Sources,transport, and sinks of SO<Subscript>2</Subscript> over the equatorial Pacific during the Pacific Atmospheric Sulfur Experiment

The Pacific Atmospheric Sulfur Experiment (PASE) is the first sulfur-budget field experiment to feature simultaneous flux measurements of DMS marine emissions and SO₂ deposition to the ocean surface. We make use of these data to constrain a 1-D chemical transport model to study the production and loss pathways for DMS and SO₂ over the equatorial Pacific. Model results suggest that OH is the main sink for DMS in the boundary layer (BL), and the average DMS-to-SO₂ conversion efficiency is ~73%. In an exploratory run involving the addition of 1 pptv of BrO as a second oxidant, a 14% increase in the DMS flux is needed beyond that based on OH oxidation alone. This BrO addition also reduces the DMS-to-SO₂ conversion efficiency from 73% to 60%. The possibility of non-DMS sources of marine sulfur influencing the estimated conversion efficiency was explored and found to be unconvincing. For BL conditions, SO₂ losses consist of 48% dry deposition, while transport loss to the BuL and aerosol scavenging each account for another 19%. The conversion of SO₂ to H₂SO₄ consumes the final 14%. In the BuL, cloud scavenging removes 85% of the SO₂, thus resulting in a decreasing vertical profile for SO₂. The average SO₂ dry deposition velocity from direct measurements (i.e., 0.36 cm sec⁻¹) is approximately 50% of what is calculated from the 1-D model and the global GEOS-Chem model. This suggests that the current generation of global models may be significantly overestimating SO₂ deposition rates over some tropical marine areas. Although the specific mechanism cannot be determined, speculation here is that the dry deposition anomalous results may point to the presence of a micro-surface chemical phenomenon involving partial saturation with either S(IV) and/or S(VI) DMS oxidation products. This could also appear as a pH drop in the ocean’s surface microfilm layer in this region. Finally, we propose that the enhanced SO₂ level observed in the lower free troposphere versus that in the upper BuL during PASE is most likely the result of transported DMS/SO₂-rich free-tropospheric air parcels from the east of the PASE sampling area, rather than an inadequate representation in the model of local convection.     

Pacific Atmospheric Sulfur Experiment (PASE): dynamics and chemistry of the south Pacific tropical trade wind regime

The Pacific Atmospheric Sulfur Experiment (PASE) was a comprehensive airborne study of the chemistry and dynamics of the tropical trade wind regime (TWR) east of the island of Kiritibati (Christmas Island, 157º, 20?? W, 2º 52?? N). Christmas Island is located due south of Hawaii. Geographically it is in the northern hemisphere yet it is 6?C12º south of the intertropical convergence zone (ITCZ) which places it in the southern hemisphere meteorologically. Christmas Island trade winds in August and September are from east south east at 3?C15 ms^?1. Clouds, if present, are fair weather cumulus located in the middle layer of the TWR which is frequently labeled the buffer layer (BuL). PASE provided clear support for the idea that small particles (80 nm) were subsiding into the tropical trade wind regime (TWR) where sulfur chemistry transformed them to larger particles. Sulfur chemistry promoted the growth of some of these particles until they were large enough to activate to cloud drops. This process, promoted by sulfur chemistry, can produce a cooling effect due to the increase in cloud droplet density and changes in cloud droplet size. These increases in particle size observed in PASE promote additional cooling due to direct scattering from the aerosol. These potential impacts on the radiation balance in the TWR are enhanced by the high solar irradiance and ocean albedo of the TWR. Finally because of the large area involved there is a large factional impact on earth??s radiation budget. The TWR region near Christmas Island appears to be similar to the TWR that persists in August and September, from southwest of the Galapagos to at least Christmas Island. Transport in the TWR between the Galapagos and Christmas involves very little precipitation which could have removed the aerosol thus explaining at least in part the high concentrations of CCN (??300 at 0.5% supersaturation) observed in PASE. As expected the chemistry of sulfur in the trade winds was found to be initiated by the emission of DMS into the convective boundary layer (BL, the lowest of three layers). However, the efficiency with which this DMS is converted to SO₂ has been brought into further question by this study. This unusual result has come about as result of our using two totally different approaches for addressing this long standing question. In the first approach, based on accepted kinetic rate constants and detailed steps for the oxidation of DMS reflecting detailed laboratory studies, a DMS to SO₂ conversion efficiency of 60?C73% was determined. This range of values lies well within the uncertainties of previous studies. However, using a completely different approach, involving a budget analysis, a conversion value of 100% was estimated. The latter value, to be consistent with all other sulfur studies, requires the existence of a completely independent sulfur source which would emit into the atmosphere at a source strength approximately half that measured for DMS under tropical Pacific conditions. At this time, however, there is no credible scientific observation that identifies what this source might be. Thus, the current study has opened for future scientific investigation the major question: is there yet another major tropical marine source of sulfur? Of equal importance, then, is the related question, is our global sulfur budget significantly in error due to the existence of an unknown marine source of sulfur? Pivotal to both questions may be gaining greater insight about the intermediate DMS oxidation species, DMSO, for which rather unusual measurements have been reported in previous marine sulfur studies. The 3 pptv bromine deficit observed in PASE must be lost over the lifetime of the aerosol which is a few days. This observation suggests that the primary BrO production rate is very small. However, considering the uncertainties in these observations and the possible importance of secondary production of bromine radicals through aerosol surface reactions, to completely rule out the importance of bromine chemistry under tropical conditions at this time cannot be justified. This point has been brought into focus from prior work that even at levels of 1 pptv, the effect of BrO oxidation on DMS can still be quite significant. Thus, as in the case of DMS conversion to SO₂, future studies will be needed. In the latter case there will need to be a specific focus on halogen chemistry. Such studies clearly must involve specific measurements of radical species such as BrO.     

