From micron-sized needle-shaped hydrates to meter-sized shotcrete tunnel shells: micromechanical upscaling of stiffness and strength of hydrating shotcrete

Knowledge on the stresses in shotcrete tunnel shells is of great importance, as to assess their safety against severe cracking or failure. Estimation of these stresses from 3D optical displacement measurements requires shotcrete material models, which may preferentially consider variations in the water–cement and aggregate–cement ratios. Therefore, we employ two representative volume elements within a continuum micromechanics framework: the first one relates to cement paste (with a spherical material phase representing cement clinker grains, needle-shaped hydrate phases with isotropically distributed spatial orientations, a spherical water phase, and a spherical air phase; all being in mutual contact), and the second one relates to shotcrete (with phases representing cement paste and aggregates, whereby aggregate inclusions are embedded into a matrix made up by cement paste). Elasticity homogenization follows self-consistent schemes (at the cement paste level) and Mori–Tanaka estimates (at the shotcrete level), and stress peaks in the hydrates related to quasi-brittle material failure are estimated by second-order phase averages derived from the RVE-related elastic energy. The latter permits upscaling from the hydrate strength to the shotcrete strength. Experimental data from resonant frequency tests, ultrasonics tests, adiabatic tests, uniaxial compression tests, and nanoindentation tests suggest that shotcrete elasticity and strength can be reasonably predicted from mixture- and hydration-independent elastic properties of aggregates, clinker, hydrates, water, and air, and from strength properties of hydrates. At the structural level, the micromechanics model, when combined with 3D displacement measurements, predicts that a decrease of the water–cement ratio increases the safety of the shotcrete tunnel shell.     

Sedimentology of coexisting travertine and tufa deposits in a mounded geothermal spring carbonate system,Obruktepe, Turkey

The recent discoveries of deeply buried Cretaceous reservoir bodies in the Atlantic Ocean revealed that relationships between the distribution of spring carbonate deposits and faults are poorly understood. The well‐exposed Quaternary deposits at Obruktepe (Denizli Basin, Turkey) provide an opportunity to reconstruct the three‐dimensional sedimentary architecture of such a system. Integration of sedimentological, lithofacies and geochemical analyses reveals complexity in the lateral relationships between sedimentary environments, faults and geothermal spring carbonates. Five environmental systems are distinguished based on the lithofacies analysis: (i) vent; (ii) smooth slope; (iii) travertine‐terrace; (iv) tufa‐barrage; and (v) flood systems. Encrusting, baffling and settling sedimentary processes are reflected in data acquired at several scales, from lithofacies observations to the morphology and arrangement of geobodies, together with microfabrics and stable carbon and oxygen isotope data. Mean values of +4·9‰ δ¹³C and −8·74‰ δ¹⁸O Vienna PeeDee Belemnite reflect geothermal circulation of springwaters. The environmental distribution and lithofacies indicate a lateral continuum between travertine and tufa deposits within this hot spring system. This finding supports two depositional models in which water flow variation is the main control on both CaCO₃ precipitation and the resulting formation of travertine and tufa. The proposed models address the factors responsible for the development of these complex mound‐shaped carbonate spring deposits, and how they are related to fluid circulation at depth and in association with faults.     

Global Radiation and Onset of Stratification as Forcing Factors of Seasonal Carbonate and Organic Matter Flux Dynamics in a Hypertrophic Hardwater Lake (Sacrower See,Northeastern Germany)

