Diffusion-controlled spherulite growth in obsidian inferred from H<Subscript>2</Subscript>O concentration profiles

Spherulites are spherical clusters of radiating crystals that occur naturally in rhyolitic obsidian. The growth of spherulites requires diffusion and uptake of crystal forming components from the host rhyolite melt or glass, and rejection of non-crystal forming components from the crystallizing region. Water concentration profiles measured by synchrotron-source Fourier transform spectroscopy reveal that water is expelled into the surrounding matrix during spherulite growth, and that it diffuses outward ahead of the advancing crystalline front. We compare these profiles to models of water diffusion in rhyolite to estimate timescales for spherulite growth. Using a diffusion-controlled growth law, we find that spherulites can grow on the order of days to months at temperatures above the glass transition. The diffusion-controlled growth law also accounts for spherulite size distribution, spherulite growth below the glass transition, and why spherulitic glasses are not completely devitrified. An erratum to this article can be found at     

New insights into the genesis of volcanic-hosted massive sulfide deposits on the seafloor from numerical modeling studies

Numerical computer simulations have been used to gain insight into the evolution of marine hydrothermal systems and the formation conditions of massive sulfide deposits in ancient and modern submarine volcanic terrains. Simulation results have been used to gain a better understanding of the formation of massive sulfide ore deposits, their location, zonation, size, and occurrence in various geotectonic settings.Most hydrothermal fluid discharging at the seafloor exhibits temperatures ranging from 200 °C to about 410 °C and average fluid discharge velocities of 1 to 2 m/s in agreement with seafloor observations. Mass calculations imply that average massive sulfide deposits may form in ~ 5000 years while giant deposits take longer than 5000 years to accumulate; supergiant deposits either need much longer time to form (> 35,000 years) or at least 100 ppm of metal in solution. Results indicate that supergiant deposits may only form in certain geotectonic environments where longevity and preservation potential of the hydrothermal system are high. An additional process (mineral precipitate cap) is proposed here to explain the zinc content of massive sulfide deposits. This cap would prevent the widespread dissolution of anhydrite and the ‘wash-out’ of zinc by subsequent hydrothermal fluid discharge.     

Microbial reduction of ferrous arsenate: Biogeochemical implications for arsenic mobilization

In reduced aqueous environments, the presence of As in solution is a function of both biotic and abiotic mechanisms. Recent studies have demonstrated a significant release of As(III) through the microbial reduction of dissolved and mineral-bound As(V), which raises health concerns when the greater comparative mobility and toxicity of As(III) is considered. These release mechanisms do not operate in isolation but occur in concert with a number of removal processes, including secondary mineralization and sorption to other natural substrates. Thermodynamic and applied experimental studies have shown that ferrous arsenates, such as symplesite [Fe(II)₃(As(V)O₄)₂·8H₂O], may provide a significant sink for Fe(II) and As(V). In this study, the stability of a representative ferrous arsenate phase in the presence of the arsenate-reducing bacterium Shewanella sp. strain ANA-3 is examined. The reduction of ferrous arsenate by ANA-3 results in the release of aqueous As(III) and, subsequently, the progressive nucleation of a biogenic ferrous arsenite phase proximal to the microbial cells. The valence states of secondary solid-phase products were verified using X-ray absorption spectroscopy (XAS). Electron microscopy reveals that nucleation occurs on cellular exudates which may imply a role of extracellular reduction through c-type cytochromes as investigated in recent literature. These observations provide new insights into the reduction mechanisms of ANA-3 and the biogeochemical cycling of As(III) in natural systems.     

Spectral Simulation of Isotropic Gaussian Random Fields on a Sphere

A spectral algorithm is proposed to simulate an isotropic Gaussian random field on a sphere equipped with a geodesic metric. This algorithm supposes that the angular power spectrum of the covariance function is explicitly known. Direct analytic calculations are performed for exponential and linear covariance functions. In addition, three families of covariance functions are presented where the calculation of the angular power spectrum is simplified (shot-noise random fields, Yadrenko covariance functions and solutions of certain stochastic partial differential equations). Numerous illustrative examples are given.

     

Geochemistry and petrography of impact breccias and target rocks from the 145 Ma Morokweng impact structure, South Africa

Morokweng is a large, 145 Ma impact structure in the Northwest Province of South Africa. The impact origin of this structure and its melt rock has been confirmed by ample evidence of shock metamorphism in clasts within the melt rock and samples from granitoid basement below the melt body. The age of this structure is indistinguishable from the biostratigraphic age of the Jurassic-Cretaceous (J-K) boundary. The size of Morokweng, for which diameters ranging from 70 to 165 kilometers have been quoted before, and which has important implications regarding its relation to the J-K boundary, remains an open question.Here we present new results of a detailed petrographic and chemical investigation of impact melt rock and country rock samples. The granophyric melt rock is mostly unaltered and contains a large number of gabbroic and felsic clasts. The occurrence of baddeleyite, formed from high-temperature dissociation of primary zircon, indicates a high-temperature origin. The impact melt rock body, which in the cores investigated here has a thickness of at least 120 m, shows no statistically significant variation or trend in chemical composition with depth or geographic location. Chemical data for impact melt rock, breccia dike/vein breccia samples, granite, quartzite, and basic to mafic clasts were used in harmonic least squares mixing calculations to determine the source rock types and their proportions involved in the formation of the impact melt rock. Granite is the dominant target rock component (50 to 63% by weight; depending on target composition input to the mixing models), with significant (35 to 50%) mafic contributions, and a (possible) minor contribution of quartzite. New platinum group element (Ru, Rh, Pd, Os, Ir, and Pt), Re, and Au data, as well as data for other siderophile elements (Cr, Co, Ni, and Ir), confirm the presence of up to ∼ 5% of a chondritic component in the melt rock. The indigenous contribution of the PGEs from the target rocks is negligible. Normalized PGE abundance patterns and interelement ratios of Morokweng impact melt rock indicate that the projectile was likely of ordinary chondritic (possibly L chondrite) composition, but the choice of the meteoritic compositional data influences this interpretation.     

