A procedure for landslide susceptibility zonation by the conditional analysis method

Numerous methods have been proposed for landslide probability zonation of the landscape by means of a Geographic Information System (GIS). Among the multivariate methods, i.e. those methods which simultaneously take into account all the factors contributing to instability, the Conditional Analysis method applied to a subdivision of the territory into Unique Condition Units is particularly straightforward from a conceptual point of view and particularly suited to the use of a GIS. In fact, working on the principle that future landslides are more likely to occur under those conditions which led to past instability, landslide susceptibility is defined by computing the landslide density in correspondence with different combinations of instability factors. The conceptual simplicity of this method, however, does not necessarily imply that it is simple to implement, especially as it requires rather complex operations and a high number of GIS commands. Moreover, there is the possibility that, in order to achieve satisfactory results, the procedure has to be repeated a few times changing the factors or modifying the class subdivision. To solve this problem, we created a shell program which, by combining the shell commands, the GIS Geographical Research Analysis Support System (GRASS) commands and the gawk language commands, carries out the whole procedure automatically. This makes the construction of a Landslide Susceptibility Map easy and fast for large areas too, and even when a high spatial resolution is adopted, as shown by application of the procedure to the Parma River basin, in the Italian Northern Apennines.     

Strategies to Make Methods Based on Flow Injection Analysis Greener

The implementation of flow injection analysis (FIA) systems and correlated techniques in the laboratory routine provides an increase of analytical throughput and the reduction of risks of analyte losses and contamination. Naturally, it contributes to the reduction of reagent consumption and minimization of waste generation. This paper presents and discusses an overview of the main strategies adopted to make methods based on FIA systems more environmentally friendly, and offers a review of these methods that covers the period from January 2002 to December 2019. Strategies based on reagent management (adoption of procedures without reagents, replacement of toxic reagents, recycling and reuse of reagents and, use of immobilized reagents), the online waste treatment, and the improvements of FIA systems (flow system configurations that avoid reagent wastage, use of green detectors, automation, and miniaturization) are approached in this perspective.     

S-wave splitting intensity analysis and inversion

Analysing S-wave splitting has become a routine step in processing multicomponent data. Typically, this analysis leads to determining the principal directions of a transversely isotropic medium with a horizontal symmetry axis, which is assumed to be responsible for azimuthal anisotropy, and to the time delays between the fast and slow S-waves. These parameters are commonly estimated layer-by-layer from the top. Errors in layer stripping occurring in shallow layers might propagate to deeper layers. We propose a method for S-wave splitting analysis and compensation that consists of inverting interval values of splitting intensity to obtain a model of anisotropic parameters that vary with time and/or depth. Splitting intensity is a robust attribute with respect to structural variations and is commutative, which means that it can be summed along a ray (or throughout a sensitivity kernel volume) and can be linearly related to anisotropic perturbations at depth. Therefore, it is possible to estimate anisotropic properties within a geological formation (e.g. the reservoir) by analysing the differences of splitting intensity measured at the top and at the bottom of the layer. This allows us to avoid layer stripping, in particular, for shallow layers where anisotropic parameters are difficult to estimate due to poor coverage, and it makes S-wave splitting analysis simpler to apply. We demonstrate this method on synthetic and real data. Because the splitting intensity attribute shows usefulness in S-wave splitting analysis in transversely isotropic media, we extend the splitting intensity theory to lower symmetry classes. It enables the characterization of tilted transversely isotropic and tilted orthorhombic media, opening new opportunities for anisotropic model building.     

Wave observations from an array of directional buoys over the southern Brazilian coast

It is well known that the majority of buoy measurements are located around the US coast and along some Europeans countries. The lack of long-term and densely spaced in situ measurements in the Southern Hemisphere in general, and the South Atlantic in particular, hinders several investigations due to the lack of detailed metocean information. Here, we present an effort to overcome this limitation, with a dense network of buoys along the Brazilian coast, equipped with several meteorological and oceanographic sensors. Out of ten currently operational buoys, three are employed to present the main characteristics of waves in the Southern part of the network. For the first time, sensor characteristics and settings are described, as well as the methods applied to the raw wave data. Statistics and distributions of wave parameters, swell propagating events, comparison with a numerical model and altimeters and a discussion about the occurrence of freak waves are presented.     

