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151.
We investigate the chemical transition of simple molecules like C2H2 and HCN into aerosol particles in the context of Titan's atmosphere. Experiments that synthesize analogs (tholins) for these aerosols can help illuminate and constrain these polymerization mechanisms. Using information available from these experiments, we suggest chemical pathways that can link simple molecules to macromolecules, which will be the precursors to aerosol particles: polymers of acetylene and cyanoacetylene, polycyclic aromatics, polymers of HCN and other nitriles, and polyynes. Although our goal here is not to build a detailed kinetic model for this transition, we propose parameterizations to estimate the production rates of these macromolecules, their C/N and C/H ratios, and the loss of parent molecules (C2H2, HCN, HC3N and other nitriles, and C6H6) from the gas phase to the haze. We use a one-dimensional photochemical model of Titan's atmosphere to estimate the formation rate of precursor macromolecules. We find a production zone slightly lower than 200 km altitude with a total production rate of 4×10−14 g cm−2 s−1 and a C/N?4. These results are compared with experimental data, and to microphysical model requirements. The Cassini/Huygens mission will bring a detailed picture of the haze distribution and properties, which will be a great challenge for our understanding of these chemical processes. 相似文献
152.
Christopher D. CooperJohn F. Mustard 《Icarus》2002,158(1):42-55
The goal of this work is to determine the spectroscopic properties of sulfate in martian soil analogs over the wavelength range 0.3 to 25 μm (which is relevant to existing and planned remotely sensed data sets for Mars). Sulfate is an abundant component of martian soil (up to 9% SO3 by weight) and apparently exists as a particulate in the soil but also as a cement. Although previous studies have addressed the spectroscopic identity of sulfates on Mars, none have used laboratory mixtures of materials with sulfates at the abundances measured by landed spacecraft, nor have any works considered the effect of salt-cementation on spectral properties of soil materials. For this work we created mixtures of a palagonitic soil (JSC Mars-1) and sulfates (MgSO4 and CaSO4·2H2O). The effects of cementation were determined and separated from the effects of packing and hydration by measuring the samples as loose powders, packed powders, cemented materials, and disaggregated materials. The results show that the presence of particulate sulfate is best observed in the 4-5 μm region. Soils cemented with sulfate exhibit a pronounced restrahlen band between 8 and 9 μm as well as well-defined absorptions in the 4-5 μm region. Cementation effects are distinct from packing effects and disaggregation of cemented samples rapidly diminishes the strength of the restrahlen bands. The results of this study show that sulfate in loose materials is more detectable in the near infrared (4-5 μm) than in the thermal infrared (8-9 μm). However, cemented materials are easily distinguished from loose mixtures in the thermal infrared because of the high values of their absorption coefficient in this region. Together these results suggest that both wavelength regions are important for determining the spatial extent and physical form of sulfates on the surface of Mars. 相似文献
153.
Estimates of spatial and temporal variations in suspended sand concentrations (SSC) made with a multi-transducer Acoustic Backscatter Sensor (ABS) under a repeated wave group over a mobile rippled bed in the wave research flume at the National Hydraulics Laboratory in Ottawa, Canada, reveal an number of complex and intriguing patterns. Ensemble averages of 8 nearly identical wave groups provided much more robust estimates of SSC and allowed a detailed examination of the wave group effects. The largest SSC near the bed (< 0.10 m) occurs in phase with the largest waves in the group. Above approximately 0.10 m elevation, SSC lags behind the near bed SSC by as much as 2–3 waves; introducing significant curvature (on a semi-log plot) to the SSC profile. The log linear segments of the SSC profile grow and decay systematically on the scale of the wave group. The range in lengths of log-linear profile segments ( 0.03–0.355 m) suggest that the boundary layer thickness also fluctuates throughout the passage of the wave group. Furthermore, there are significant variations in the patterns of SSC, which occur under the largest and smallest waves in the group. Under the largest waves vertical bands of alternating high and low SSC produce an intra-wave modulation in the upper water column ( 0.075–0.30 m). The equivalent horizontal excursion of these bands scales to the ripple length. Under the smaller waves the intra-wave modulation of the SSC disappears and is replaced by temporally homogenous suspension that expands vertically through several individual wave cycles. The former pattern of homogenous suspension appears to be associated with growth of a boundary layer due to the persistent uni-directional horizontal flow during this part of the group together with the persistence of antecedent bed generated turbulence and vorticity which maintains the suspension. The latter pattern of bands of high and low SSC indicates a strong temporal and spatial constraint on the SSC (phase coupling) induced by the presence of the bedforms which may be enhanced by strong reversals in both flow and vorticity under the large waves in the group. 相似文献
154.
Remineralization Ratios in the Subtropical North Pacific Gyre 总被引:2,自引:0,他引:2
Yuan-Hui Li David M. Karl Christopher D. Winn Fred T. Mackenzie Kathleen Gans 《Aquatic Geochemistry》2000,6(1):65-85
Based on a new mixing model of two end-members, the water column remineralization ratios of P/N/Corg - O2 = 1/13 ± 1/135 ± 18/170 ± 9 are obtained for the Hawaii Ocean Time-series (HOT) data set at station ALOHA. The traditional Redfield ratios of P/N/Corg/–O2 = 1/16/106/138 have standard deviations of more than 50%, when they are based on the average composition of phytoplankton. Apparently, the remineralization processes in the water column have smoothed out the observed large variability of plankton compositions. A new molar formula for the remineralized plankton may be written as 135H280O105N13P or C25(CH2O)101(CH4)9(NH3)13(H3PO4). Oxidation of this formula results inC25(CH2O)101(CH4)9(NH3)13(H3PO4) + 170O2 135CO2 + 132H2O + 13NO3
- + H2PO4
- + 14H+.For comparison, remineralization using Redfield's formula gives:(CH2O)106(NH3)16(H3PO4) + 138O2 106CO2 + 122H2O + 16NO3
-+ H2PO4
- + 17H+ 相似文献
155.
