Role of permeability barriers in alluvial hydromorphic palaeosols: The Eocene Pondaung Formation,Myanmar

This study examines the lateral distribution of hydromorphy in the fine‐grained alluvial deposits of the Eocene Pondaung Formation, central Myanmar. Through detailed outcrop analysis and using a combined sedimentological and pedological approach, this study proposes a reconstruction of Pondaung overbank floodplain palaeoenvironments. The variations of hydromorphic features in the different overbank sub‐environments are then discussed and used to build a model of hydromorphic variability in alluvial deposits. Two main architectural associations with distinctive lithofacies and pedogenic features were identified, corresponding to different sub‐environments: heterolithic deposits and extensive mudstone successions. The heterolithic deposits display variegated fine‐grained lithofacies and contain poorly developed palaeosols with gley and vertic features, which are interpreted to reflect a seasonal wetlands landscape, developed in actively aggrading avulsion belts. Extensive mudstone successions with Vertisols that locally exhibit mukkara‐style pseudogley features are interpreted to represent a distal open‐forested environment. The palaeosols of both sub‐environments display dense local hydromorphic variations they are also characterized by a gradual shift from gley‐dominated to pseudogley‐dominated features with increasing distance from the avulsion belt. The clay‐dominated lithology of the floodplain parent material, which forms numerous subsurface permeability barriers, is shown to have acted as a fundamental control in limiting water‐table dynamics in coarse‐grained parts of the succession, thereby favouring hydromorphic variability. Palaeosol sequences of the Pondaung Formation contrast with the soil‐landscape associations described in other studies and provide an alternative model with which to account for the hydromorphic variability in poorly drained, alluvial soils. The model proposed as an outcome of this study demonstrates that hydromorphic variations can be dramatic in floodplains where permeability barriers are numerous. Further, the model stresses the importance of undertaking detailed lateral palaeosol analyses prior to making interpretations regarding hydromorphic variability.     

Adapting rail and road networks to weather extremes: case studies for southern Germany and Austria

The assessment of the current impacts of extreme weather conditions on transport systems reveals high costs in specific locations. Prominent examples for Europe are the economic consequences of the harsh winter periods 2009/2010 and 2010/2011 and the floods in Austria, Eastern Europe, Germany and the United Kingdom in 2005 and 2007. Departing from the EC-funded project WEATHER, this paper delves into the subject of adaptation strategies by revisiting the project’s general findings on adaptation strategies and by adding two specific cases: (1) advanced winter maintenance on roads in southwest Germany and (2) technical and organizational measures in Alpine rail transport. For these two cases, feasible adaptation strategies are elaborated and their potential is discussed in light of damage cost forecasts up to 2050. For the road sector, we find a high potential to mitigate weather-related costs, although damages here are expected to decline. In contrast, rail systems face strongly increasing damages and the mitigation options offered by improved information and communication systems seem to be largely exploited. Consequently, it is easier to justify expensive adaptation measures for high-cost rail infrastructures than for road transport. A generic analysis of 14 damage cases worldwide, however, revealed that generally awareness raising, cooperation and communication strategies are sufficient to mitigate the most severe damages by natural disasters.     

Submicromolar Oxygen Profiles at the Oxic–Anoxic Boundary of Temperate Lakes

Elements involved in biogeochemical cycles undergo rapid turnover at the oxic–anoxic interface of stratified lakes. Here, the presence or absence of oxygen governs abiotic and biotic processes and rates. However, achieving a detailed sampling resolution to precisely locate the oxic–anoxic interface is difficult due to a lack of fast, drift-free sensors in the working range of 10 to a few 1,000 nmol O₂ L^?1. Here, we demonstrate that conventional amperometric and optical microsensors can be used to resolve submicromolar oxygen concentrations in a continuous profiling mode. The amperometric drift was drastically reduced by anoxic preconditioning. In situ offset correction in the anoxic layer and a high amplification scheme allowed for an excellent detection limit of < 10 nmol L^?1. The optical microsensors also showed a similar performance with a detection limit of < 20 nmol L^?1. Their drift stability allowed for a laboratory calibration in combination with a minor in situ anoxic offset correction. The two different sensor systems showed virtually identical profiles during parallel use in stratified lakes. Both sensors were able to resolve the fine-scale structure at the oxic–anoxic interface and revealed hitherto unnoticed extended zones of submicromolar oxygen concentrations even below a steep oxycline. The zones extended up to several meters and showed substantial vertical variability. These results underline the need of a precise localization of the oxic–anoxic interface on a submicromolar scale in order to constrain the relevant aerobic and anaerobic redox processes.     

