Determination of volatile fatty acid turnover rates in organic-rich marine sediments

Volatile fatty acid (VFA) apparent turnover rates in organic-rich marine sediments were determined by measuring whole sediment VFA concentration and the corresponding first-order reaction rate constants. In order to measure VFA concentrations, bulk wet sediment samples were basified, freeze-dried, extracted with methanol, derivatized to form methyl esters of the VFAs, and analyzed by packed-column gas chromatography using hexanoic acid as an internal standard. The detection limits for acetate, propionate, iso-butyrate and butyrate were 1.0, 0.4, 0.2 and 0.2 μmol l^?1_s, respectively, for 600 ml samples. Rate constants for acetate and propionate were determined by anaerobically incubating samples at in-situ temperatures with tracer levels of ¹⁴C-labelled VFAs. Metabolized label was recovered as CO₂, CH₄, cellular material, water-soluble material, and VFA (ether-soluble) fractions. Apparent turnover rates measured during summer and winter in anoxic Cape Lookout Bight, North Carolina (U.S.A.) sediments were in the range of 19–330 μmol l^?1_s h^?1 for acetate and 0.7–7.0 μmol l^?1_s h^?1 for propionate.     

Possible production by lightning of aerosols and trace gases in Titan's atmosphere

Although lightning has not yet been observed in Titan's atmosphere, the presence of condensable vapors and the deposition of a significant amount of solar energy at the surface suggest the possibility of lightning activity. Based on an understanding of the relationship of lightning activity to the amount of convective energy available on Titan, a lightning energy dissipation rate of 4 × 10^?6, W/m² can be expected. This value is much lower than that for Earth or Jupiter, and is a result of both the reduced solar flux at Titan and the absorption of sunlight by the aerosols that lie above the convective layer. For this dissipation rate, the amount of HCN and C₂N₂ produced by lightning should be greater than that by solar UV, but could be less than that produced by electron precipitation and galactic cosmic rays. Equilibrium calculations indicate that large mole fractions of elemental solid phase carbon will also be produced. Using a simplified model of aerosol formation, coagulation, and settling, it is estimated that a lightning-produced aerosol could have a typical optical depth of 10^?2, with values as high as 0.1. The accumulation of soot over geological time might reach a meter or more in depth.     

Fish assemblage stability over fifty years in the Lake Pontchartrain estuary; Comparisons among habitats using canonical correspondence analysis

We assessed fish assemblage stability over the last half century in Lake Pontchartrain, an environmentally degraded oligohaline estuary in southeastern Louisiana. Because assemblage instability over time has been consistently associated with severe habitat degradation, we attempted to determine whether fish assemblages in demersal, nearshore, and pelagic habitats exhibited change that was unrelated to natural fluctuations in environmental variables (e.g., assemblage changes between wet and dry periods). Collection data from three gear types (trawl, beach seine, and gill nets) and monthly environmental data (salinity, temperature, and Secchi depth) were compared for four collecting periods: 1954 (dry period), 1978 (wet period), 1996–1998 (wet period), and 1998–2000 (dry period). Canonical correspondence analysis (CCA) revealed that although the three environmental variables were significantly associated with the distribution and abundance patterns of fish assemblages in all habitats (with the exception of Secchi depth for pelagic samples), most fish assemblage change occurred among sampling periods (i.e., along a temporal gradient unrelated to changing environmental variables). Assemblage instability was the most pronounced for fishes collected by trawls from demersal habitats. A marked lack of cyclicity in the trawl data CCA diagram indicated a shift away from a baseline demersal assemblage of 50 yr ago. Centroid positions for the five most collected species indicated that three benthic fishes, Atlantic croaker (Micropogonias undulatus), spot (Leiostomus xanthurus), and hardhead catfish (Arius felis), were more dominant in past demersal assemblages (1954 and 1978). A different situation was shown for planktivorous species collected by trawls with bay anchovy (Anchoa mitchilli) becoming more dominant in recent assemblage and Gulf menhaden (Brevoortia patromus) remaining equally represented in assemblages over time. Changes in fish assemblages from nearshore (beach seine) and pelagic (gill net) habitats were more closely related to environmental fluctuations, though the CCA for beach seine data also indicated a decrease in the dominance ofM. undulatus and an increase in the proportion ofA. mitchilli over time. The reduced assemblage role of benthic fishes and the marked assemblage change indicated by trawl data suggest that over the last half century demersal habitats in Lake Pontchartrain have been impacted more by multiple anthropogenic stressors than nearshore or pelagic habitats.     