Characteristics and evolution of the Tertiary palaeovalleys in the northwest Gawler Craton,South Australia

Integrated geoscientific datasets have contributed to an understanding of the Tertiary palaeovalleys once draining the Gawler Craton. Systematic investigations of both the shape and depth of the channels are based on interpretations from field exposures, a compendium of geological and drilling data, computer modelling of ancient landscapes, topographic and evaluated digital elevation models, remote sensing imagery, magnetics, seismic, gravity, airborne and transient electromagnetics, and radiometrics. Physical property contrasts that exist between the channel sediments and the underlying bedrock, for example, can be differentiated by geophysical methods to locate the incised‐valley thalweg. Evidence from sedimentology is combined with evidence from other geological and geophysical characteristics to arrive at a general reconstruction of palaeovalley architecture and history. The palaeovalleys were originally incised into the weathered pre‐Tertiary landscape of mostly weathered basement, and Tertiary fluvial, lacustrine, estuarine and even marine sediments accumulated during the Eocene and Miocene. Marine influence extended at least 100 km up the palaeovalleys during at least three major transgressions in the Eocene and Miocene intervals. Major sedimentary phases occurred in the Paleocene to Early Eocene, Middle to Late Eocene, Oligocene to Early Miocene, and Middle Miocene to Early Pliocene times.     

Description of littoral,alongshore sediment movement from empirical eigen‐function analysis

Measurements of 18 closely spaced beach profiles spanning Warilla Beach, N.S.W., over a 5‐year period have been examined for alongshore exchanges in beachface configuration. Horizontal slices of beach corresponding with berm, upper swash, upper and lower intertidal zones were examined by empirical orthogonal function (EOF) analysis. The first four EOF's for each of the four slices contain over 90% of the total variance for each slice. In each instance the first eigen‐function mode represents the onshore‐offshore component of beach response, and accounts for 50 to 60% of the variance. Subsequent modes describe alongshore exchange of sediment associated with large, standing, cellular water circulations of the embayment. Sediment shunts along each horizontal slice are determined by identification of nodal points in the eigen‐functions. These represent pivotal points through which sediment is transferred. The patterns of exchange vary considerably from slice to slice, reflecting change in the dominant beach processes from swash processes in the top of the beach to wave, tidal and current processes on the lower beach slope. Despite their disparity, similar periodicities are determined for the sediment exchanges in each slice. The amplitude spectra of the time series associated with each eigen‐function indicate that the exchanges take place at 24, 12 and 6 monthly periods.     

Temporal Accuracy in Urban Growth Forecasting: A Study Using the SLEUTH Model

This study attempts to establish multi‐temporal accuracy of the predicted maps produced by a land use change simulation model over time. Validation of the forecasted results is an essential part of predictive modeling and it becomes even more important when the models are used for decision making purposes. The present study uses a popular land use change model called SLEUTH to investigate the temporal trend of accuracy of the predicted maps. The study first investigates the trend of accuracy of the predicted maps from the immediate future to the distant future. Secondly, it investigates the impact of the prediction date range on the accuracy of the predicted maps. The objectives are tested for the city of Gorizia (Italy) using three sets of map comparison techniques, Kappa coefficients, Kappa Simulation and quantity disagreement and allocation disagreement. Results show that, in addition to the model's performance, the decrease in the accuracy of the predicted maps is dependent on factors such as urban history, uncertainty of input data and accuracy of reference maps.     