The role of hydrogeological setting in two Canadian peatlands investigated through 2D steady-state groundwater flow modelling

This study investigated how hydrogeological setting influences aquifer–peatland connections in slope and basin peatlands. Steady-state groundwater flow was simulated using Modflow on 2D transects for an esker slope peatland and for a basin peatland in southern Quebec (Canada). Simulations investigated how hydraulic heads and groundwater flow exported toward runoff from the peatland can be influenced by recharge, hydraulic properties, and heterogeneity. The slope peatland model was strongly dominated by horizontal flow from the esker. This suggests that slope peatlands are dependent on the hydrogeological conditions of the adjacent aquifer reservoir, but are resilient to hydrological changes. The basin peatland produced groundwater outflow to the surface aquifer. Lateral and vertical peat heterogeneity due to peat decomposition or compaction were identified as having a significant influence on fluxes. These results suggest that basin peatlands are more dependent on recharge conditions, and could be more susceptible to land use and climate changes.     

Linking shock textures revealed by BSE,CL, and EBSD with U‐Pb data (LA‐ICP‐MS and SIMS) from zircon from the Araguainha impact structure,Brazil

A silicious impact melt rock from polymict impact breccia of the northern part of the alkali granite core of the Araguainha impact structure, central Brazil, has been investigated. The melt rock is thought to represent a large mass of impact‐generated melt in suevite. In particular, a diverse population of zircon grains, with different impact‐induced microstructures, has been analyzed for U‐Pb isotopic systematics. Backscattered electron and cathodoluminescence images reveal heterogeneous intragrain domains with vesicular, granular, vesicular plus granular, and vesicular plus (presumably) baddeleyite textures, among others. The small likely baddeleyite inclusions are not only preferentially located along grain margins but also occur locally within grain interiors. LA‐ICP‐MS U‐Pb data from different domains yield lower intercept ages of 220, 240, and 260 Ma, a result difficult to reconcile with the previous “best age” estimate for the impact event at 254.7 ± 2.7 Ma. SIMS U‐Pb data, too, show a relatively large range of ages from 245 to 262 Ma. A subset of granular grains that yielded concordant SIMS ages were analyzed for crystallographic orientation by EBSD. Orientation mapping shows that this population consists of approximately micrometer‐sized neoblasts that preserve systematic orientation evidence for the former presence of the high‐pressure polymorph reidite. In one partially granular grain (#36), the neoblasts occur in linear arrays that likely represent former reidite lamellae. Such grains are referred to as FRIGN zircon. The best estimate for the age of the Araguainha impact event from our data set from a previously not analyzed type of impact melt rock is based on concordant SIMS data from FRIGN zircon grains. This age is 251.5 ± 2.9 Ma (2σ, MSWD = 0.45, p = 0.50, n = 4 analyses on three grains), indistinguishable from previous estimates based on zircon and monazite from other impact melt lithologies at Araguainha. Our work provides a new example of how FRIGN zircon can be combined with in situ U‐Pb geochronology to extract an accurate age for an impact event.     

Antioxidant and antitumor potential of wild and IMTA-cultivated Osmundea pinnatifida

