Electron microprobe U–Th–Pb monazite dating of the Transamazonian metamorphic overprint on Archean rocks from the Amapá Block, southeastern Guiana Shield, Northern Brazil

The Amapá Block, southeastern Guiana Shield, represents an Archean block involved in a large Paleoproterozoic belt, with evolution related to the Transamazonian orogenic cycle (2.26 to 1.95 Ga). High spatial resolution dating using an electron-probe microanalyzer (EPMA) was employed to obtain U–Th–Pb chemical ages in monazite of seven rock samples of the Archean basement from that tectonic block, which underwent granulite- and amphibolite-facies metamorphism. Pb–Pb zircon dating was also performed on one sample.Monazite and zircon ages demonstrate that the metamorphic overprinting of the Archean basement occurred during the Transamazonian orogenesis, and two main tectono-thermal events were recorded. The first one is revealed by monazite ages of 2096 ± 6, 2093 ± 8, 2088 ± 8, 2087 ± 3 and 2086 ± 8 Ma, and by the zircon age of 2091 ± 5 Ma, obtained in granulitic rocks. These concordant ages provided a reliable estimate of the time of the granulite-facies metamorphism in the southwest of the Amapá Block and, coupled with petro-structural data, suggest that it was contemporaneous to the development of a thrusting system associated to the collisional stage of the Transamazonian orogenesis, at about 2.10–2.08 Ga.The later event, under amphibolite-facies conditions, is recorded by monazite ages of 2056 ± 7 and 2038 ± 6 Ma, and is consistent with a post-collisional stage, marked by granite emplacement and coeval migmatization of the Archean basement along strike-slip shear zones.     

River dissolved and solid loads in the Lesser Antilles: New insight into basalt weathering processes

We present here the first available estimations of chemical weathering and associated atmospheric CO₂ consumption rates as well as mechanical erosion rate for the Lesser Antilles. The chemical weathering (100–120 t/km²/year) and CO₂ consumption (1.1–1.4 × 10⁶ mol/km²/year) rates are calculated after subtraction of the atmospheric and hydrothermal inputs in the chemical composition of the river dissolved loads. These rates thus reflect only the low-temperature basalt weathering. Mechanical erosion rates (approx. 800–4000 t/km²/year) are estimated by a geochemical mass balance between the dissolved and solid loads and mean unaltered rock. The calculated chemical weathering rates and associated atmospheric CO₂ consumption rates are among the highest values worldwide but are still lower than those of other tropical volcanic islands and do not fit with the HCO₃⁻ concentration vs. 1/T correlation proposed by Dessert et al. (2001). The thick soils and explosive volcanism context of the Lesser Antilles are the two possible keys to this different weathering behaviour; the development of thick soils limits the chemical weathering and the presence of very porous pyroclastic flows allows an important water infiltration and thus subsurface weathering mechanisms, which are less effective for atmospheric CO₂ consumption.     

Compressibility and permeability of sand–kaolin mixtures. Experiments versus non‐linear homogenization schemes

This study deals with the behaviour of mixtures of sand and saturated kaolin paste considered as composite materials made of permeable and deformable (with non‐linear behaviour) matrix (the kaolin paste) with rigid and impervious inclusions (the sand grains). Oedometric and permeability tests highlight the key role of the state of the clay paste, and show the existence of a threshold of sand grain concentration above which a structuring effect influences both compressibility and permeability. At the light of these experiments two homogenization schemes (with simplifying assumptions to make the problem manageable) are considered to model these two parameters. Qualitative and quantitative comparisons with experimental data point out their respective domain of interest and limitations: a tangent homogenization scheme is shown to be sufficient to describe the macroscopic properties for dilute sand concentration; above the concentration threshold, the structuring effect is captured by the new homogenization scheme developed in this paper. Copyright © 2010 John Wiley & Sons, Ltd.     

Measure of the exponential splitting of the homoclinic tangle in four-dimensional symplectic mappings

Using four-dimensional symplectic maps as a model problem, we numerically compute the unstable manifolds of the hyperbolic manifolds of the phase space related to the single resonances. We measure an exponential dependence of the size of the lobes of these manifolds through many orders of magnitude of the perturbing parameter. This is an indirect numerical verification of the exponential decay of the normal form, as predicted by the Nekhoroshev theorem. The variation of the size of the lobes turns out to be correlated to the diffusion coefficient.     

A numerical study of the hyperbolic manifolds in a priori unstable systems. A comparison with Melnikov approximations

Using numerical methods we study the hyperbolic manifolds in a model of a priori unstable dynamical system. We compare the numerically computed manifolds with their analytic expression obtained with the Melnikov approximation. We find that, at small values of the perturbing parameter, the topology of the numerically computed stable and unstable manifolds is the same as in their Melnikov approximation. Increasing the value of the perturbing parameter, we find that the stable and unstable manifolds have a peculiar topological transition. We find that this transition occurs near those values of the perturbing parameter for which the error terms of Melnikov approximations have a sharp increment. The transition value is also correlated with a change in the behaviour of dynamical quantities, such as the largest Lyapunov exponent and the diffusion coefficient.     

