New Activity of Chiron: Results from 5 Years of Photometric Monitoring

The results of photometric observations of Centaur object Chiron carried out at the Observatório do Pico dos Dias (OPD, Brazil), the Estación Astrof?́sica de Bosque Alegre (EABA, Argentina), and Complejo Astronómico El Leoncito (CASLEO, Argentina) from 1997 to 2001 are presented here. The analysis of the photometric data shows that the brightness of Chiron reached a minimum value in 1999 and began increasing again in 2000. The absolute magnitude, H_V, varied from 7.26 in June 1999 to 5.78 in April 2001. The data tend to indicate that Chiron is starting a new outburst of activity which is compatible with a sporadic cometary behavior not related to heliocentric distance.     

An evaluation of the CMIP3 and CMIP5 simulations in their skill of simulating the spatial structure of SST variability

The natural sea surface temperature (SST) variability in the global oceans is evaluated in simulations of the Climate Model Intercomparison Project Phase 3 (CMIP3) and CMIP5 models. In this evaluation, we examine how well the spatial structure of the SST variability matches between the observations and simulations on the basis of their leading empirical orthogonal functions-modes. Here we focus on the high-pass filter monthly mean time scales and the longer 5 years running mean time scales. We will compare the models and observations against simple null hypotheses, such as isotropic diffusion (red noise) or a slab ocean model, to illustrate the models skill in simulating realistic patterns of variability. Some models show good skill in simulating the observed spatial structure of the SST variability in the tropical domains and less so in the extra-tropical domains. However, most models show substantial deviations from the observations and from each other in most domains and particularly in the North Atlantic and Southern Ocean on the longer (5 years running mean) time scale. In many cases the simple spatial red noise null hypothesis is closer to the observed structure than most models, despite the fact that the observed SST variability shows significant deviations from this simple spatial red noise null hypothesis. The CMIP models tend to largely overestimate the effective spatial number degrees of freedom and simulate too strongly localized patterns of SST variability at the wrong locations with structures that are different from the observed. However, the CMIP5 ensemble shows some improvement over the CMIP3 ensemble, mostly in the tropical domains. Further, the spatial structure of the SST modes of the CMIP3 and CMIP5 super ensemble is more realistic than any single model, if the relative explained variances of these modes are scaled by the observed eigenvalues.     

Characterization of particulate matter in the Apulia Region (South of Italy): features and critical episodes

The chemical composition of PM₁₀ and PM_2.5 samples collected during two seasonal monitoring campaigns at residential, urban and industrial Apulia Region- sites was investigated. Ionic fraction, carbonaceous compounds and Polycyclic Aromatic Hydrocarbons were determined for all samples. High correlations among PM data collected in the investigated sites suggested the regional character of particulate matter. It was also confirmed by five days back trajectories analysis. Moreover, no significant seasonal trend in PM mass concentration was observed in the investigated sites. These results, relevant for the area under investigations, were not observed in the North of Italy and Europe and allow to conclude that PM₁₀ and PM_2.5 cannot be considered ‘good’ indicators for the evaluation of local anthropic contributions to air quality. On the contrary, the high levels of Polycyclic Aromatic Hydrocarbons found in Taranto sampling sites suggested that PAHs can be a better indicator for this purpose. This result is also relevant in order to weigh the importance of industrial area and to suggest right policy control to decision makers.     

Development of Kinetic Inductance Detectors for Cosmic Microwave Background experiments

We describe the design, optimization, electrical and optical tests of Microwave Kinetic Inductance Detectors (MKIDs) for the mm-wave range. Our detectors are based on a novel resonator design, and are suitable for ground-based astronomical observations in the 143 GHz atmospheric window. The measured optical Noise Equivalent Power (NEP) at 0.3 K is $\sim 10^{-16}~\text{W}/\sqrt{\rm Hz}$ under a 300 K background load. This is equivalent or better than the performance of the best current bolometric detectors for the 140 GHz atmospheric window, limited by atmospheric noise in the best available sites. We also describe which improvements can be introduced to reduce the NEP of our detector, for lower background applications (narrow band or space-based).     