The first major incision of the Swiss Deckenschotter landscape

The Swiss Deckenschotter (“cover gravels”) is the oldest Quaternary units in the northern Swiss Alpine Foreland. They are a succession of glaciofluvial gravel layers intercalated with glacial and/or overbank deposits. This lithostratigraphic sequence is called Deckenschotter because it “covers” Molasse or Mesozoic bedrock and forms mesa-type hill-tops. Deckenschotter occurs both within and beyond the extent of the Last Glacial Maximum glaciers. The Swiss Deckenschotter consist of two sub-units: Höhere (Higher) and Tiefere (Lower) Deckenschotter. Although the Höhere Deckenschotter sub-unit (HDS) is topographically higher than the Tiefere Deckenschotter, it is older. The only available age for the Swiss Deckenschotter is 2.5–1.8 Ma based on mammal remains found in HDS at the Irchel site. In this study, we present an exposure age for the topographically lowest HDS, calculated from a cosmogenic ¹⁰Be depth-profile. Our results show that the first phase of the Deckenschotter glaciations in the Swiss Alps terminated at least 1,020\(_{ - 120}^{ + 80}\) ka ago, which is indicated by a significant fluvial incision. This line of evidence seems to be close to synchronous with the beginning of the Mid-Pleistocene Revolution, when the frequency of the glacial-interglacial cyclicity changed from 41 to 100 ka and the amplitude from low to high, between marine isotope stages 23 and 22.     

Hydrologic fragmentation-induced eutrophication in Dove Sound,Upper Florida Keys,USA

Anthropogenic impacts to island systems can have deleterious effects on coastal aquatic ecosystems. These effects can alter water quality, primary production as well as habitat. Land development often fragments hydrologic connectivity within aquatic ecosystems forcing alterations in nutrient transport and increases the potential for eutrophication. Dove Sound, a tidal lagoon located in the Upper Florida Keys on Key Largo, has been subjected to anthropogenic influences of land development during the last century. To investigate these influences a short sediment core was collected from within Dove Sound and investigated using ²¹⁰Pb dating, stable isotopes of carbon and nitrogen, and sedimentary pigments. Results indicated that Dove Sound has undergone eutrophication and the primary producer community structure has shifted from dominantly macrophytic to a system that supports substantial algal production. While septic waste was a possible source for eutrophication, low δ¹⁵N did not support this conclusion. However, the timing of the shifts in Dove Sound along with indicators of anoxia leads to the conclusion that fragmentation caused by the construction of a railroad was the root cause. The hydrologic fragmentation reduced the flushing rates, thereby enhancing anoxic conditions in the system and increasing the internal nutrient loading.     

Geochemistry of highly acidic mine water following disposal into a natural lake with carbonate bedrock

Acid mine drainage (AMD) from the Zn–Pb(–Ag–Bi–Cu) deposit of Cerro de Pasco (Central Peru) and waste water from a Cu-extraction plant has been discharged since 1981 into Lake Yanamate, a natural lake with carbonate bedrock. The lake has developed a highly acidic pH of ∼1. Mean lake water chemistry was characterized by 16,775 mg/L acidity as CaCO₃, 4330 mg/L Fe and 29,250 mg/L SO₄. Mean trace element concentrations were 86.8 mg/L Cu, 493 mg/L Zn, 2.9 mg/L Pb and 48 mg/L As, which did not differ greatly from the discharged AMD. Most elements showed increasing concentrations from the surface to the lake bottom at a maximal depth of 41 m (e.g. from 3581 to 5433 mg/L Fe and 25,609 to 35,959 mg/L SO₄). The variations in the H and O isotope compositions and the element concentrations within the upper 10 m of the water column suggest mixing with recently discharged AMD, shallow groundwater and precipitation waters. Below 15 m a stagnant zone had developed. Gypsum (saturation index, SI ∼ 0.25) and anglesite (SI ∼ 0.1) were in equilibrium with lake water. Jarosite was oversaturated (SI ∼ 1.7) in the upper part of the water column, resulting in downward settling and re-dissolution in the lower part of the water column (SI ∼ −0.7). Accordingly, jarosite was only found in sediments from less than 7 m water depth. At the lake bottom, a layer of gel-like material (∼90 wt.% water) of pH ∼1 with a total organic C content of up to 4.40 wet wt.% originated from the kerosene discharge of the Cu-extraction plant and had contaminant element concentrations similar to the lake water. Below the organic layer followed a layer of gypsum with pH 1.5, which overlaid the dissolving carbonate sediments of pH 5.3–7. In these two layers the contaminant elements were enriched compared to lake water in the sequence As < Pb ≈ Cu < Cd < Zn = Mn with increasing depth. This sequence of enrichment was explained by the following processes: (i) adsorption of As on Fe-hydroxides coating plant roots at low pH (up to 3326 mg/kg As), (ii) adsorption at increasing pH near the gypsum/calcite boundary (up to 1812 mg/kg Pb, 2531 mg/kg Cu, and 36 mg/kg Cd), and (iii) precipitation of carbonates (up to 5177 mg/kg Zn and 810 mg/kg Mn; all data corrected to a wet base). The infiltration rate was approximately equal to the discharge rate, thus gypsum and hydroxide precipitation had not resulted in complete clogging of the lake bedrocks.     