156.
Andrey M. Korjenkov J. Ramon Arrowsmith Christopher Crosby Ernes Mamyrov Lyubov A. Orlova Irina E. Povolotskaya Kubatbek Tabaldiev 《Journal of Seismology》2006,10(4):431-442
A paleoseismological study of the medieval Kamenka fortress in the northern part of the Issyk-Kul Lake depression, northern Tien Shan in Kyrgyzstan, revealed an oblique slip thrust fault scarp offsetting the fortification walls. This 700 m long scarp is not related to the 1911 Kebin Earthquake (Ms 8.2) fault scarps which are widespread in the region. As analysis of stratigraphy in a paleoseismic trench and archaeological evidence reveal, it can be assigned to a major twelfth century a.d. earthquake which produced up to 4 m of oblique slip thrusting antithetic to that of the nearby dominant faults. The inferred surface rupturing earthquake apparently caused the fortress destruction and was likely the primary reason for its abandonment, not the Mongolian–Tatar invasions as previously thought. 相似文献
157.
This paper highlights an analytical method based on mass measurement that can be used to directly quantify 129I in groundwater samples at concentrations below the maximum contaminant level (MCL) without the need for sample pre-concentration or extraction. Samples were analyzed on a Perkin Elmer ELAN DRC II ICP-MS after minimal dilution using O2 as the reaction gas. Analysis of continuing calibration verification standards indicated that the dynamic reaction cell (DRC) mode could be used for quantitative analysis of 129I in samples below the MCL (0.0057 ng/mL or 1 pCi/L). The low analytical detection limit of 129I analysis in the DRC mode coupled with minimal sample dilution (1.02x) resulted in a final estimated quantification limit of 0.0051 ng/mL. Subsequent analysis of three groundwater samples containing 129I resulted in fully quantitative results in the DRC mode, and spike recovery analyses performed on all three samples confirmed that the groundwater matrix did not adversely impact the analysis of 129I in the DRC mode. This analytical approach has been proven to be a cost-effective, high-throughput technique for the direct, quantitative analysis of 129I in groundwater samples at environmentally relevant concentrations that reach below the current MCL. 相似文献
158.
Bottom water hypoxic events were observed in Narragansett Bay, Rhode Island during the summer of 2001 using a towed sensor, vertical casts at fixed stations, and continuous monitoring buoys. This combination of approaches allowed for both extensive spatial and temporal sampling. Oxygen concentrations below the U.S. Environmental Protection Agency (EPA) acute hypoxia criterion of 2.3 mg l?1 were observed in the northern parts of Narragansett Bay, including the Providence River. We estimate 39% of the area of the Providence River was affected by acute hypoxia between July and September 2001. All other regions experienced only small areas of acute hypoxia (<5%), and no acute hypoxia was observed from Quonset Point south. The area encompassing oxygen concentrations below the EPA chronic hypoxia criterion of 4.8 mg l?1 was much more extensive in the upper half of Narragansett Bay, sometimes covering the majority of the region, though it is unclear whether exposure to concentrations below this criterion persisted long enough to significantly affect marine species in these areas. Vertical profiles of dissolved oxygen typically exhibited a mid water oxygen minimum near the pycnocline, followed by a slight increase in oxygen with depth. The surface waters above the pycnocline were typically supersaturated with oxygen. The northern portions of the Bay where the most extensive hypoxia was observed corresponded to the regions with both the greatest thermohaline stratification, the highest nutrient inputs, and the highest primary productivity. 相似文献
159.
Accurate upward continuation of gravity anomalies supports future precision, free-inertial navigation systems, since the latter
cannot by themselves sense the gravitational field and thus require appropriate gravity compensation. This compensation is
in the form of horizontal gravity components. An analysis of the model errors in upward continuation using derivatives of
the standard Pizzetti integral solution (spherical approximation) shows that discretization of the data and truncation of
the integral are the major sources of error in the predicted horizontal components of the gravity disturbance. The irregular
shape of the data boundary, even the relatively rough topography of a simulated mountainous region, has only secondary effect,
except when the data resolution is very high (small discretization error). Other errors due to spherical approximation are
even less important. The analysis excluded all measurement errors in the gravity anomaly data in order to quantify just the
model errors. Based on a consistent gravity field/topographic surface simulation, upward continuation errors in the derivatives
of the Pizzetti integral to mean altitudes of about 3,000 and 1,500 m above the mean surface ranged from less than 1 mGal
(standard deviation) to less than 2 mGal (standard deviation), respectively, in the case of 2 arcmin data resolution. Least-squares
collocation performs better than this, but may require significantly greater computational resources. 相似文献
160.
For the 1980–2003 period, we analyzed the relationship between crop yield and three climatic variables (minimum temperature,
maximum temperature, and precipitation) for 12 major Californian crops: wine grapes, lettuce, almonds, strawberries, table
grapes, hay, oranges, cotton, tomatoes, walnuts, avocados, and pistachios. The months and climatic variables of greatest importance
to each crop were used to develop regressions relating yield to climatic conditions. For most crops, fairly simple equations
using only 2–3 variables explained more than two-thirds of observed yield variance. The types of variables and months identified
suggest that relatively poorly understood processes such as crop infection, pollination, and dormancy may be important mechanisms
by which climate influences crop yield. Recent climatic trends have had mixed effects on crop yields, with orange and walnut
yields aided, avocado yields hurt, and most crops little affected by recent climatic trends. Yield-climate relationships can
provide a foundation for forecasting crop production within a year and for projecting the impact of future climate changes. 相似文献