Scanning electron microscopy,cathodoluminescence, and Raman spectroscopy of experimentally shock‐metamorphosed quartzite

Abstract— We studied unshocked and experimentally (at 12, 25, and 28 GPa, with 25, 100, 450, and 750°C pre‐shock temperatures) shock‐metamorphosed Hospital Hill quartzite from South Africa using cathodoluminescence (CL) images and spectroscopy and Raman spectroscopy to document systematic pressure or temperature‐related effects that could be used in shock barometry. In general, CL images of all samples show CL‐bright luminescent patchy areas and bands in otherwise nonluminescent quartz, as well as CL‐dark irregular fractures. Fluid inclusions appear dominant in CL images of the 25 GPa sample shocked at 750°C and of the 28 GPa sample shocked at 450°C. Only the optical image of our 28 GPa sample shocked at 25°C exhibits distinct planar deformation features (PDFs). Cathodoluminescence spectra of unshocked and experimentally shocked samples show broad bands in the near‐ultraviolet range and the visible light range at all shock stages, indicating the presence of defect centers on, e.g., SiO₄ groups. No systematic change in the appearance of the CL images was obvious, but the CL spectra do show changes between the shock stages. The Raman spectra are characteristic for quartz in the unshocked and 12 GPa samples. In the 25 and 28 GPa samples, broad bands indicate the presence of glassy SiO₂, while high‐pressure polymorphs are not detected. Apparently, some of the CL and Raman spectral properties can be used in shock barometry.     

Carbon isotope fractionation between graphite and diamond during shock experiments

Abstract— Carbon isotopic compositions were measured for shock‐produced diamond and shocked graphite formed at peak pressures ranging from 37 to 52 GPa. The δ¹³C values of diamonds produced in a sealed container were generally lower than that of the initial graphite. The differences in the carbon isotopic composition between initial graphite and shocked graphite/diamond may reflect kinetic isotopic fractionation during the oxidation of the graphite/diamond and/or analytical artifacts possibly induced by impurities in the samples. The pressure effect on the isotopic fractionations between graphite and diamond can be estimated from the δ¹³C values of impurity‐free diamonds produced using a vented container from which gases, including oxygen, in pore spaces escaped during or after the diamond formation (e.g., 0.039 ± 0.085‰ at a peak pressure of 52 GPa). Any isotopic fractionation induced by shock conversion of graphite to diamond is too small to be detected in natural shock‐induced diamond‐graphite systems related to terrestrial impact cratering processes.     

The orion-IRc2 outflow observed in COJ=4-3

A CO J=4-3 map of the Orion-IRc2 region (size 80, beam 15) is presented. The outflow has a bipolar structure observed nearly pole-on. We interpret our observations in terms of an hierarchy of tubes where the fastest gas proceeds through the narrowest, innermost cone. The gas has an inhomogeneous temperature distribution and must be highly clumped. Most of the properties derived comply with the picture developed for the few known extreme high velocity outflows; however, this outflow contains exceptionally dense gas ( > 10⁶ cm^–3).     

The presolar grain inventory of fine‐grained chondrule rims in the Mighei‐type (CM) chondrites

We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine‐grained chondrule rims in six Mighei‐type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM‐related carbonaceous chondrite Sutter's Mill. Sixteen O‐anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix‐normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O‐rich grains are enriched in ¹⁷O, and could originate from low‐mass asymptotic giant branch stars. One grain is enriched in ¹⁷O and significantly depleted in ¹⁸O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core‐collapse supernova origin showing enhanced ¹⁸O/¹⁶O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O‐anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O‐rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe‐rich silicates, one forsterite‐like Mg‐rich silicate, two Al‐oxides with spinel‐like compositions, and one Fe‐(Mg‐)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca₂Mg[Si₂O₇]) or a an åkermanite‐diopside (MgCaSi₂O₆) intergrowth.     

The Cuban Tektite Revisited

Abstract— A tektite, probably found in Cuba, was previously classified as belonging to the North American tektite strewn field on the basis of chemistry, age, isotopic, and petrographic characteristics. New major element analyses and trace element analyses show that the sample falls within the range of other North American tektites, and is close to the bediasite compositions. There are, however, some differences to normal georgiaites and bediasites. In a Na₂O/K₂O diagram the sample plots between the two distinct fields formed by georgiaites and bediasites. The rare earth elements and some lithophile trace elements are slightly enriched compared to bediasites, and much higher than in georgiaites. The discovery of tektite fragments from locations at Barbados and a DSDP site off the coast of New Jersey makes it likely that the North American strewn field is larger than previously thought, in agreement with microtektite distributions. Thus it is possible that the “Cuban” tektite really originated from Cuba.     

