In blank flotation tests, or for very low residual xanthate concentrations, a peak at 208 nm and a shoulder at 255 nm were observed. The former was assigned to the uncomplexed Pb²⁺ ion, and the latter was tentatively attributed to the PbOH⁺ ion.Lead in solution results from dissolution of the oxidation products of galena, as galena itself has an exceedingly low solubility. The curve for total lead in solution vs. initial xanthate concentration, had a minimum for an initial xanthate concentration of 10^?5M, the further increase in dissolved lead is attributed to formation of complexes such as PbX⁺ (X = xanthate). Dissolved lead concentrations were nearly as high for cleaned as for uncleaned galena, which indicates a high oxidation rate of the mineral.     

Assessing the rock glacier kinematics on three different timescales: a case study from the southern Swiss Alps

Surface temperature increases since the 1990s have often been associated with an increase in the speed of rock glaciers. Evidence of similar links on the centennial to millennial scale are, however, still lacking due to less focus to date on the medium‐ and long‐term kinematics of these landforms. In order to assess (palaeo)climatic variations in rock glacier kinematics, we analysed the movements of the Stabbio di Largario rock glacier in the southern Swiss Alps using three different timescales. The Schmidt hammer exposure‐age dating (SHD) was applied to study long‐term kinematics in order to extrapolate the minimal age of the formation of the rock glacier, which may have started its development after the Mid‐Holocene climate optimum, and to detect possible accelerations of the horizontal surface velocity during the Medieval Warm Period. Georeferentiation and orthorectification of six historical photographs of the rock glacier taken between ad 1910 and today were analysed using monoplotting to detect the rock glacier displacement on the decennial scale from the end of the Little Ice Age. Finally, differential global positioning system (dGPS) monitoring data available since ad 2009 were used to assess annual and seasonal creep rates of the rock glacier at present. Our results show a link between the periods of increase in mean air temperature on different timescales and variations in rock glacier kinematics and provide important new insights into rock glacier development and evolution on the long‐term scale. Copyright © 2014 John Wiley & Sons, Ltd.     

Identification of source of a marine oil-spill using geochemical and chemometric techniques

The current work aimed to identify the source of an oil spill off the coast of Maranhão, Brazil, in September 2005 and effect a preliminary geochemical survey of this environment. A combination of bulk analytical parameters, such as carbon isotope (δ¹³C) and Ni/V ratios, and conventional fingerprinting methods (High Resolution Gas Chromatography and Mass Spectrometry) were used. The use of bulk methods greatly speeded source identification for this relatively unaltered spill: identification of the likely source was possible at this stage. Subsequent fingerprinting of biomarker distributions supported source assignment, pointing to a non-Brazilian oil. Steranes proved the most useful biomarkers for sample correlation in this work. Distribution patterns of environmentally more resilient compound types, such as certain aromatic structures, proved inconclusive for correlation, probably in view of their presence in the background.