A 2-year (October 2003–October 2005) high-resolution sediment trap study was conducted in Sacrower See, a dimictic hardwater lake in northeastern Germany. Geochemical and diatom data from sediment trap samples were compared with a broad range of limnological and meteorological parameters to quantify the impact of single parameters on biochemical calcite precipitation and organic matter production. Our goals were to disentangle how carbonaceous varves and their sublaminae form during the annual cycle to better understand the palaeorecords and to detect influences of dissolution, resuspension as well as of global radiation and stratification on lake internal particle formation. Total particle fluxes in both investigated years were highest during spring and summer. Sedimentation was dominated by autochthonous organic matter and biochemically precipitated calcite. Main calcite precipitation occurred between April and July and was preceded and followed by smaller flux peaks caused by resuspension during winter and blooms of the calcified green algae Phacotus lenticularis during summer. In some of the trap intervals during summer up to 100% of the precipitated calcite was dissolved in the hypolimnion. High primary production due to stable insolation conditions in epilimnic waters began with stratification of the water column. Start and development of stratification is closely related to air and water surface temperatures. It is assumed that global radiation influences the onset and stability of water column stratification and thereby determining the intensity of primary production and consequently of timing and amount of calcite precipitation which is triggered by phytoplanktonic CO₂ consumption. Sediment fluxes of organic matter and calcite are also related to the winter NAO-Index. Therefore these fluxes will be used as a proxy for ongoing reconstruction of Holocene climate conditions.     

A post-IR IRSL chronology and dust mass accumulation rates of the Nosak loess-palaeosol sequence in northeastern Serbia

In the Middle Danube Basin, Quaternary deposits are widely distributed in the Vojvodina region where they cover about 95% of the area. Major research during the last two decades has been focused on loess deposits in the Vojvodina region. During this period, loess in the Vojvodina region has become one of the most important Pleistocene European continental climatic and environmental records. Here we present the dating results of 15 samples taken from the Nosak loess-palaeosol sequence in northeastern Serbia in order to establish a chronology over the last three glacial–interglacial cycles. We use the pIRIR₂₉₀ signal of the 4–11 μm polymineral grains. The calculated ages are within the error limits partially consistent with the proposed multi-millennial chronostratigraphy for Serbian loess. The average mass accumulation rate for the last three glacial–interglacial cycles is 265 g m⁻² a⁻¹, which is in agreement with the values of most sites in the Carpathian Basin. Our results indicate a highly variable deposition rate of loess, especially during the MIS 3 and MIS 6 stages, which is contrary to most studies conducted in Serbia where linear sedimentation rates were assumed.     

Switching of a paleo-ice stream in northwest Svalbard

Ice streams are the fast-flowing zones of ice sheets that can discharge a large flux of ice. The glaciated western Svalbard margin consists of several cross-shelf troughs which are the former ice stream drainage pathways during the Pliocene–Pleistocene glaciations. From an integrated analysis of high-resolution multibeam swath-bathymetric data and several high-resolution two-dimensional reflection seismic profiles across the western and northwestern Svalbard margin we infer the ice stream flow directions and the deposition centres of glacial debris that the ice streams deposited on the outer margin. Our results show that the northwestern margin of Svalbard experienced a switching of a major ice stream. Based on correlation with the regional seismic stratigraphy as well as the results from ODP 911 on Yermak Plateau and ODP 986 farther south on the western margin of Spitsbergen, off Van Mijenfjord, we find that first a northwestward flowing ice stream developed during initial northern hemispheric cooling (starting ～2.8–2.6 Ma). A switch in ice stream flow direction to the present-day Kongsfjorden cross-shelf trough took place during a glaciation at ～1.5 Ma or probably later during an intensive major glaciation phase known as the ‘Mid-Pleistocene Revolution’ starting at ～1.0 Ma. The seismic and bathymetric data suggest that the switch was abrupt rather than gradual and we attribute it to the reaching of a tipping point when growth of the Svalbard ice sheet had reached a critical thickness and the ice sheet could overcome a topographic barrier.     