The particle background of the <Emphasis Type="Italic">X-IFU</Emphasis> instrument

In this paper we are going to review the latest estimates for the particle background expected on the X-IFU instrument onboard of the ATHENA mission. The particle background is induced by two different particle populations: the so called “soft protons” and the Cosmic rays. The first component is composed of low energy particles (< 100s keV) that get funnelled by the mirrors towards the focal plane, losing part of their energy inside the filters and inducing background counts inside the instrument sensitivity band. The latter component is induced by high energy particles (> 100 MeV) that possess enough energy to cross the spacecraft and reach the detector from any direction, depositing a small fraction of their energy inside the instrument. Both these components are estimated using Monte Carlo simulations and the latest results are presented here.     

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.     

Geochemical evidence of an extraterrestrial component in impact melt breccia from the Paleoproterozoic Dhala impact structure,India

The Paleoproterozoic Dhala structure with an estimated diameter of ~11 km is a confirmed complex impact structure located in the central Indian state of Madhya Pradesh in predominantly granitic basement (2.65 Ga), in the northwestern part of the Archean Bundelkhand craton. The target lithology is granitic in composition but includes a variety of meta‐supracrustal rock types. The impactites and target rocks are overlain by ~1.7 Ga sediments of the Dhala Group and the Vindhyan Supergroup. The area was cored in more than 70 locations and the subsurface lithology shows pseudotachylitic breccia, impact melt breccia, suevite, lithic breccias, and postimpact sediments. Despite extensive erosion, the Dhala structure is well preserved and displays nearly all the diagnostic microscopic shock metamorphic features. This study is aimed at identifying the presence of an impactor component in impact melt rock by analyzing the siderophile element concentrations and rhenium‐osmium isotopic compositions of four samples of impactites (three melt breccias and one lithic breccia) and two samples of target rock (a biotite granite and a mafic intrusive rock). The impact melt breccias are of granitic composition. In some samples, the siderophile elements and HREE enrichment observed are comparable to the target rock abundances. The Cr versus Ir concentrations indicate the probable admixture of approximately 0.3 wt.% of an extraterrestrial component to the impact melt breccia. The Re and Os abundances and the ¹⁸⁷Os/¹⁸⁸Os ratio of 0.133 of one melt breccia specimen confirm the presence of an extraterrestrial component, although the impactor type characterization still remains inconclusive.     

On the occurrence and origin of anthropogenic radionuclides found in a fragment of the Chelyabinsk (LL5) meteorite

A piece of the 2013 Chelyabinsk meteorite was investigated for its content of anthropogenic radionuclides. In addition to traces of cesium‐137 that had been previously reported for this particular fragment, we found an unusually high amount of strontium‐90, which indicates that the source of this contamination was the Kyshtym accident (1957). A high Sr‐90/Cs‐137 activity ratio is characteristic for Kyshtym‐derived contaminations. Based on the cesium‐137 content in the soil from the finding site, it is estimated that the fragment was contaminated with soil particles in the milligram range upon impact. Investigation of the soil revealed very unusual ferromagnetic characteristics and an iron‐rich chemical composition. Mössbauer spectroscopy indicated the presence of steel components in this soil, suggesting that the investigated meteorite fragment was found in an industrial dumping site rather than natural soil.     

Accretionary lapilli from the Sudbury impact event

Meteorite impact‐generated accretionary lapilli are not well studied. The recently discovered distal ejecta from the 1850 Ma Sudbury impact event contain abundant accretionary lapilli generated during the impact and deposited at great distances from the crater. We petrographically and geochemically examined lapilli from five sites (McClure, Connors Creek, Hwy 588, Pine River, and Grand Trunk Pacific, approximately 480–750 km from the center of the Sudbury structure). The compositions of quartz, K‐feldspar, calcite, biotite, and chlorite minerals are similar to each other in all of the samples, although the relative proportions of the minerals vary from site to site. The lapilli occur in a matrix of coarse‐grained quartz, carbonate, and feldspar grains. Zonation within lapilli appears to be due to grain size distribution rather than compositional variation. The inner zones are coarser grained than outer zones. The relative abundances of calcite, phyllosilicates, and feldspars are similar in each zone within individual lapilli. A meteoritic component is indicated by up to 1.8 ppb Ir in one lapillus from the Pine River site, and Ni and Cr ratios are on a chondritic trend line for many of the lapilli. Mechanisms previously proposed for accretionary lapilli formation seem inadequate to explain deposition of distal accretionary lapilli resulting from impact events. A new mechanism for upper atmospheric accretion is proposed, whereby ash ejected from impact events concentrates at altitudes of neutral buoyancy, where it then accretes and is deposited later than ballistically emplaced particles. Likely, multiple processes are taking place in the chaotic postimpact environment.