The economic impact of future increase in tropical cyclones in Japan

This article estimates the non-first-order economic loss in Japan due to a future increase in tropical cyclones. One possible effect of global warming could be the increase in intensity of tropical cyclones. Using historical storm tracks between the years 1978 and 2007 and altering their intensities due to this potential increase in their intensity, this paper calculates the future potential regional GDP loss in a certain area that is affected by tropical cyclones. Most of the literature is concerned with physical damage and the loss of lives due to tropical cyclones. However, there are additional economic costs when sustained wind speeds are higher than 30 knots (55.56 km/h), a level that generally will lead to a precautionary cessation of many human activities. Using a Monte Carlo simulation, the paper calculates the potential economic costs for the year 2085 under a climate change scenario with a linear one-per cent yearly increase in CO₂. Using a spatial distribution of economic activity in Japan, it is possible to forecast which parts of the country are likely to experience the highest loss risk.     

Effect of citrate on the local Fe coordination in ferrihydrite, arsenate binding, and ternary arsenate complex formation

In oxic environments contaminated with arsenate (As(V)), small polyhydroxycarboxylates such as citrate may impact the structure of precipitating ferrihydrite (Fh) and thus the surface speciation of As(V). In this study, ‘2-line’ Fh was precipitated from ferric nitrate solutions that were neutralized to pH 6.5 in the presence of increasing citrate concentrations and in the absence or presence of As(V). The initial citrate/Fe and As/Fe ratios were 0-50 mol% and 5 mol%, respectively. The reaction products, enriched with up to 0.32 mol citrate per mole Fe, were characterized by X-ray diffraction, transmission electron microscopy, and Fe and As K-edge X-ray absorption spectroscopy. Citrate decreased the particle size of Fh by impairing the polymerization of Fe(O,OH)₆ octahedra via edge and corner linkages. In the presence of citrate and As(V), coordination numbers of Fe decreased by up to 28% relative to pure Fh. Citrate significantly reduced the static disorder of Fe-O bonds, implying a decreased octahedral distortion in Fh. Mean bond distances in Fh were not affected by citrate and remained constant within error at 1.98 Å for Fe-O, 3.03 Å for Fe-Fe1, and 3.45 Å for Fe-Fe2. Likewise, citrate had no effect on the As-Fe (3.31 Å) bond distance in As(V) coprecipitated with Fh. The As K-edge EXAFS data comply with the formation of (i) only monodentate binuclear (²C) As(V) surface complexes and (ii) combinations of ²C, monodentate mononuclear (¹V), and outersphere As(V) surface complexes. Our results suggest that increasing citrate concentrations led to a decreasing ¹V/²C ratio and/or that citrate increasingly impaired the formation of outersphere As(V) complexes. Moreover, citrate stabilized colloidal suspensions of Fh (pH 4.3-6.6, I ∼0.45 M) and reduced Fh formation at the expense of soluble Fe(III)-citrate complexes. At initial citrate/Fe ratios ?25 mol%, between 8% and 41% of total Fe was bound in Fe(III)-citrate complexes after Fh formation. Polynuclear Fe(III)-citrate species were found to bind As(V) via surface complexes indistinguishable by EXAFS from those of As(V) adsorbed to or coprecipitated with Fh. Our study implies that low molecular weight polyhydroxycarboxylates may enhance the mobility of As(V) in aqueous systems of high ionic strength (e.g., neutralizing acid mine drainage) by colloidal stabilization of suspended Fh particles and the formation of ternary As(V) complexes.     

Mercury flux to estuarine sediments, derived from Pb-210 and Cs-137 geochronologies (Guaratuba Bay, Brazil)

A sediment core from Guaratuba Bay was used to indicate possible Hg modifications to this coastal environment brought about by growing agricultural activity. Sedimentation rates were estimated to be 6.1 mm/year and 5.2 mm/year through 210Pb and 137Cs geochronologies, respectively. Mercury concentrations and organic matter ratios in the surface layers are greater than in the older sediments, supporting the hypothesis of anthropogenic enrichment. Results show that the Hg flux has raised more than twofold during the second half of the 20th century. These results point to the need for further studies to substantiate the hypothesis of anthropogenic enrichment and to quantify point sources of Hg to this estuary.     

Pumping test in a confined aquifer under tidal influence

In a coastal environment, tide-induced head fluctuations can complicate the interpretation of drawdown data from pumping tests. For confined aquifers and sinusoidal tides, the superposition principle can be used to obtain a closed-form solution. After subtracting the net tidal effects, the drawdown data become amenable to the standard analyses. Numerical simulations have shown that the method is reliable when the distance of the monitoring well to the well does not exceed 10% of the distance between the well and the tidal boundary.