Mixed-magma pyroclastic surge deposits associated with debris avalanche deposits at Colima volcanoes,Mexico

The transition between the terminal cones and the ancestral edifices of Nevado de Colima and Fuego de Colima volcanoes is marked by the deposits of gigantic volcanic debris avalanches of the Mount St. Helens (MSH) or Bezymianny type. Unusual mafic juvenile fragments and cauliflower bombs as well as juvenile fragments of mixed and more evolved composition are abundant in dune-bedded pyroclastic-surge deposits directly associated with these catastrophic events at both volcanoes. At Nevado, these mafic juvenile fragments represent the most primitive magma ever erupted by the volcano (SiO₂52.50%). The lavas directly preceding and following the debris-avalanche event are silicic andesites (SiO₂59%). At Fuego these juvenile fregments have 56% SiO₂. The lavas from the upper parts of the caldera wall are dacites (65% SiO₂), whereas the terminal cone is composed of andesites (57% to 62% SiO₂). At Nevado, petrologic evidence for interaction of mafic magma with andesitic or dacitic magma in a high-level magma chamber, just before the eruption of pyroclastic surge deposits, consists of: (1) banded juvenile bombs of intermediate composition; (2) the range of composition of these bombs from SiO₂52% to 58%; (3) the presence of highly magnesian olivine with reaction rims; (4) inverse zoning in clinopyroxene with strong Mg enrichment towards the rim; (5) resorption of plagioclase; and (6) significant compositional heterogeneity in the vitric phase. Volcanic debris-avalanche events at Nevado and Fuego de Colima may thus correspond with major breaks in the petrological evolution of the volcanoes and the start of a new magmatic cycle. Injection of mafic magma into the presently perched viscous surface dome of the active Fuego cone, as occurred in 1818 and 1913, could enhance the likelihood of southward collapse of the flank of an already unstable edifice, and it must be considered in future hazard assessment of this active volcano. Risk to life and property for the entire Colima region associated with such catastrophic phenomena would be immeasurably greater in comparison with hazards related to the last explosive outburst in 1913, which resulted in emplacement of pyroclastic flows over uninhabited areas of the upper flanks of the volcano.     

Nutrient Enrichments of Waters of "Golfo de San Jose" (Argentina, 42 oS), Growth and Species Selection of Phytoplankton

Abstract. Coastal Patagonian sea waters had been differentially nutrient-enriched to determine (i) the magnitude of the algal biomass supported and (ii) which species were able to best compete for the available nutrients. Nitrogen was found to be the nutrient limiting growth of the natural phytoplankton population. The addition of NO₃ at 25 μg at 1^-1 led to a 10 to 30 μg 1^-1 increase in chlorophyll a in all but those treatments containing trace metal additions. The best yield coefficients were obtained when a chelator (EDTA) was added with NO₃. A pool of nine diatom species were common in the N0₃ supplemented waters and the addition of vitamins along with NO₃ allowed two of the nine species to dominate.     

Solidus and liquidus temperatures and mineralogies for anhydrous garnet-lherzolite to 15 GPa

A review of experimental data for systems, pertaining to anhydrous fertile garnet-lherzolite shows strong convergence in the liquidus and solidus temperatures for the range 6.5–15 GPa. These can converge either to a common temperature or to temperatures which differ by only ～ 100°C. The major-element composition of magmas generated by even minor degrees of partial melting may be similar to the primordial bulk silicate Earth composition in an upper-mantle stratigraphic column extending over 160 km in depth.The convergence of the solidus and liquidus temperatures is a consequence of the highly variable $\text{d}\text{T}\text{d}\text{P}$ of the fusion curves for minerals which crystallize in peridotite systems. In particular, $\text{d}\text{T}\text{d}\text{P}$ for the forsterite fusion curve is much less than that for diopside and garnet. Whether or not the solidus and liquidus intersect, the liquidus mineralogy for undepleted garnet-lherzolite compositions changes from olivine at low pressures to pyroxene, garnet, or a complex pyroxene-garnet solid solution at pressures in excess of 10–15 GPa. Geochemical data for the earliest Archean komatiites are consistent with an upper-mantle phase diagram having garnet as a liquidus phase for garnet-lherzolite compositions at high pressures. All estimates of the anhydrous solidus and liquidus for the range 10–15 GPa are consistent with silicate liquid compressibility data, which indicate that olivine may be neutrally buoyant in ultramafic magmas at these pressures.     

