Zircon geochronology and Sm–Nd isotopic study: Further constraints for the Archean and Paleoproterozoic geodynamical evolution of the southeastern Guiana Shield, north of Amazonian Craton, Brazil

The eastern part of the Guiana Shield, northern Amazonian Craton, in South America, represents a large orogenic belt developed during the Transamazonian orogenic cycle (2.26–1.95 Ga), which consists of extensive areas of Paleoproterozoic crust and two major Archean terranes: the Imataca Block, in Venezuela, and the here defined Amapá Block, in the north of Brazil.

Pb-evaporation on zircon and Sm–Nd on whole rock dating were provided on magmatic and metamorphic units from southwestern Amapá Block, in the Jari Domain, defining its long-lived evolution, marked by several stages of crustal accretion and crustal reworking. Magmatic activity occurred mainly at the Meso-Neoarchean transition (2.80–2.79 Ga) and during the Neoarchean (2.66–2.60 Ga). The main period of crust formation occurred during a protracted episode at the end of Paleoarchean and along the whole Mesoarchean (3.26–2.83 Ga). Conversely, crustal reworking processes have dominated in Neoarchean times. During the Transamazonian orogenic cycle, the main geodynamic processes were related to reworking of older Archean crust, with minor juvenile accretion at about 2.3 Ga, during an early orogenic phase. Transamazonian magmatism consisted of syn- to late-orogenic granitic pulses, which were dated at 2.22 Ga, 2.18 Ga and 2.05–2.03 Ga. Most of the ε_Nd values and T_DM model ages (2.52–2.45 Ga) indicate an origin of the Paleoproterozoic granites by mixing of juvenile Paleoproterozoic magmas with Archean components.

The Archean Amapá Block is limited in at southwest by the Carecuru Domain, a granitoid-greenstone terrane that had a geodynamic evolution mainly during the Paleoproterozoic, related to the Transamazonian orogenic cycle. In this latter domain, a widespread calc-alkaline magmatism occurred at 2.19–2.18 Ga and at 2.15–2.14 Ga, and granitic magmatism was dated at 2.10 Ga. Crustal accretion was recognized at about 2.28 Ga, in agreement with the predominantly Rhyacian crust-forming pattern of the eastern Guiana Shield. Nevertheless, T_DM model ages (2.50–2.38 Ga), preferentially interpreted as mixed ages, and ε_Nd < 0, point to some participation of Archean components in the source of the Paleoproterozoic rocks. In addition, the Carecuru Domain contains an oval-shaped Archean granulitic nucleus, named Paru Domain. In this domain, Neoarchean magmatism at about 2.60 Ga was produced by reworking of Mesoarchean crust, as registered in the Amapá Block. Crustal accretion events and calc-alkaline magmatism are recognized at 2.32 Ga and at 2.15 Ga, respectively, as well as charnockitic magmatism at 2.07 Ga.

The lithological association and the available isotopic data registered in the Carecuru Domain suggests a geodynamic evolution model based on the development of a magmatic arc system during the Transamazonian orogenic cycle, which was accreted to the southwestern border of the Archean Amapá Block.     

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

Reconstructing hydrological variability from testate amoebae analysis in Carpathian peatlands

Peatlands offer the potential for high resolution records of water balance over Holocene timescales, yet this potential is under-exploited in many areas of the world. Within Europe, peatlands are mostly confined to areas north of 55° N, but several areas of southern and eastern Europe contain small peatlands which may be suitable for palaeoclimatic reconstruction. In this paper we test the potential of peatlands in the Carpathian region for deriving quantified estimates of water table changes using testate amoebae analysis. A training set for palaeohydrological reconstruction from testate amoebae assemblages was obtained by collecting surface samples from 13 peatlands, including 9 from Hungary and 4 from Transylvania (Romania). Using a simple measure of mean annual water tables estimated from staining of PVC tape, we found that some peatlands were heavily influenced by runoff and groundwater, and were therefore not suitable as modern analogues of ombrotrophic climatically sensitive sites. The relationship between the testate amoebae assemblages in the modern samples and the environmental variables was explored using CCA. The CCA biplot showed that the most important variables are depth to water table and moisture content, confirming that hydrology is a key control on taxon distribution. pH was a secondary gradient. A transfer function for % moisture and depth to water table was established and applied to fossil assemblages from a sequence from Fenyves-tető, Transylvania, Romania. The reconstructed water table shows a number of variations which have parallels with other palaeoclimatic records from Europe and the North Atlantic prominent phases of higher water tables are associated with the periods 8000–8300 cal BP, 3000–2500 cal BP and after 600 cal BP. We suggest that these were periods of particular intensification of westerly airflow which affected eastern Europe as well as western and central Europe.     