Osmundea pinnatifida is a red edible seaweed known as pepper dulse. O. pinnatifida was cultivated in the farm of ALGAplus(Ilhavo, Portugal). This farm is integrated with a seabream and seabass commercial aquaculture and uses the nutrient-enriched water resultant from the fish production as its cultivation medium in the integrated multi-trophic aquaculture(IMTA) manner. Wild and IMTA-cultivated samples of O. pinnatifida were screened for antioxidant and antitumor activities. The antioxidant capacity of solvent extracts from wild and IMTA cultivated samples was assessed in two methods(2,2-diphenyl-1-picrylhydrazyl(DPPH) and oxygen radical absorbance capacity(ORAC)), and their total phenolic contents(TPC) were estimated. Antitumor activity was evaluated in three different tumor cell lines(HepG-2, MCF-7, and SH-SY5Y) through 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide(MTT)assay. Among the solvents used for extraction, dichloromethane was the most effective to extract phenolic compounds and presented higher ORAC. A significant correlation was found between TPC and ORAC,which was also sustained by the principal components analysis(PCA). Dichloromethane extracts induced a cytostatic effect on MCF-7 cells and showed weak cytotoxicity to SH-SY5Y cells and weak impact on cell proliferation. Overall, there were no statistically significant differences in the biological activities shown by the wild and IMTA-cultivated samples. Hence, O. pinnatifida can be obtained in an economical and environmentally sustainable way through IMTA, maintaining bioactive properties in a high potential for further nutraceutical purposes.     

The effect of salinity on Fucus ceranoides (Ochrophyta,Phaeophyceae) in the Mondego River (Portugal)

Algae(and their extracts) are increasingly important for pharmaceutical applications due to the diversity of useful compounds they contain. The genus Fucus contains one of the most studied species,Fucus vesiculosus. The species F. ceranoides differs from the others of the genus by presenting longitudinal air-vesicles and a capacity to survive at low salinities. It is an alga that inhabits the Mondego River estuary(Portugal), at the southern limit of its distribution, and can serve as a role model to understand the effect of a salt gradient on the production of bioactive compounds. We assessed the phenolic content and antioxidant activity of different F. ceranoides extracts(e.g. methanolic, aqueous and polysaccharide) prepared from samples harvested from two different zones to evaluate if the adaptation of F. ceranoides to different salinity levels influenced its chemical composition. The antioxidant activity of the extracts was determined using 1,2-diphenyl-picrylhydrazyl(DPPH) and 2.2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)(ABTS)radicals. These assays demonstrated that the methanolic extract of lyophilized F. ceranoides that grew at low salinities was the most bioactive, i.e. DPPH(IC_(50)=50.39 μg/mL) and ABTS(TEAC=2.42). The total phenolic content(Folin-Ciocalteu method) and the methanolic extract of the lyophilized F. ceranoides collected from a low salinity habitat exhibited the highest phenolic content(PGE=49.48 μg/mg of lyophilized extract)amongst those sampled. Thin layer chromatography(TLC) and Fourier transform infrared spectroscopy(FTIR) were used for the identification of compounds in the extracts. This characterization allowed confirmation that the various extracts contained almost the same compounds but with notable quantitative differences. Based on these results, we conclude that there were differences in the quantity of the compounds due to the effect of salinity. The drying methods used were also found to have influenced the quality of the extracted compounds.     

Insights about the formation of a complex impact structure formed in basalt from numerical modeling: The Vista Alegre structure,southern Brazil

We present the outcomes of simulations of the formation of the Vista Alegre impact structure, Paraná Basin, Brazil. The target comprised a thick sequence of volcanic rocks of predominantly basaltic composition of the Serra Geral Formation that had been deposited on top of sedimentary rocks (sandstones) of the Pirambóia/Botucatu formations. The cratering process was modeled using the iSALE shock physics code. Our best‐fit model suggests that (1) the crater was originally ~10 km in size; (2) it was formed in ~115 s by a stony projectile of 1000 m in diameter, for an assumed impact velocity of 12 km s^?1; (3) target rocks underwent a peak pressure of ~20 GPa, in agreement with previous petrographic investigations of shock deformation. Furthermore, the model points out that the sedimentary strata below the layer of volcanic rocks were raised by ~650 meters at the central part of the crater, which resulted in the current partial exposure of the sandstones at the surface. The outcomes of our modeling suggest that parameters like cohesion and strength of the target rocks, after shock compression, determined the final morphology of the crater, especially the absence of a topographically prominent central peak. Finally, the results of the numerical modeling are roughly in agreement with gravity data over the structure, in particular with respect to the presence of the uplifted sedimentary strata, which are responsible for a low gravity signature at the center of the structure.