Molecular-level modes of As binding to Fe(III) (oxyhydr)oxides precipitated by the anaerobic nitrate-reducing Fe(II)-oxidizing Acidovorax sp. strain BoFeN1

Sorption of contaminants such as arsenic (As) to natural Fe(III) (oxyhydr)oxides is very common and has been demonstrated to occur during abiotic and biotic Fe(II) oxidation. The molecular mechanism of adsorption- and co-precipitation of As has been studied extensively for synthetic Fe(III) (oxyhydr)oxide minerals but is less documented for biogenic ones. In the present study, we used Fe and As K-edge X-ray Absorption Near Edge Structure (XANES), extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, Mössbauer spectroscopy, XRD, and TEM in order to investigate the interactions of As(V) and As(III) with biogenic Fe(III) (oxyhydr)oxide minerals formed by the nitrate-reducing Fe(II)-oxidizing bacterium Acidovorax sp. strain BoFeN1. The present results show the As immobilization potential of strain BoFeN1 as well as the influence of As(III) and As(V) on biogenic Fe(III) (oxyhydr)oxide formation. In the absence of As, and at low As loading (As:Fe ≤ 0.008 mol/mol), goethite (Gt) formed exclusively. In contrast, at higher As/Fe ratios (As:Fe = 0.020-0.067), a ferrihydrite (Fh) phase also formed, and its relative amount systematically increased with increasing As:Fe ratio, this effect being stronger for As(V) than for As(III). Therefore, we conclude that the presence of As influences the type of biogenic Fe(III) (oxyhydr)oxide minerals formed during microbial Fe(II) oxidation. Arsenic-K-edge EXAFS analysis of biogenic As-Fe-mineral co-precipitates indicates that both As(V) and As(III) form inner-sphere surface complexes at the surface of the biogenic Fe(III) (oxyhydr)oxides. Differences observed between As-surface complexes in BoFeN1-produced Fe(III) (oxyhydr)oxide samples and in abiotic model compounds suggest that associated organic exopolymers in our biogenic samples may compete with As oxoanions for sorption on Fe(III) (oxyhydr)oxides surfaces. In addition HRTEM-EDXS analysis suggests that As(V) preferentially binds to poorly crystalline phases, such as ferrihydrite, while As(III) did not show any preferential association regarding Fh or Gt.     

Estimation of phase center corrections for GLONASS-M satellite antennas

Driven by the comprehensive modernization of the GLONASS space segment and the increased global availability of GLONASS-capable ground stations, an updated set of satellite-specific antenna phase center corrections for the current GLONASS-M constellation is determined by processing 84 weeks of dual-frequency data collected between January 2008 and August 2009 by a worldwide network of 227 GPS-only and 115 combined GPS/GLONASS tracking stations. The analysis is performed according to a rigorous combined multi-system processing scheme providing full consistency between the GPS and the GLONASS system. The solution is aligned to a realization of the International Terrestrial Reference Frame 2005. The estimated antenna parameters are compared with the model values currently used within the International GNSS Service (IGS). It is shown that the z-offset estimates are on average 7 cm smaller than the corresponding IGS model values and that the block-specific mean value perfectly agrees with the nominal GLONASS-M z-offset provided by the satellite manufacturer. The existence of azimuth-dependent phase center variations is investigated and uncertainties in the horizontal offset estimates due to mathematical correlations and yaw-attitude modeling problems during eclipse seasons are addressed. Finally, it is demonstrated that the orbit quality benefits from the updated GLONASS-M antenna phase center model and that a consistent set of satellite antenna z-offsets for GPS and GLONASS is imperative to obtain consistent GPS- and GLONASS-derived station heights.