Late Holocene lake level dynamics inferred from magnetic susceptibility and stable oxygen isotope data: Lake Elsinore, southern California (USA)

Southern California faces an imminent freshwater shortage. To better assess the future impact of this water crisis, it is essential that we develop continental archives of past hydrological variability. Using four sediment cores from Lake Elsinore in Southern California, we reconstruct late Holocene (3800 calendar years B.P.) hydrological change using a twentieth-century calibrated, proxy methodology. We compared magnetic susceptibility from Lake Elsinore deep basin sediments, lake level from Lake Elsinore, and regional winter precipitation data over the twentieth century to calibrate the late Holocene lake sediment record. The comparison revealed a strong positive, first-order relationship between the three variables. As a working hypothesis, we suggest that periods of greater precipitation produce higher lake levels. Greater precipitation also increases the supply of detritus (i.e., magnetic-rich minerals) from the lake's surrounding drainage basin into the lake environment. As a result, magnetic susceptibility values increase during periods of high lake level. We apply this modern calibration to late Holocene sediments from the lake's littoral zone. As an independent verification of this hypothesis, we analyzed ¹⁸O_(calcite), interpreted as a proxy for variations in the precipitation:evaporation ratio, which reflect first order hydrological variability. The results of this verification support our hypothesis that magnetic susceptibility records regional hydrological change as related to precipitation and lake level. Using both proxy data, we analyzed the past 3800 calendar years of hydrological variability. Our analyses indicate a long period of dry, less variable climate between 3800 and 2000 calendar years B.P. followed by a wet, more variable climate to the present. These results suggest that droughts of greater magnitude and duration than those observed in the modern record have occurred in the recent geological past. This conclusion presents insight to the potential impact of future droughts on the over-populated, water-poor region of Southern California.     

Containment criterion for contaminant isolation by cutoff walls

A rigorous solution is developed from first principles to guide the preliminary design of cutoff walls installed to contain the migration of contaminants from source zones. The full analytic solution is used to develop a criterion for determining the configuration and hydraulics of optimal wall designs. The solution is used to demonstrate the interaction between the properties of the wall, the Darcy flux, and the concentration of contaminants at the outside face of the well. For a particular wall design, the containment criterion can be used to estimate the long-term concentration that will develop at the outside face of the wall. Alternatively, for a given concentration on the outside face of the cutoff wall, the containment criterion can be used to estimate the Darcy flux required to balance the outward diffusion of contaminants. The results of numerical simulations are presented to evaluate the analytic approach. The numerical results confirm that for a wall with known transport properties, a specified Darcy flux is associated with a unique outside contaminant concentration.     

Ar/Ar thermochronology of the Kampa Dome, southern Tibet: Implications for tectonic evolution of the North Himalayan gneiss domes

Structural and thermochronological studies of the Kampa Dome provide constraints on timing and mechanisms of gneiss dome formation in southern Tibet. The core of Kampa Dome contains the Kampa Granite, a Cambrian orthogneiss that was deformed under high temperature (sub-solidus) conditions during Himalayan orogenesis. The Kampa Granite is intruded by syn-tectonic leucogranite dikes and sills of probable Oligocene to Miocene age. Overlying Paleozoic to Mesozoic metasedimentary rocks decrease in peak metamorphic grade from kyanite + staurolite grade at the base of the sequence to unmetamorphosed at the top. The Kampa Shear Zone traverses the Kampa Granite — metasediment contact and contains evidence for high-temperature to low-temperature ductile deformation and brittle faulting. The shear zone is interpreted to represent an exhumed portion of the South Tibetan Detachment System. Biotite and muscovite ⁴⁰Ar/³⁹Ar thermochronology from the metasedimentary sequence yields disturbed spectra with 14.22 ± 0.18 to 15.54 ± 0.39 Ma cooling ages and concordant spectra with 14.64 ± 0.15 to 14.68 ± 0.07 Ma cooling ages. Petrographic investigations suggest disturbed samples are associated with excess argon, intracrystalline deformation, mineral and fluid inclusions and/or chloritization that led to variations in argon systematics. We conclude that the entire metasedimentary sequence cooled rapidly through mica closure temperatures at  14.6 Ma. The Kampa Granite yields the youngest biotite ⁴⁰Ar/³⁹Ar ages of  13.7 Ma immediately below the granite–metasediment contact. We suggest that this age variation reflects either varying mica closure temperatures, re-heating of the Kampa Granite biotites above closure temperatures between 14.6 Ma and 13.7 Ma, or juxtaposition of rocks with different thermal histories. Our data do not corroborate the “inverse” mica cooling gradient observed in adjacent North Himalayan gneiss domes. Instead, we infer that mica cooling occurred in response to exhumation and conduction related to top-to-north normal faulting in the overlying sequence, top-to-south thrusting at depth, and coeval surface denudation.