Local and remote impacts of a tropical Atlantic salinity anomaly

The climatic impacts of an enhanced evaporation prescribed during 50 years in the tropical Atlantic are investigated in a coupled ocean–atmosphere general circulation model. Locally, the salinity increase leads to a rapid deepening and cooling of the surface mixed layer. This induces a deepening of the equatorial undercurrent and an intensification of the south equatorial current. A remote atmospheric response to the tropical Atlantic perturbation is detected in the North Atlantic sector after ten years. It has the form of a robust wave-like tropospheric perturbation seemingly excited by the weakening of atmospheric deep convection over the Amazonian basin. Meanwhile, the salt anomaly is carried northward by the mean oceanic circulation. It is traced up to the convection sites and then on its return path at depth towards lower latitudes. Consistent with the density increase, deep convection is enhanced after the arrival of the salt anomaly and the Atlantic meridional overturning circulation (AMOC) intensifies about 20 years after the beginning of the perturbation. The adjustment of the tropical Atlantic to the AMOC intensification then modifies its initial response to the freshwater forcing, leading to a weaker cooling in the northern tropical Atlantic than in the southern tropical Atlantic, a slight northward shift of the tropical Atlantic precipitation pattern and an intensification of the North Brazil current. On the other hand, no significant anomalous precipitations are found in the Pacific. The initial remote atmospheric response is also modulated, by an NAO-like response to the AMOC intensification.     

The 3640–3510 BC rhyodacite eruption of Chachimbiro compound volcano,Ecuador: a violent directed blast produced by a satellite dome

Based on geochronological, petrological, stratigraphical, and sedimentological data, this paper describes the deposits left by the most powerful Holocene eruption of Chachimbiro compound volcano, in the northern part of Ecuador. The eruption, dated between 3640 and 3510 years BC, extruded a ～650-m-wide and ～225-m-high rhyodacite dome, located 6.3 km east of the central vent, that exploded and produced a large pyroclastic density current (PDC) directed to the southeast followed by a sub-Plinian eruptive column drifted by the wind to the west. The PDC deposit comprises two main layers. The lower layer (L1) is massive, typically coarse-grained and fines-depleted, with abundant dense juvenile fragments from the outgassed dome crust. The upper layer (L2) consists of stratified coarse ash and lapilli laminae, with juvenile clasts showing a wide density range (0.7–2.6 g cm^?3). The thickness of the whole deposit ranges from few decimeters on the hills to several meters in the valleys. Deposits extending across six valleys perpendicular to the flow direction allowed us to determine a minimum velocity of 120 m s^?1. These characteristics show striking similarities with deposits of high-energy turbulent stratified currents and in particular directed blasts. The explosion destroyed most of the dome built during the eruption. Subsequently, the sub-Plinian phase left a decimeter-thick accidental-fragment-rich pumice layer in the Chachimbiro highlands. Juvenile clasts, rhyodacitic in composition (SiO₂?=?68.3 wt%), represent the most differentiated magma of Chachimbiro volcano. Magma processes occurred at two different depths (～14.4 and 8.0 km). The hot (～936 °C) deep reservoir fed the central vent while the shallow reservoir (～858 °C) had an independent evolution, probably controlled by El Angel regional fault system. Such destructive eruptions, related to peripheral domes, are of critical importance for hazard assessment in large silicic volcanic complexes such as those forming the Frontal Volcanic Arc of Ecuador and Colombia.     

Hydrodynamic behaviour of coarse bioclastic sand from shelly cheniers

Cheniers from Mont‐Saint‐Michel bay (France) are coarse shelly sand ridges migrating on the mudflat up to the salt marshes where they accumulate and merge in a littoral barrier. In this macrotidal setting and low wave forcing, the cheniers are rarely submerged. However, they are found to move up to several metres during coincidence of spring tide and wave activity. Their processes of migration, morphology and internal structure (composition of the beddings, grain size, sorting and grain arrangement) are thought to be closely related to the hydrodynamic behaviour of the coarse and shelly sediment. This paper focuses on the hydrodynamic behaviour of bioclastic sand sampled from the cheniers: settling velocities of the shell fragments were measured using a 2 m long sedimentation tube. Thresholds of motion under unidirectional current, velocity and turbulence vertical profiles were characterized in a small recirculating flume using Laser Doppler Anemometry (LDA). The flat‐shaped bioclastic particles feature low settling velocities and reveal a good resistance to the re‐suspension effect of the flow when imbricated in a sediment bed. The shear stress in the bottom boundary layer has been measured in the viscous and log sub‐layers. Nikuradse roughness heights (k_s) for shell debris beds of different sizes have been quantified. It is found that k_s ≈ 2·56d₅₀. This value is close to the ones used for classic rounded sand grains despite their major differences of shape. The dual behaviour of the shell fragments (low settling velocity, good resistance to unidirectional flow) should be considered as a key to understanding how this coarse material is transported across the tidal flat, and finally accumulated as cheniers. Further flume experiments including wave activity and tidal fluctuations are necessary to better quantify these complex processes. Copyright © 2010 John Wiley & Sons, Ltd.