A gigantic Bezymianny-type event at the beginning of modern volcan Popocatepetl

The history of volcan Popocatepetl can be divided into two main periods: the formation of a large primitive volcano — approximatively 30 km wide — on which is superimposed a modern cone (6–8 km in diameter and 1700m high). A major event of Bezymianny type marks the transition between these two dissimilar periods.The activity of the primitive volcano was essentially effusive and lasted several hundred thousands of years. The total volume of products ejected by the volcano is of the order of 500–600 km³. Its last differentiated magmas are dacitic.A gigantic debris flow (D.F.) spread on the southern side is related to the Bezymianny-type event which destroyed the summit area of the ancient edifice. An elliptical caldera ( 6.5 × 11 km wide) was formed by the landslide. Its deposits, with a typical hummocky surface, cover 300 km² for a volume of 28–30 km³. Numerous outcrops belonging to this debris flow show “slabs” of more or less fractured and dislocated rocks that come from the primitive volcano. These deposits are compared to two studied debris flows of similar extent and volume: the Mount Shasta and Colima's D.F.This eruption takes a major place in the volcanologic and magmatic history of Popocatepetl: pyroclastic products of surge-type with “laminites” and crude layers, ashflows, and pumiceous airfall layers are directly related to this event and begin the history of the modern volcano probably less than 50,000 years ago. In addition, a second andesitic and dacitic phase rose both from the central vent — forming the basis of modern Popo — and from lateral vents.The terminal cone is characterized by long periods of construction by lava flows alternating with phases of destruction, the duration of these episodes being 1000 to 2000 years. The cone is composed of two edifices: the first, volcan El Fraile, began with effusive activity and was partly destroyed by three periods of intense explosive activity. The first period occurred prior to 10.000 years B.P., the second from 10.000 to 8000 years B.P. and the third from 5000 to 3800 years B.P. Each period of destruction shows cycles producing collapsing pyroclastic flows or nuées of the St Vincent-type related to the opening of large craters, plinian air-fall deposits and minor lava flows. The second edifice, the summit Popo, produced lava flows until 1200 years B.P. and since that time, entered into an explosive period. Two cataclysmic episodes, each including major pyroclastic eruptions, occurred 1200 and 900–1000 years ago. During the Pre-Hispanic and historic times effusive activity was restricted entirely to the summit area alternating with plinian eruptions. Nevertheless, despite the quiet appearance of the volcano, the last period of pyroclastic activity which started 1200 years ago may not have ended and can be very dangerous for the nearby populations.     

87Rb87Sr chronology of H chondrites: Constraint and speculations on the early evolution of their parent body

A precise⁸⁷Rb-⁸⁷Sr whole-rock isochron for H chondrites and an internal isochron for Tieschitz (H3) have been determined. The age and⁸⁷Sr/⁸⁶Sr initial ratio of the whole rocks are4.52 ± 0.05 b.y. and0.69876 ± 0.00040(λ(⁸⁷Rb) = 1.42 × 10^?11yr^?1). For Tieschitz, whereas handpicked separates plot on a well-defined line, heavy liquid separates scatter in the⁸⁷Rb/⁸⁶Sr vs.⁸⁷Sr/⁸⁶Sr diagram. Leaching experiments by heavy liquids indicate that they might have a sizeable effect on Tieschitz minerals. The age and⁸⁷Sr/⁸⁶Sr initial ratio as determined by handpicked separates are4.53 ± 0.06 b.y. and0.69880 ± 0.00020, indistinguishable from the whole-rock isochron.These results are interpreted as “primitive isochrons” dating the condensation of chondrites from the solar nebula. The best value of this event is given by joining both isochrons together at4.518 ± 0.026 b.y. and⁸⁷Sr/⁸⁶Sr= 0.69881 ± 0.00016. The near identity of this initial ratio with the one of Allende white inclusions argues in favor of a sharp isochronism of condensation from a⁸⁷Sr/⁸⁶Sr homogeneous nebula. Data from Guaren?a [11] and Richardton [48] are interpreted as secondary internal isochrons, 100 m.y. after the condensation of the whole rocks.The data are then used to constrain a thermal evolution model of the H chondrite parent body. This body might have a 150–175 km radius, and might have been heated by²⁶Al. An²⁶Al/²⁷Al ratio of 4–6 × 10^?6 is enough for heating such a body. Further tests for this model are proposed.     

Contributions of H2S to the atmospheric sulfur cycle

H₂S is a most important biogenic sulfur compound with regard to the atmospheric sulfur cycle. Our present knowledge of the spatial and temporal distribution of this trace gas is rather incomplete owing to unreliable analytical methods. Therefore, a new method for the analysis of H₂S in the g-range was applied. This paper deals with the results of ground- and aircraft measurements of H₂S in unpolluted air over swamps and tidal flats. Based on the measured vertical distributions a removal coefficient of 2.3×10^–5 sec^–1 and an average lifetime of 12 hours were calculated. Some conclusions of the contribution of H₂S to the atmospheric sulfur budget are added.     

87Rb87Sr age of soils and rock from Mare Crisium Luna 24

The soil and one gabbroic fragment from Mare Crisium, brought back by the Luna-24 mission, have been measured through the ⁸⁷Rb/⁸⁷Sr method. The soil is one of the least radiogenic from the moon, comparable with Luna-16 soils. The gabbroic rock, which has a very low Rb/Sr ratio, gives an internal isochron age of 3.74 ± 0.58 Ga and an initial Sr ratio of 0.699085 ± 0.000070.     

Fine chronology of volcanic processes using 238U-230Th systematics

The²³⁰Th-²³⁸U radioactive disequilibrium method was applied to the study of recent volcanic rocks from Costa Rica. Most samples are from the Irazu volcano. Some samples were dated by internal isochrons using the (²³⁰Th/²³²Th)-(²³⁸U/²³²Th) diagram, others were studied only by whole rock analyses. The evolution of the parent magma may be followed by the initial (²³⁰Th/²³²Th)₀ ratios of the rocks. A model involving a differentiating magma chamber that existed for 140,000 years under the Irazu volcano correlates well with the observations. Other volcanoes seem to be in earlier stages of their evolution. Continuing study may help to solve the tholeiitic to andesitic volcanism relationship.