Stratigraphic simulations of the shelf of the Gulf of Lions: testing subsidence rates and sea‐level curves during the Pliocene and Quaternary

Determining the relative importance of factors interacting to control stratigraphic organization is a key issue in sedimentology. The Pliocene‐Quaternary chronostratigraphy on the Gulf of Lions platform is still poorly constrained, giving rise to different interpretations of the evolution of its subsidence through time. This paper examines the Pliocene‐Quaternary sedimentary filling of the Gulf of Lion's shelf with Dionisos, a numerical stratigraphic model. Our results show that a constant subsidence rate accurately reproduces the observed geometries, whereas a varying subsidence rate reproduces them only if the acceleration of subsidence is limited. At this time‐scale, a third‐order eustatic curve is also reappraised: a higher resolution curve (built using δ¹⁸O measurements) gives a more realistic restitution of our stratigraphic markers. Finally, the constant subsidence rate and sediment fluxes implied in these modellings are discussed relative to climate and local factors of sedimentation.     

The SW African volcanic rifted margin and the initiation of the Walvis Ridge,South Atlantic

The continental margin of SW Africa is typical of a volcanic rifted margin associated with a hotspot trail characterized by a large volcanic ridge, the Walvis Ridge, defining the hotspot migration, and extensive extrusive volcanism that produced seaward-dipping reflectors (SDR). Previously unpublished seismic data show two significant anomalies of the SW African Margin when compared to other typical volcanic rifted margins: (1) Hyaloclastitic outer highs are rare, and (2) the SDR in the North dip towards the Walvis Ridge. We explain these anomalies by a major transform segment close to the centre of volcanism combined with pulsed volcanism. The Walvis Ridge represents an east-west striking extrusive centre which produced a SDR sequence. Following break-up the northern boundary of the Walvis Ridge became a left lateral transform fault. Our data support the idea that a transform fault system interacting with a ridge jump were responsible for the accretion of the São Paulo Plateau to the American plate.     

Current velocity forecasting in straits with artificial neural networks,a case study: Strait of Istanbul

Owing to their complex character, modeling flow patterns of narrow straits has always been a challenge, even with the numerical techniques of today. This study was aimed at predicting vertical current profiles of a given point in a narrow strait, the Strait of Istanbul. On account of the speed and simplicity it offers, and of its remarkable success in solving complex problems, the feed forward back propagation (FFBP) artificial neural network (ANN) technique was chosen for this study. The model was built on 7039 hours of concurrent measurements of current profiles, meteorological conditions, and surface elevations. The model predicted 12 outputs of East and North velocity components at different depths in a given location. Various alternative models with different inputs and neuron numbers were evaluated attaining the best model by trial and error. Predictions from proposed ANN model were in accordance with the observations with average root mean square error of 0.16 m/s. The same input parameters were then used to build models that predicted current velocities 1–12 h into the future. Results of these predictions show good overall agreement with observations and that FFBP ANN can be used as a reliable tool for forecasting current profiles in straits.     

Accuracy of the spatial representation of the seafloor with bathymetric sidescan sonars

When isobath maps of the seafloor are constructed with a bathymetric sidescan sonar system the position of each sounding is derived from estimates of range and elevation. The location of each pixel forming the acoustic backscatter image is calculated from the same estimates. The accuracy of the resulting maps depends on the acoustic array geometry, on the performances of the acoustic signal processing, and on knowledge of other parameters including: the platform's navigation, the sonar transducer's attitude, and the sound rays' trajectory between the sonar and the seafloor. The relative importance of these factors in the estimation of target location is assesed. The effects of the platform motions (e.g. roll, pitch, yaw, sway, surge and heave) and of the uncertainties in the elevation angle measurements are analyzed in detail. The variances associated with the representation (orientation and depth) of a plane, rectangular patch of the seafloor are evaluated, depending on the geometry of the patch. The inverse problem is addressed. Its solution gives the lateral dimensions of the spatial filter that must be applied to the bathymetric data to obtain specified accuracies of the slopes and depths. The uncertainty in the estimate of elevation angle, mostly due to the acoustic noise, is found to bring the main error contribution in across-track slope estimates. It can also be critical for along-track slope estimates, overshadowing error contributions due to the platform's attitude. Numerical examples are presented.On leave at the Naval Research Laboratory, Code 7420, Washington D.C. 20375-5350, U.S.A.