Secular changes in Earth’s shape and surface mass loading derived from combinations of reprocessed global GPS networks

The changing distribution of surface mass (oceans, atmospheric pressure, continental water storage, groundwater, lakes, snow and ice) causes detectable changes in the shape of the solid Earth, on time scales ranging from hours to millennia. Transient changes in the Earth’s shape can, regardless of cause, be readily separated from steady secular variation in surface mass loading, but other secular changes due to plate tectonics and glacial isostatic adjustment (GIA) cannot. We estimate secular station velocities from almost 11 years of high quality combined GPS position solutions (GPS weeks 1,000–1,570) submitted as part of the first international global navigation satellite system service reprocessing campaign. Individual station velocities are estimated as a linear fit, paying careful attention to outliers and offsets. We remove a suite of a priori GIA models, each with an associated set of plate tectonic Euler vectors estimated by us; the latter are shown to be insensitive to the a priori GIA model. From the coordinate time series residuals after removing the GIA models and corresponding plate tectonic velocities, we use mass-conserving continental basis functions to estimate surface mass loading including the secular term. The different GIA models lead to significant differences in the estimates of loading in selected regions. Although our loading estimates are broadly comparable with independent estimates from other satellite missions, their range highlights the need for better, more robust GIA models that incorporate 3D Earth structure and accurately represent 3D surface displacements.     

Contemporary American cartographic research: a review and prospective

ABSTRACT

We review recent developments in cartographic research in North America, in the context of informing the 29th International Cartographic Conference, and 18th General Assembly in 2019. The titles of papers published since 2015 in four leading cartographic journals yielded a corpus of 245 documents containing 1109 unique terms. These terms were analyzed using Latent Dirichlet Allocation and by visual analytics to produce 14 topic groups that mapped onto five classes. These classes were named as information visualization, cartographic data, spatial analysis and applications, methods and models, and GIScience. The classes were then used as themes to discuss the recent cartographic literature more broadly, first, to review recent trends in the research and to identify research gaps, and second, to examine prospects for new research over the next 20 years. A conclusion draws some broad findings from the review, suggesting that cartographic research in the future will be aimed less at dealing with data, and more at generating insight and knowledge to better inform society about global challenges.     

Exploring the Past and Future of Our Planet: Not Bit-by-Bit but All at Once

Understanding the Changing Planet lacks the spark of wonder and synthesis that initially attracted me into geography. Its structure around compelling questions reflects disciplinary fragmentation and the model of interdisciplinary science favored in the late twentieth century. It is suggested that geography can move beyond the “big tent with three poles” approach, to a twenty-first-century hyperdisciplinary model where content, science, analysis, and synthesis blur and a new bottom-up science can emerge. In this science, new theory and even grand unified theory might be possible. As discussed in Understanding the Changing Planet, the Web and the emergence of volunteered geographic information are examples. This would make study of the whole earth and its systems “a respectable object for scholarly efforts.”     

UV spectrum of Enceladus

We present a far ultraviolet (FUV) spectrum of Saturn’s moon Enceladus from the Cosmic Origins Spectrograph (COS) on the Hubble Space Telescope (HST). We have put upper limits on emission from C, N, and O lines in Enceladus’ atmosphere and column densities for the C lines assuming solar resonance scattering. We find these upper limits to be relatively low—on the order of tens to thousands of Rayleighs and with C column densities on the order of 10⁸–10¹⁵ cm^?2, depending on the assumed source size. We also present a segment of a reflectance spectrum in the FUV from ～1900–2130 Å. This region was sensitive to the different ice mixtures in the model spectra reported by Hendrix et al. (Hendrix, A.R., Hansen, C.J., Holsclaw, G.M. [2010]. Icarus, 206, 608). We find the spectrum brightens quickly longward of ～1900 Å, constraining the absorption band observed by Hendrix et al. from ～170 to 190 nm. We find our data is consistent with the suggestion of Hendrix et al. of the presence of ammonia ice (or ammonia hydrate) to darken that region, and also possibly tholins to darken the mid-UV, as reported by Verbiscer et al. (Verbiscer, A.J., French, R.G., McGhee, C.A. [2005]. Icarus, 173, 66).