Control of sulfate pore-water profiles by sedimentary events and the significance of anaerobic oxidation of methane for the burial of sulfur in marine sediments

Gravity driven mass-flow deposits proven by sedimentary and digital echosounder data are indicative for prevailing dynamic sedimentary conditions along the continental margin of the western Argentine Basin. In this study we present geochemical data from a total of 23 gravity cores. Pore-water SO₄ is generally depleted within a few meters below the sediment surface by anaerobic oxidation of methane (AOM). The different shapes of SO₄ profiles (concave, kink- and s-type) can be consistently explained by sedimentary slides possibly in combination with changes in the CH₄ flux from below, thus, mostly representing transient pore-water conditions. Since slides may keep their original sedimentary signature, a combined analysis and numerical modeling of geochemical, physical properties, and hydro acoustic data could be applied in order to reconstruct the sedimentary history. We present first order estimates of the dating of sedimentary events for an area where conventional stratigraphic methods failed to this day. The results of the investigated sites suggest that present day conditions are the result of events that occurred decades to thousands of years ago and promote a persisting mass transport from the shelf into the deep-sea, depositing high amounts of reactive compounds. The high abundance of reactive iron phases in this region maintains low hydrogen sulfide levels in the sediments by a nearly quantitative precipitation of all reduced sulfate by AOM. For the total region we estimate a SO₄ (or CH₄) flux of 6.6 × 10¹⁰ moles per year into the zone of AOM. Projected to the global continental slope and rise area, this may sum up to about 2.6 × 10¹² moles per year. Provided that the sulfur is completely fixed in the sediments it is about twice the global value of the recent global sulfur burial in marine sediments of 1.2 × 10¹² moles per year as previously estimated. Thus, AOM obviously contributes very significantly to the regulation of global sulfur reservoirs, which is hitherto not sufficiently recognized. This finding may have implications for global geochemical models, as sulfur burial is an important control factor in the development of atmospheric oxygen levels over time.     

Distribution patterns and habitat characterization of Simuliidae (Insecta: Diptera) in a low-order sandstone stream (Weidlingbach, Lower Austria)

A total of 1504 larval and 31 pupal Simuliidae were caught from March 2000 to February 2001 at the Weidlingbach, a fourth order tributary of the Danube near Vienna, Austria, using a modified box sampler (sampling area = 2116 cm²) at 12 sampling stations from source to mouth. From the six species collected, Prosimulium tomosvaryi (Enderlein) and two species of the Simulium ornatum-group (S. trifasciatum Curtis and S. ornatum Meigen) accounted for 97.5% of the total. Based on head width, instars 1–7 were collected in the S. ornatum-group and instars 2–7 in P. tomosvaryi; from two of the remaining species [Simulium (Nevermannia) cryophilum (Rubzov) and S. (N.) vernum Macquart], only pupae were sampled. The S. ornatum-group was most abundant on coarse substrates (median = 55.9 mm) exposed to high water velocity (median = 55.9 cm/s; range = 9–83 cm/s); the latter was also true for P. tomosvaryi although it favoured smaller sediment grain sizes (median = 32.4 mm). Species richness and population density increased from source to mouth. At sampling sites near the source Simuliidae were completely lacking. In headwaters only P. tomosvaryi was present, whereas the S. ornatum-group and Simulium (Simulium) argyreatum Meigen was collected exclusively near the mouth.     

Une méthode de simulation de l'évolution des profils d'altération

Calculations of transfer of elements between minerals and aqueous solutions can be extended to water open systems. With this method, we can obtain steady state for water composition. Furthermore, evolution in space and time of a weathering profile can be computed.     

Paleoclimatic record of a long deep sea core from the eastern Mediterranean

A deep-sea core over 16 m long from the crestal area of the Mediterranean Ridge has been investigated with different techniques, including quantitative micropaleontology, stable isotopes (measured on the epipelagic species Globigerinoides ruber and on the mesopelagic species Globorotalia inflata), and clay mineralogy. The resulting record of climatic fluctuations can be cross correlated to other Mediterranean cores by means of isochronous lithologies (tephra layers and sapropels). The climatic record of the Mediterranean is similar in character, phase, and chronology to the records investigated in the equatorial Pacific and in the Caribbean. Isotope stages 1 to 17 have been recognized. Cyclically repeated stagnant cycles resulting in sapropel deposition complicate both the isotopic and the faunal signal. The isotopic investigations reveal that the temperature change in the surface layers of the eastern Mediterranean was no greater than 8°C in the late “glacial” Pleistocene. The chronostratigraphic and biostratigraphic interpretation of Core KS09 indicate that the mean sedimentation rate was 2.4 cm/1000 years, a value very close to the 2.5 cm/1000 years calculated for the entire Quaternary section at DSDP Site 125, also located in the crestal area of the Mediterranean Ridge in the Ionian Basin. The base of KS09 is likely to be very close to the Brunhes/Matuyama boundary dated at 0.7 my.