Diffusion-limited REE uptake by eclogite garnets and its consequences for Lu–Hf and Sm–Nd geochronology

Garnets from the Zermatt-Saas Fee eclogites contain narrow central peaks for Lu + Yb + Tm ± Er and at least one additional small peak towards the rim. The REE Sm + Eu + Gd + Tb ± Dy are depleted in the cores but show one prominent peak close to the rim. These patterns cannot be modeled using Rayleigh fractionation accompanied by mineral breakdown reactions. Instead, the patterns are well explained using a transient matrix diffusion model where REE uptake is limited by diffusion in the matrix surrounding the porphyroblast. Observed profiles are well matched if a roughly linear radius growth rate is used. The secondary peaks in the garnet profiles are interpreted to reflect thermally activated diffusion due to temperature increase during prograde metamorphism. The model predicts anomalously low ¹⁷⁶Lu/¹⁷⁷Hf and ¹⁴⁷Sm/¹⁴⁴Nd ratios in garnets where growth rates are fast compared to diffusion of the REE, and these results have important implications for Lu–Hf and Sm–Nd geochronology using garnet.     

Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Are Natural Climate Forcings Able to Counteract the Projected Anthropogenic Global Warming?

A two-dimensional global climate model is used to assessthe climatic changes associated with the new IPCC SRES emissions scenarios and to determine which kind of changes in total solar irradiance and volcanic perturbations could mask the projected anthropogenic global warming associated to the SRES scenarios. Our results suggest that only extremely unlikely changes in total solar irradiance and/or volcanic eruptions would be able to overcome the simulated anthropogenic global warming over the century. Nevertheless, in the critical interval of the next two decades the externally-driven natural climate variability might possibly confuse the debate about temperature trends and impede detection of the anthropogenic climate change signal.     

A Note On Surface Humidity Measurements In The Cold Canadian Environment

In the cold Canadian environment, humidity measurements can be verydifficult to conduct. In this brief communication, humidity observationstaken by two different sensors at six remote Canadian Arctic locations arecompared. The observations collected by Vaisala HMP35CF sensors displaya strong tendency toward the ice saturation point whereas dew cell instrumentsexhibit significantly lower values of relative humidity with respect to ice (RH_i).Humidity data collected by HMP35CF hygrometers are therefore unreliable sincethey are subject to persistent icing that lead them to record values of RH_i near 100%, irrespective of the air temperature. The high humidity bias emerges atmeteorological stations mounted with the HMP35CF probes since these instrumentsare usually neither sheltered nor heated, and are not attended to at regular intervals. Thus, great care must be taken in utilizing humidity data recorded by HMP35CF sensors across the network of climate autostations in Canada.     

Contested terrains: Cities and hinterlands in post-apartheid boundary delimitations

In South Africa attempts are being made to address the socio-spatial distortions of the apartheid era through a more equitable distribution of resources, and the re-drawing of municipal geographical boundaries. However, boundaries are not neutral geographic lines. Boundary changes are often associated with a redistribution of political power and resources. The aim of this paper is to analyse the effects of the contemporary territorial and administrative restructuring on urban dynamics in South Africa. More specifically, the focus is on how the process of territorial restructuring impacted on metropolitan areas as well as on secondary cities and their hinterlands. Examining and elucidating the manner in which various social, economic and political forces have manifested themselves in the process of boundary delimitation in a major metropolitan centre as well as adjacent rural areas is a central theme of this paper. There were considerable contestations over the delimitation of new local government boundaries. Affluent metro authorities like that in Durban were opposed to the spatial extension of their boundaries because of the costs of the providing services and infrastructure in the deprived margins. Similarly, there was concern that incorporation of rural areas will result in increased municipal service charges being imposed on these communities. Tensions were heightened between urban and rural regions because traditional leaders believed that their territorial jurisdiction and authority were being undermined. In other parts of the country, the merger of traditionally white and black fragments of secondary cities often resulted in many black locations continuing to be marginalized. There appears to be neither the political will nor the economic capacity to upgrade these zones of marginalized urban communities. While the Municipal Demarcation Board was largely successful in eliminating the political geography of apartheid at a macro- scale, this paper suggests that the greater challenge for government and policy makers is to reduce the socio-spatial and economic inequalities which appears to be still very high and perhaps increasing. This revised version was published online in July 2006 with corrections to the Cover Date.